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Aromatic Hydroxyketones: Preparation & Physical Properties [[electronic resource] ] : Aromatic Hydroxyketones from Butanone (C4) to Dotriacontanone (C32) / / by Robert Martin, Jean-Pierre Buisson
Aromatic Hydroxyketones: Preparation & Physical Properties [[electronic resource] ] : Aromatic Hydroxyketones from Butanone (C4) to Dotriacontanone (C32) / / by Robert Martin, Jean-Pierre Buisson
Autore Martin Robert
Edizione [1st ed. 2015.]
Pubbl/distr/stampa Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015
Descrizione fisica 1 online resource (1456 p.)
Disciplina 547
547.036
547/.036
Soggetto topico Organic chemistry
Medicinal chemistry
Pharmacy
Organic Chemistry
Medicinal Chemistry
ISBN 3-319-14185-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto From the Contents: Part I Monoketones -- Part II Polyketones -- Pentanones -- Hexanones -- Heptanones -- Octanones -- Nonanones -- Decanones -- Undecanones -- Tridecanones -- Tetradecanones -- Pentadecanones.- Hexadecanones -- Heptadecanones -- Octadecanones -- Nonadecanones -- Eicosanones -- Heneicosanones -- Docosanones -- Tricosanones -- Pentacosanones -- Hexacosanones -- Triacont Anones -- Dotriacont Anones.
Record Nr. UNINA-9910298625803321
Martin Robert  
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Carbonyl compounds : reactants, catalysts and products / / Feng Shi, Hongli Wang, Xingchao Dai
Carbonyl compounds : reactants, catalysts and products / / Feng Shi, Hongli Wang, Xingchao Dai
Autore Shi Feng
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2022]
Descrizione fisica 1 online resource (375 pages)
Disciplina 547.036
Soggetto topico Carbonyl compounds
Soggetto genere / forma Electronic books.
ISBN 3-527-82561-4
3-527-82562-2
3-527-82560-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Copyright -- Contents -- Preface -- Part I Carbonyl Molecules as Reactants -- Chapter 1 Carbon Monoxide -- 1.1 Hydroformylation of Alkenes and Alkynes -- 1.1.1 Co Catalysts -- 1.1.2 Rh Catalysts -- 1.1.3 Au Catalysts -- 1.1.4 Ligand‐Modified Heterogeneous Catalysts -- 1.1.5 Single‐Atom Catalysts -- 1.2 Hydroxy-, Alkoxy-, and Aminocarbonylation of Alkenes and Alkynes -- 1.2.1 Hydroxycarbonylation of Alkenes -- 1.2.2 Hydroxycarbonylation of Alkynes -- 1.2.3 Alkoxycarbonylation of Alkenes -- 1.2.4 Alkoxycarbonylation of Alkynes -- 1.2.5 Aminocarbonylation of Alkenes -- 1.2.6 Aminocarbonylation of Alkynes -- 1.3 The Pauson-Khand Reaction -- 1.3.1 The Catalytic Pauson-Khand Reaction -- 1.3.2 Stereoselective Pauson-Khand Reactions -- 1.3.3 Pauson-Khand Transfer Carbonylation Reactions -- 1.4 Synthesis of Acetic Acid -- 1.4.1 Process Considerations -- 1.4.2 Rhodium‐Catalyzed Carbonylation -- 1.4.3 Iridium‐Catalyzed Carbonylation -- 1.5 Carbonylation of C X Bonds -- 1.5.1 Hydroxy‐, Alkoxy‐, and Aminocarbonylations of C X Bonds -- 1.5.2 Reductive Carbonylations -- 1.5.3 Carbonylative Coupling Reactions with Organometallic Reagents -- 1.5.4 Carbonylative Sonogashira Reactions -- 1.5.5 Carbonylative C-H Activation Reactions -- 1.5.6 Carbonylative Heck Reactions -- 1.6 Carbonylation of Epoxides -- 1.6.1 Ring‐expansion Carbonylation of Epoxides -- 1.6.2 Hydroformylation and Silylformylation of Epoxides -- 1.6.3 Alternating Copolymerization of Epoxides -- 1.6.4 Alkoxycarbonylation and Aminocarbonylation of Epoxides -- 1.7 Carbonylation of Aldehydes -- 1.7.1 Amidocarbonylations of Aldehydes -- 1.7.2 Hydroformylation and Silylformylation of Aldehydes -- 1.7.3 Hetero Pauson-Khand Reactions of Aldehydes -- 1.7.4 Reactions of Aldehydes with Acylanions -- 1.7.5 Miscellaneous of Aldehydes -- 1.8 Oxidative Carbonylation Reaction.
1.8.1 Oxidative Carbonylation of Alkenes -- 1.8.2 Oxidative Carbonylation of Alkynes -- 1.8.3 Oxidative Carbonylation of Organometallic Reagents -- 1.8.4 Oxidative Carbonylation of Arenes -- 1.8.5 Oxidative Carbonylation of Amines -- 1.9 Other Reactions -- 1.9.1 Reactions of Diazoalkanes with Carbon Monoxide -- 1.9.2 Reaction of C-NO2 with CO -- Chapter 2 Carbon Dioxide -- 2.1 Synthesis of Urea Derivatives -- 2.1.1 Metal‐free Catalyst Systems -- 2.1.2 Ph3SbO as Catalyst -- 2.1.3 Pd Catalyst Systems -- 2.1.4 Ionic Liquids as Catalyst -- 2.1.5 CeO2 as Catalyst -- 2.2 Synthesis of Carbamate Derivatives -- 2.2.1 Ru Catalyst Systems -- 2.2.2 Sn or Ni Catalyst Systems -- 2.2.3 Zeolite as Catalyst -- 2.2.4 Other Catalyst Systems -- 2.3 Synthesis of Carboxyl Acid Derivatives -- 2.4 Cycloaddition of Epoxide with CO2 -- 2.4.1 Oxides Catalysts -- 2.4.2 Zeolite Catalysts -- 2.4.3 Supported Nanoparticle and Lewis Acid Catalysts -- 2.4.4 Carbon Catalysts -- 2.4.5 Salen, Porphyrins, and Phthalocyanines Catalysts -- 2.4.6 Ionic Liquid Catalysts -- 2.4.7 Metal-Organic Framework (MOF) Catalysts -- 2.4.8 Bifunctional Catalysts -- 2.4.9 Other Catalysts -- 2.5 Reaction of Polyalcohols/Olefins with CO2 -- 2.6 Formylation of Amines with CO2 -- 2.7 Reactions of Propargyl Alcohols/Propargyl Amines with CO2 -- 2.8 Other Reactions -- 2.8.1 Reactions of Aromatic Halides with CO2 -- 2.8.2 Reactions of 2‐Aminobenzonitriles with CO2 -- Chapter 3 Other C1 Carbonyl Molecules -- 3.1 Formaldehyde (HCHO) -- 3.1.1 Carbonylation of Halides with HCHO -- 3.1.2 Carbonylation of Olefins with HCHO -- 3.1.3 Carbonylation of Alkynes with HCHO -- 3.2 Formic Acid (HCOOH) -- 3.2.1 Hydroxycarbonylation of Arenes with Formic Acid -- 3.2.2 Carbonylation of Alkenes with Formic Acid -- 3.2.3 Carbonylation of Alkynes with Formic Acid -- 3.2.4 N‐Formylation Reactions with Formic Acid.
3.2.4.1 Metal Oxides Catalysts -- 3.2.4.2 Brønsted Acidic as Catalyst -- 3.2.4.3 Amberlite IR‐120 Resins as Catalysts -- 3.2.4.4 Magnetic Catalysts -- 3.2.4.5 Zeolite as Catalyst -- 3.2.4.6 Ionic Liquids (ILs) as Catalyst -- 3.2.4.7 Other Catalysts -- 3.2.5 Carbonylation of C-X with Formic Acid -- 3.2.6 Other Reactions -- Chapter 4 CO Surrogates -- 4.1 Carbonyl Metal -- 4.2 Formates -- 4.3 Formamides -- 4.4 Formic Anhydride -- 4.5 Silacarboxylic Acid -- 4.6 N‐Formylsaccharin -- 4.7 Acyl Chloride -- 4.8 In Situ Generated Carbonyl Source -- 4.8.1 Methanol -- 4.8.2 Glycerol -- 4.8.3 Aldoses -- 4.8.4 Epoxide -- 4.8.5 Chloroform -- 4.8.5.1 Pd‐catalyzed Carbonylation Reactions -- 4.8.5.2 Fe‐Catalyzed Carbonylation Reactions -- 4.8.5.3 Zn‐Catalyzed Carbonylation Reactions -- Part I References -- Part II Carbonyl Compounds as Catalysts -- Chapter 5 Acid‐Catalyzed Reactions with -CO2H -- 5.1 Carboxylic Acid Molecules Catalyzed Reactions -- 5.1.1 Hydrolysis/Aminolysis/Ethanolysis Reactions -- 5.1.2 Mutarotation of 2,3,4,6‐Tetramethyl‐d‐glucose (TM‐G) -- 5.1.3 Depolymerization of Polyoxymethylenes -- 5.1.4 Elimination Reactions -- 5.1.5 Hydrogen-Deuterium Exchange Reactions -- 5.1.6 Reduction Reactions -- 5.1.7 Decomposition of Diazodiphenylmethane -- 5.1.8 Amino-Imino Tautomerism Reactions -- 5.1.9 Aldol Reaction -- 5.1.10 Friedel-Crafts Reaction -- 5.1.11 Hydrogen Shifts Reaction -- 5.1.12 Cyclization Reaction -- 5.1.13 Hydroboration Reaction -- 5.1.14 Trifluoromethylation Reaction -- 5.2 Carbon Material-Catalyzed Reactions -- 5.2.1 Reduction of Nitric Oxide -- 5.2.2 Oxidative Coupling of Amines to Imines -- 5.2.3 Depolymerization of Cellulose and Lignocellulose -- 5.2.4 Nitrobenzene Reduction Reaction and Beckmann Rearrangement Reaction -- 5.2.5 Ring‐Opening Reaction of Styrene Oxide -- Chapter 6 Reactions via Carbonyl and Hydroxyl Groups Recycling.
6.1 Carbon‐Catalyzed Selective Oxidation Reactions -- 6.1.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.1.2 Oxidative Dehydrogenation of n‐Butane -- 6.1.3 Oxidative Dehydrogenation of Isobutane -- 6.1.4 Oxidative Dehydrogenation of Propane -- 6.2 Polymer‐Catalyzed Selective Oxidation Reactions -- 6.2.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.2.2 Oxidative Dehydrogenation of Heterocyclic Compounds -- 6.3 Aldehyde/Ketone‐Catalyzed Borrowing‐Hydrogen Reactions -- 6.3.1 Dehydrative β‐C‐Alkylation Reaction of Methyl Carbinols with Alcohols -- 6.3.2 Dehydrative α‐Alkylation Reactions of Ketones with Alcohols -- 6.3.3 Dehydrative Alkylation Reactions of Fluorenes with Alcohols -- 6.3.4 Dehydrative N‐Alkylation Reactions of Amines with Alcohols -- 6.4 Carbon‐Catalyzed Borrowing‐Hydrogen Reactions -- Part II References -- Part III The Synthetic Applications of Carbonyl Compounds -- Chapter 7 Synthesis of Functional Molecules -- 7.1 Reduction of Carbonyl Compounds -- 7.1.1 Aldehydes and Ketones to Alcohol -- 7.1.2 Acids to the Alcohols and Aldehydes -- 7.1.2.1 To Alcohols -- 7.1.2.2 To Aldehydes -- 7.1.3 Ester to Alcohols and Ethers -- 7.1.3.1 To Alcohols -- 7.1.3.2 To Ethers -- 7.1.4 Amides to Amines -- 7.1.5 Clemmensen Reduction -- 7.1.6 Wolff-Kishner Reduction -- 7.2 Nucleophilic Addition Reactions of Aldehydes and Ketones -- 7.2.1 Carbon Nucleophiles -- 7.2.1.1 Grignard Reagent and Other Organometallic Reagents -- 7.2.1.2 Reformatsky Reaction -- 7.2.1.3 Benzoin Condensation -- 7.2.1.4 CN Group -- 7.2.1.5 Aromatic and Aliphatic C H Bond -- 7.2.2 Nitrogen Nucleophiles -- 7.2.3 Oxygen Nucleophiles -- 7.2.3.1 H2O as a Nucleophile -- 7.2.3.2 ROH as a Nucleophile -- 7.3 Addition Elimination Reactions of Aldehydes and Ketones -- 7.3.1 Aldol Reaction -- 7.3.2 Perkin Reaction -- 7.3.3 Knoevenagel Condensation -- 7.4 Oxidation of Aldehydes and Ketones.
7.4.1 Baeyer-Villiger Oxidation -- 7.4.2 To Acid -- 7.5 Wittig Reaction -- 7.6 Reductive Amination Reaction -- 7.6.1 Homogeneous Catalyst System -- 7.6.2 Heterogeneous Catalyst System -- 7.7 Hydroboration/Hydrophosphonylation/Hydrosilylation/Hydroacylation of Aldehydes and Ketones -- 7.7.1 Hydroboration -- 7.7.2 Hydrophosphonylation -- 7.7.3 Hydrosilylation Reactions -- 7.7.4 Hydroacylation Reactions -- 7.8 Oxidative Cross‐Coupling Reaction of Aldehydes -- 7.8.1 Homogeneous Catalyst System -- 7.8.2 Heterogeneous Catalyst System -- 7.9 Reductive Coupling Reactions of Aldehydes -- 7.10 Reaction of Acids as Starting Materials -- 7.10.1 Esterification Reactions -- 7.10.2 Amidation Reactions -- 7.10.3 Decarboxylation Coupling Reactions -- 7.11 Reaction of Esters as Starting Materials -- 7.11.1 Hydrolysis Reaction -- 7.11.2 Transesterification Reaction -- 7.11.3 Aminolysis Reaction -- 7.12 Reaction of Amides as Starting Materials -- 7.12.1 Hydrolysis Reaction -- 7.12.2 Alcoholysis Reaction -- Chapter 8 Synthesis of Functional Materials -- 8.1 Polyamides -- 8.1.1 Aliphatic Polyamides -- 8.1.2 Aromatic Polyamides -- 8.1.3 Long‐Chain Semiaromatic Polyamides -- 8.2 Phenol Formaldehyde Resins -- 8.2.1 Novolac Resins -- 8.2.2 Resole Resins -- 8.3 Polyurethanes -- 8.4 Polyesters -- Part III References -- Chapter 9 Conclusion and Perspectives -- 9.1 Conclusion -- 9.2 Perspectives -- Index -- EULA.
Record Nr. UNINA-9910555179403321
Shi Feng  
Weinheim, Germany : , : Wiley-VCH, , [2022]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Carbonyl compounds : reactants, catalysts and products / / Feng Shi, Hongli Wang, Xingchao Dai
Carbonyl compounds : reactants, catalysts and products / / Feng Shi, Hongli Wang, Xingchao Dai
Autore Shi Feng
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2022]
Descrizione fisica 1 online resource (375 pages)
Disciplina 547.036
Soggetto topico Carbonyl compounds
ISBN 3-527-82561-4
3-527-82562-2
3-527-82560-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Copyright -- Contents -- Preface -- Part I Carbonyl Molecules as Reactants -- Chapter 1 Carbon Monoxide -- 1.1 Hydroformylation of Alkenes and Alkynes -- 1.1.1 Co Catalysts -- 1.1.2 Rh Catalysts -- 1.1.3 Au Catalysts -- 1.1.4 Ligand‐Modified Heterogeneous Catalysts -- 1.1.5 Single‐Atom Catalysts -- 1.2 Hydroxy-, Alkoxy-, and Aminocarbonylation of Alkenes and Alkynes -- 1.2.1 Hydroxycarbonylation of Alkenes -- 1.2.2 Hydroxycarbonylation of Alkynes -- 1.2.3 Alkoxycarbonylation of Alkenes -- 1.2.4 Alkoxycarbonylation of Alkynes -- 1.2.5 Aminocarbonylation of Alkenes -- 1.2.6 Aminocarbonylation of Alkynes -- 1.3 The Pauson-Khand Reaction -- 1.3.1 The Catalytic Pauson-Khand Reaction -- 1.3.2 Stereoselective Pauson-Khand Reactions -- 1.3.3 Pauson-Khand Transfer Carbonylation Reactions -- 1.4 Synthesis of Acetic Acid -- 1.4.1 Process Considerations -- 1.4.2 Rhodium‐Catalyzed Carbonylation -- 1.4.3 Iridium‐Catalyzed Carbonylation -- 1.5 Carbonylation of C X Bonds -- 1.5.1 Hydroxy‐, Alkoxy‐, and Aminocarbonylations of C X Bonds -- 1.5.2 Reductive Carbonylations -- 1.5.3 Carbonylative Coupling Reactions with Organometallic Reagents -- 1.5.4 Carbonylative Sonogashira Reactions -- 1.5.5 Carbonylative C-H Activation Reactions -- 1.5.6 Carbonylative Heck Reactions -- 1.6 Carbonylation of Epoxides -- 1.6.1 Ring‐expansion Carbonylation of Epoxides -- 1.6.2 Hydroformylation and Silylformylation of Epoxides -- 1.6.3 Alternating Copolymerization of Epoxides -- 1.6.4 Alkoxycarbonylation and Aminocarbonylation of Epoxides -- 1.7 Carbonylation of Aldehydes -- 1.7.1 Amidocarbonylations of Aldehydes -- 1.7.2 Hydroformylation and Silylformylation of Aldehydes -- 1.7.3 Hetero Pauson-Khand Reactions of Aldehydes -- 1.7.4 Reactions of Aldehydes with Acylanions -- 1.7.5 Miscellaneous of Aldehydes -- 1.8 Oxidative Carbonylation Reaction.
1.8.1 Oxidative Carbonylation of Alkenes -- 1.8.2 Oxidative Carbonylation of Alkynes -- 1.8.3 Oxidative Carbonylation of Organometallic Reagents -- 1.8.4 Oxidative Carbonylation of Arenes -- 1.8.5 Oxidative Carbonylation of Amines -- 1.9 Other Reactions -- 1.9.1 Reactions of Diazoalkanes with Carbon Monoxide -- 1.9.2 Reaction of C-NO2 with CO -- Chapter 2 Carbon Dioxide -- 2.1 Synthesis of Urea Derivatives -- 2.1.1 Metal‐free Catalyst Systems -- 2.1.2 Ph3SbO as Catalyst -- 2.1.3 Pd Catalyst Systems -- 2.1.4 Ionic Liquids as Catalyst -- 2.1.5 CeO2 as Catalyst -- 2.2 Synthesis of Carbamate Derivatives -- 2.2.1 Ru Catalyst Systems -- 2.2.2 Sn or Ni Catalyst Systems -- 2.2.3 Zeolite as Catalyst -- 2.2.4 Other Catalyst Systems -- 2.3 Synthesis of Carboxyl Acid Derivatives -- 2.4 Cycloaddition of Epoxide with CO2 -- 2.4.1 Oxides Catalysts -- 2.4.2 Zeolite Catalysts -- 2.4.3 Supported Nanoparticle and Lewis Acid Catalysts -- 2.4.4 Carbon Catalysts -- 2.4.5 Salen, Porphyrins, and Phthalocyanines Catalysts -- 2.4.6 Ionic Liquid Catalysts -- 2.4.7 Metal-Organic Framework (MOF) Catalysts -- 2.4.8 Bifunctional Catalysts -- 2.4.9 Other Catalysts -- 2.5 Reaction of Polyalcohols/Olefins with CO2 -- 2.6 Formylation of Amines with CO2 -- 2.7 Reactions of Propargyl Alcohols/Propargyl Amines with CO2 -- 2.8 Other Reactions -- 2.8.1 Reactions of Aromatic Halides with CO2 -- 2.8.2 Reactions of 2‐Aminobenzonitriles with CO2 -- Chapter 3 Other C1 Carbonyl Molecules -- 3.1 Formaldehyde (HCHO) -- 3.1.1 Carbonylation of Halides with HCHO -- 3.1.2 Carbonylation of Olefins with HCHO -- 3.1.3 Carbonylation of Alkynes with HCHO -- 3.2 Formic Acid (HCOOH) -- 3.2.1 Hydroxycarbonylation of Arenes with Formic Acid -- 3.2.2 Carbonylation of Alkenes with Formic Acid -- 3.2.3 Carbonylation of Alkynes with Formic Acid -- 3.2.4 N‐Formylation Reactions with Formic Acid.
3.2.4.1 Metal Oxides Catalysts -- 3.2.4.2 Brønsted Acidic as Catalyst -- 3.2.4.3 Amberlite IR‐120 Resins as Catalysts -- 3.2.4.4 Magnetic Catalysts -- 3.2.4.5 Zeolite as Catalyst -- 3.2.4.6 Ionic Liquids (ILs) as Catalyst -- 3.2.4.7 Other Catalysts -- 3.2.5 Carbonylation of C-X with Formic Acid -- 3.2.6 Other Reactions -- Chapter 4 CO Surrogates -- 4.1 Carbonyl Metal -- 4.2 Formates -- 4.3 Formamides -- 4.4 Formic Anhydride -- 4.5 Silacarboxylic Acid -- 4.6 N‐Formylsaccharin -- 4.7 Acyl Chloride -- 4.8 In Situ Generated Carbonyl Source -- 4.8.1 Methanol -- 4.8.2 Glycerol -- 4.8.3 Aldoses -- 4.8.4 Epoxide -- 4.8.5 Chloroform -- 4.8.5.1 Pd‐catalyzed Carbonylation Reactions -- 4.8.5.2 Fe‐Catalyzed Carbonylation Reactions -- 4.8.5.3 Zn‐Catalyzed Carbonylation Reactions -- Part I References -- Part II Carbonyl Compounds as Catalysts -- Chapter 5 Acid‐Catalyzed Reactions with -CO2H -- 5.1 Carboxylic Acid Molecules Catalyzed Reactions -- 5.1.1 Hydrolysis/Aminolysis/Ethanolysis Reactions -- 5.1.2 Mutarotation of 2,3,4,6‐Tetramethyl‐d‐glucose (TM‐G) -- 5.1.3 Depolymerization of Polyoxymethylenes -- 5.1.4 Elimination Reactions -- 5.1.5 Hydrogen-Deuterium Exchange Reactions -- 5.1.6 Reduction Reactions -- 5.1.7 Decomposition of Diazodiphenylmethane -- 5.1.8 Amino-Imino Tautomerism Reactions -- 5.1.9 Aldol Reaction -- 5.1.10 Friedel-Crafts Reaction -- 5.1.11 Hydrogen Shifts Reaction -- 5.1.12 Cyclization Reaction -- 5.1.13 Hydroboration Reaction -- 5.1.14 Trifluoromethylation Reaction -- 5.2 Carbon Material-Catalyzed Reactions -- 5.2.1 Reduction of Nitric Oxide -- 5.2.2 Oxidative Coupling of Amines to Imines -- 5.2.3 Depolymerization of Cellulose and Lignocellulose -- 5.2.4 Nitrobenzene Reduction Reaction and Beckmann Rearrangement Reaction -- 5.2.5 Ring‐Opening Reaction of Styrene Oxide -- Chapter 6 Reactions via Carbonyl and Hydroxyl Groups Recycling.
6.1 Carbon‐Catalyzed Selective Oxidation Reactions -- 6.1.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.1.2 Oxidative Dehydrogenation of n‐Butane -- 6.1.3 Oxidative Dehydrogenation of Isobutane -- 6.1.4 Oxidative Dehydrogenation of Propane -- 6.2 Polymer‐Catalyzed Selective Oxidation Reactions -- 6.2.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.2.2 Oxidative Dehydrogenation of Heterocyclic Compounds -- 6.3 Aldehyde/Ketone‐Catalyzed Borrowing‐Hydrogen Reactions -- 6.3.1 Dehydrative β‐C‐Alkylation Reaction of Methyl Carbinols with Alcohols -- 6.3.2 Dehydrative α‐Alkylation Reactions of Ketones with Alcohols -- 6.3.3 Dehydrative Alkylation Reactions of Fluorenes with Alcohols -- 6.3.4 Dehydrative N‐Alkylation Reactions of Amines with Alcohols -- 6.4 Carbon‐Catalyzed Borrowing‐Hydrogen Reactions -- Part II References -- Part III The Synthetic Applications of Carbonyl Compounds -- Chapter 7 Synthesis of Functional Molecules -- 7.1 Reduction of Carbonyl Compounds -- 7.1.1 Aldehydes and Ketones to Alcohol -- 7.1.2 Acids to the Alcohols and Aldehydes -- 7.1.2.1 To Alcohols -- 7.1.2.2 To Aldehydes -- 7.1.3 Ester to Alcohols and Ethers -- 7.1.3.1 To Alcohols -- 7.1.3.2 To Ethers -- 7.1.4 Amides to Amines -- 7.1.5 Clemmensen Reduction -- 7.1.6 Wolff-Kishner Reduction -- 7.2 Nucleophilic Addition Reactions of Aldehydes and Ketones -- 7.2.1 Carbon Nucleophiles -- 7.2.1.1 Grignard Reagent and Other Organometallic Reagents -- 7.2.1.2 Reformatsky Reaction -- 7.2.1.3 Benzoin Condensation -- 7.2.1.4 CN Group -- 7.2.1.5 Aromatic and Aliphatic C H Bond -- 7.2.2 Nitrogen Nucleophiles -- 7.2.3 Oxygen Nucleophiles -- 7.2.3.1 H2O as a Nucleophile -- 7.2.3.2 ROH as a Nucleophile -- 7.3 Addition Elimination Reactions of Aldehydes and Ketones -- 7.3.1 Aldol Reaction -- 7.3.2 Perkin Reaction -- 7.3.3 Knoevenagel Condensation -- 7.4 Oxidation of Aldehydes and Ketones.
7.4.1 Baeyer-Villiger Oxidation -- 7.4.2 To Acid -- 7.5 Wittig Reaction -- 7.6 Reductive Amination Reaction -- 7.6.1 Homogeneous Catalyst System -- 7.6.2 Heterogeneous Catalyst System -- 7.7 Hydroboration/Hydrophosphonylation/Hydrosilylation/Hydroacylation of Aldehydes and Ketones -- 7.7.1 Hydroboration -- 7.7.2 Hydrophosphonylation -- 7.7.3 Hydrosilylation Reactions -- 7.7.4 Hydroacylation Reactions -- 7.8 Oxidative Cross‐Coupling Reaction of Aldehydes -- 7.8.1 Homogeneous Catalyst System -- 7.8.2 Heterogeneous Catalyst System -- 7.9 Reductive Coupling Reactions of Aldehydes -- 7.10 Reaction of Acids as Starting Materials -- 7.10.1 Esterification Reactions -- 7.10.2 Amidation Reactions -- 7.10.3 Decarboxylation Coupling Reactions -- 7.11 Reaction of Esters as Starting Materials -- 7.11.1 Hydrolysis Reaction -- 7.11.2 Transesterification Reaction -- 7.11.3 Aminolysis Reaction -- 7.12 Reaction of Amides as Starting Materials -- 7.12.1 Hydrolysis Reaction -- 7.12.2 Alcoholysis Reaction -- Chapter 8 Synthesis of Functional Materials -- 8.1 Polyamides -- 8.1.1 Aliphatic Polyamides -- 8.1.2 Aromatic Polyamides -- 8.1.3 Long‐Chain Semiaromatic Polyamides -- 8.2 Phenol Formaldehyde Resins -- 8.2.1 Novolac Resins -- 8.2.2 Resole Resins -- 8.3 Polyurethanes -- 8.4 Polyesters -- Part III References -- Chapter 9 Conclusion and Perspectives -- 9.1 Conclusion -- 9.2 Perspectives -- Index -- EULA.
Record Nr. UNINA-9910830037203321
Shi Feng  
Weinheim, Germany : , : Wiley-VCH, , [2022]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Chemistry of Enones and Related Compounds
Chemistry of Enones and Related Compounds
Autore Patai Saul E
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Descrizione fisica 1 online resource (xvi, 1267 pages) : illustrations
Disciplina 547.036
Collana PATAI'S Chemistry of Functional Groups
Soggetto topico Carbonyl compounds
ISBN 0-470-77883-0
0-470-77221-2
0-470-77232-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto [pt. 1.] General and theoretical / A.Y. Meyer -- Structural chemistry of enones / B. Schweizer -- Conformations, chiroptical and related spectral properties of enones / J. Gawronksi -- Thermochemistry of enones and related species / J.F. Liebman and R.M. Pollack -- NMR spectroscopy of enones / H.E. Gottlieb -- The chemistry of ionized enones in the gas phase / F. Tureček -- Synthesis of enones / C. Thebtaranonth and Y. Thebtaranonth -- Synthetic uses of enones / G.V. Boyd -- Acid-base behaviour of enones / R.I. Zalewski -- Nucleophilic attacks on enones / D. Duval and S. Géribaldi -- Additions of electrons or radicals to [alpha], [beta]-unsaturated enones / G.A. Russell -- The reaction of enones with electrophiles / K. Müllen and P. Wolf -- Chemical and enzymatic conversion of [beta], [gamma]-enomes to [alpha], [beta]-enones / R.M. Pollack, P.L. Bounds and C.L. Bevins -- [pt. 2.] Enone electrochemistry / R.D. Little and M.M. Baizer -- The photochemistry of enones / D.I. Schuster -- Radiation chemistry of enones / P. Neta and M. Dizdaroglu -- The oxygenation of enones / A.A. Frimer -- The reduction of [alpha], [beta]-unsaturated carbonyl compounds / E. Keinan and N. Greenspoon -- Organometallic derivatives of [alpha], [beta]-unsaturated enones / J.A.S. Howell -- Dienols (enolization of enones) / B. Capon -- Asymmetric synthesis with chiral enones / M.R. Peel and C.R. Johnson -- Dimerization and polymerization of enones in the fluid and solid states / C.R. Theocharis.
Record Nr. UNINA-9910830853203321
Patai Saul E  
[Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Chemistry of Enones and Related Compounds
Chemistry of Enones and Related Compounds
Autore Patai Saul E
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Descrizione fisica 1 online resource (xvi, 1267 pages) : illustrations
Disciplina 547.036
Collana PATAI'S Chemistry of Functional Groups
Soggetto topico Carbonyl compounds
ISBN 0-470-77883-0
0-470-77221-2
0-470-77232-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto [pt. 1.] General and theoretical / A.Y. Meyer -- Structural chemistry of enones / B. Schweizer -- Conformations, chiroptical and related spectral properties of enones / J. Gawronksi -- Thermochemistry of enones and related species / J.F. Liebman and R.M. Pollack -- NMR spectroscopy of enones / H.E. Gottlieb -- The chemistry of ionized enones in the gas phase / F. Tureček -- Synthesis of enones / C. Thebtaranonth and Y. Thebtaranonth -- Synthetic uses of enones / G.V. Boyd -- Acid-base behaviour of enones / R.I. Zalewski -- Nucleophilic attacks on enones / D. Duval and S. Géribaldi -- Additions of electrons or radicals to [alpha], [beta]-unsaturated enones / G.A. Russell -- The reaction of enones with electrophiles / K. Müllen and P. Wolf -- Chemical and enzymatic conversion of [beta], [gamma]-enomes to [alpha], [beta]-enones / R.M. Pollack, P.L. Bounds and C.L. Bevins -- [pt. 2.] Enone electrochemistry / R.D. Little and M.M. Baizer -- The photochemistry of enones / D.I. Schuster -- Radiation chemistry of enones / P. Neta and M. Dizdaroglu -- The oxygenation of enones / A.A. Frimer -- The reduction of [alpha], [beta]-unsaturated carbonyl compounds / E. Keinan and N. Greenspoon -- Organometallic derivatives of [alpha], [beta]-unsaturated enones / J.A.S. Howell -- Dienols (enolization of enones) / B. Capon -- Asymmetric synthesis with chiral enones / M.R. Peel and C.R. Johnson -- Dimerization and polymerization of enones in the fluid and solid states / C.R. Theocharis.
Record Nr. UNINA-9910841157803321
Patai Saul E  
[Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
The Chemistry of Enones. Vol. 2
The Chemistry of Enones. Vol. 2
Autore Patai Saul E
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Descrizione fisica 1 online resource (xvi, 1267 pages) : illustrations
Disciplina 547.036
Collana PATAI'S Chemistry of Functional Groups
Soggetto topico Carbonyl compounds
Functional groups
ISBN 0-470-77884-9
0-470-77222-0
0-470-77233-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto [pt. 1.] General and theoretical / A.Y. Meyer -- Structural chemistry of enones / B. Schweizer -- Conformations, chiroptical and related spectral properties of enones / J. Gawronksi -- Thermochemistry of enones and related species / J.F. Liebman and R.M. Pollack -- NMR spectroscopy of enones / H.E. Gottlieb -- The chemistry of ionized enones in the gas phase / F. Tureček -- Synthesis of enones / C. Thebtaranonth and Y. Thebtaranonth -- Synthetic uses of enones / G.V. Boyd -- Acid-base behaviour of enones / R.I. Zalewski -- Nucleophilic attacks on enones / D. Duval and S. Géribaldi -- Additions of electrons or radicals to [alpha], [beta]-unsaturated enones / G.A. Russell -- The reaction of enones with electrophiles / K. Müllen and P. Wolf -- Chemical and enzymatic conversion of [beta], [gamma]-enomes to [alpha], [beta]-enones / R.M. Pollack, P.L. Bounds and C.L. Bevins -- [pt. 2.] Enone electrochemistry / R.D. Little and M.M. Baizer -- The photochemistry of enones / D.I. Schuster -- Radiation chemistry of enones / P. Neta and M. Dizdaroglu -- The oxygenation of enones / A.A. Frimer -- The reduction of [alpha], [beta]-unsaturated carbonyl compounds / E. Keinan and N. Greenspoon -- Organometallic derivatives of [alpha], [beta]-unsaturated enones / J.A.S. Howell -- Dienols (enolization of enones) / B. Capon -- Asymmetric synthesis with chiral enones / M.R. Peel and C.R. Johnson -- Dimerization and polymerization of enones in the fluid and solid states / C.R. Theocharis.
Record Nr. UNINA-9910829971303321
Patai Saul E  
[Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
The Chemistry of Enones. Vol. 2
The Chemistry of Enones. Vol. 2
Autore Patai Saul E
Pubbl/distr/stampa [Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Descrizione fisica 1 online resource (xvi, 1267 pages) : illustrations
Disciplina 547.036
Collana PATAI'S Chemistry of Functional Groups
Soggetto topico Carbonyl compounds
Functional groups
ISBN 0-470-77884-9
0-470-77222-0
0-470-77233-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto [pt. 1.] General and theoretical / A.Y. Meyer -- Structural chemistry of enones / B. Schweizer -- Conformations, chiroptical and related spectral properties of enones / J. Gawronksi -- Thermochemistry of enones and related species / J.F. Liebman and R.M. Pollack -- NMR spectroscopy of enones / H.E. Gottlieb -- The chemistry of ionized enones in the gas phase / F. Tureček -- Synthesis of enones / C. Thebtaranonth and Y. Thebtaranonth -- Synthetic uses of enones / G.V. Boyd -- Acid-base behaviour of enones / R.I. Zalewski -- Nucleophilic attacks on enones / D. Duval and S. Géribaldi -- Additions of electrons or radicals to [alpha], [beta]-unsaturated enones / G.A. Russell -- The reaction of enones with electrophiles / K. Müllen and P. Wolf -- Chemical and enzymatic conversion of [beta], [gamma]-enomes to [alpha], [beta]-enones / R.M. Pollack, P.L. Bounds and C.L. Bevins -- [pt. 2.] Enone electrochemistry / R.D. Little and M.M. Baizer -- The photochemistry of enones / D.I. Schuster -- Radiation chemistry of enones / P. Neta and M. Dizdaroglu -- The oxygenation of enones / A.A. Frimer -- The reduction of [alpha], [beta]-unsaturated carbonyl compounds / E. Keinan and N. Greenspoon -- Organometallic derivatives of [alpha], [beta]-unsaturated enones / J.A.S. Howell -- Dienols (enolization of enones) / B. Capon -- Asymmetric synthesis with chiral enones / M.R. Peel and C.R. Johnson -- Dimerization and polymerization of enones in the fluid and solid states / C.R. Theocharis.
Record Nr. UNINA-9910841432303321
Patai Saul E  
[Place of publication not identified], : John Wiley & Sons Incorporated, 1989
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Autore Tidwell Thomas T. <1939->
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2006
Descrizione fisica 1 online resource (672 p.)
Disciplina 547.036
547.436
547/.436
Soggetto topico Ketenes
Soggetto genere / forma Electronic books.
ISBN 1-280-28821-3
9786610288212
0-470-36177-8
0-471-76767-0
0-471-76766-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto KETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References
2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl Halides and Activated Acids; References
3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References
3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes
4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References
4.2 Nitrogen-Substituted Ketenes
Record Nr. UNINA-9910143557903321
Tidwell Thomas T. <1939->  
Hoboken, N.J., : Wiley-Interscience, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Autore Tidwell Thomas T. <1939->
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2006
Descrizione fisica 1 online resource (672 p.)
Disciplina 547.036
547.436
547/.436
Soggetto topico Ketenes
ISBN 1-280-28821-3
9786610288212
0-470-36177-8
0-471-76767-0
0-471-76766-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto KETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References
2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl Halides and Activated Acids; References
3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References
3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes
4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References
4.2 Nitrogen-Substituted Ketenes
Record Nr. UNINA-9910830727603321
Tidwell Thomas T. <1939->  
Hoboken, N.J., : Wiley-Interscience, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Ketenes II [[electronic resource] /] / Thomas T. Tidwell
Autore Tidwell Thomas T. <1939->
Edizione [2nd ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2006
Descrizione fisica 1 online resource (672 p.)
Disciplina 547.036
547.436
547/.436
Soggetto topico Ketenes
ISBN 1-280-28821-3
9786610288212
0-470-36177-8
0-471-76767-0
0-471-76766-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto KETENES II; Contents; Preface; Introduction; References; 1 Structure, Bonding, and Thermochemistry of Ketenes; 1.1 Theoretical and Computational Studies of Ketenes; 1.1.1 Molecular and Electronic Structure and Energy; References; 1.1.2 Theoretical and Computational Studies of Ketene Reactions; References; 1.1.3 Substituent Effects on Ketenes; References; 1.2 Molecular Structure Determinations; References; 1.3 Thermochemistry of Ketenes; References; 2 Spectroscopy and Physical Properties of Ketenes; 2.1 Nuclear Magnetic Resonance Spectroscopy; References
2.2 Ultraviolet Spectra, Photoelectron Spectra, and Chiroptical PropertiesReferences; 2.3 Infrared Spectra and Raman Spectra; References; 2.4 Dipole Moments; References; 2.5 Mass Spectrometry and Gas Phase Ion Chemistry; References; 3 Preparation of Ketenes; 3.1 Ketenes from Ketene Dimers; References; 3.2 Ketenes from Carboxylic Acids and their Derivatives; 3.2.1 Ketenes from Carboxylic Acids and Anhydrides; 3.2.1.1 Ketenes from Carboxylic Acids; References; 3.2.1.2 Ketenes from Acid Anhydrides; References; 3.2.2 Ketenes from Acyl Halides and Activated Acids; References
3.2.3 Ketenes from Esters3.2.3.1 Ketenes from Ester Enolates; 3.2.3.2 Ketenes by Ester Pyrolysis; References; 3.2.4 Ketenes by Dehalogenation of a-Halo Carboxylic Acid Derivatives; References; 3.3 Ketenes from Diazo Ketones (Wolff Rearrangements); 3.3.1 Thermal Wolff Rearrangement; 3.3.2 Catalyzed Wolff Rearrangement; 3.3.3 Photochemical Wolff Rearrangement; 3.3.4 Other Routes to Ketocarbene Rearrangements; References; 3.4 Ketenes by Photochemical and Thermolytic Methods; 3.4.1 Ketenes from Cyclobutanones and Cyclobutenones; References
3.4.2 Ketenes from Photolysis of Cycloalkanones and EnonesReferences; 3.4.3 Ketenes from Cyclohexadienones and other Cycloalkenones; References; 3.4.4 Ketenes from Dioxinones; References; 3.4.5 Ketenes by Thermolysis of Alkynyl Ethers; References; 3.4.6 Ketenes from other Thermolytic and Photochemical Routes; References; 3.5 Ketenes from Metal Carbene Complexes; References; 3.6 Ketene Formation from Cations and Free Radicals; References; 3.7 Ketenes from Oxidation of Alkynes; References; 3.8 Other Routes to Ketenes; References; 4 Types of Ketenes; 4.1 Carbon-Substituted Ketenes
4.1.1 AlkylketenesReferences; 4.1.2 Alkenylketenes; References; 4.1.3 Alkynyl- and Cyanoketenes; References; 4.1.4 Aryl- and Heteroarylketenes; References; 4.1.5 Cyclopropyl-, Cyclopropenyl-, and Oxiranylketenes; References; 4.1.6 Acylketenes; References; 4.1.7 Imidoylketenes; References; 4.1.8 Cumulene-Substituted Ketenes; References; 4.1.9 Ketenes with Charged, Radical, or Carbenic Side Chains; References; 4.1.10 Fulvenones and Cumulenones; 4.1.10.1 Triafulvenones; 4.1.10.2 Pentafulvenones; References; 4.1.11 Oxoquinone Methides, Oxoxylylenes, and Related Species; References
4.2 Nitrogen-Substituted Ketenes
Record Nr. UNINA-9910841283203321
Tidwell Thomas T. <1939->  
Hoboken, N.J., : Wiley-Interscience, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui