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Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich
| Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich |
| Autore | Meijere A. de |
| Edizione | [Second, completely revised and enlarged edition.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (xxii, 2 v. ) : ill. ; |
| Disciplina | 547/.2 |
| Altri autori (Persone) | DiederichFrançois |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| ISBN | 3-527-61953-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Mechanic aspects of metal-catalyzed C, C- and C, X-bond-forming reactions / Antonio M. Echavarren and Diego J. Cárdenas -- Metal-catalyzed cross-coupling reactions of organoboron compounds with organic halides / Norio Miyaura -- Organotin reagents in cross-coupling reactions / Terence N. Mitchell -- Organosilicon compounds in cross-coupling reactions / Scott E. Denmark and Ramzi F. Sweis -- Cross-coupling of organyl halides with alkenes: the Heck reaction / Stefan Bräse and Armin de Meijere -- Cross-coupling reactions to sp carbon atoms / Jeremiah A. Marsden and Michael M. Haley -- Carbometallation reactions / Ilan Marek, Nicka Chinkov, and Daniella Banon-Tenne -- Palladium-catalyzed 1,4-additions to conjugated dienes / Jan-E. Bäckvall -- Cross-coupling reactions via [pi]-allylmetal intermediates / Uli Kazmaier and Matthias Pohlman -- Palladium-catalyzed coupling reactions of propargyl compounds / Jiro Tsuji and Tadakatsu Mandai -- Carbon-carbon bond-forming reactions mediated by organozinc reagents / Paul Knochel, M. Isabel Calaza, and Eike Hupe -- Carbon-carbon bond-forming reactions mediated by organomagnesium reagents / Paul Knochel, Ioannis Sapountzis, and Nina Gommermann -- Palladium-catalyzed aromatic carbon-nitrogen bond formation / Lei Jiang and Stephen L. Buchwald -- The directed ortho-metallation (DoM) cross-coupling nexus, synthetic methodology for the formation of aryl-aryl and aryl-heteroatom-aryl bonds / Eric J.-G. Anctil and Victor Snieckus -- Palladium- or nickel-catalyzed cross-coupling with organometals containing zinc, aluminum, and zirconium: the Negishi coupling / Ei-ichi Negishi, Xingzhong Zeng, Ze Tan, Mingxing Qian, Qian Hu, and Zhihong Huang. |
| Record Nr. | UNINA-9910144278303321 |
Meijere A. de
|
||
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich
| Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich |
| Autore | Meijere A. de |
| Edizione | [Second, completely revised and enlarged edition.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (xxii, 2 v. ) : ill. ; |
| Disciplina | 547/.2 |
| Altri autori (Persone) | DiederichFrançois |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| ISBN | 3-527-61953-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Mechanic aspects of metal-catalyzed C, C- and C, X-bond-forming reactions / Antonio M. Echavarren and Diego J. Cárdenas -- Metal-catalyzed cross-coupling reactions of organoboron compounds with organic halides / Norio Miyaura -- Organotin reagents in cross-coupling reactions / Terence N. Mitchell -- Organosilicon compounds in cross-coupling reactions / Scott E. Denmark and Ramzi F. Sweis -- Cross-coupling of organyl halides with alkenes: the Heck reaction / Stefan Bräse and Armin de Meijere -- Cross-coupling reactions to sp carbon atoms / Jeremiah A. Marsden and Michael M. Haley -- Carbometallation reactions / Ilan Marek, Nicka Chinkov, and Daniella Banon-Tenne -- Palladium-catalyzed 1,4-additions to conjugated dienes / Jan-E. Bäckvall -- Cross-coupling reactions via [pi]-allylmetal intermediates / Uli Kazmaier and Matthias Pohlman -- Palladium-catalyzed coupling reactions of propargyl compounds / Jiro Tsuji and Tadakatsu Mandai -- Carbon-carbon bond-forming reactions mediated by organozinc reagents / Paul Knochel, M. Isabel Calaza, and Eike Hupe -- Carbon-carbon bond-forming reactions mediated by organomagnesium reagents / Paul Knochel, Ioannis Sapountzis, and Nina Gommermann -- Palladium-catalyzed aromatic carbon-nitrogen bond formation / Lei Jiang and Stephen L. Buchwald -- The directed ortho-metallation (DoM) cross-coupling nexus, synthetic methodology for the formation of aryl-aryl and aryl-heteroatom-aryl bonds / Eric J.-G. Anctil and Victor Snieckus -- Palladium- or nickel-catalyzed cross-coupling with organometals containing zinc, aluminum, and zirconium: the Negishi coupling / Ei-ichi Negishi, Xingzhong Zeng, Ze Tan, Mingxing Qian, Qian Hu, and Zhihong Huang. |
| Record Nr. | UNINA-9910830833503321 |
|
Meijere A. de
|
||
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich
| Metal-catalyzed cross-coupling reactions [[electronic resource] /] / edited by Armin de Meijere and François Diederich |
| Autore | Meijere A. de |
| Edizione | [Second, completely revised and enlarged edition.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (xxii, 2 v. ) : ill. ; |
| Disciplina | 547/.2 |
| Altri autori (Persone) | DiederichFrançois |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| ISBN | 3-527-61953-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Mechanic aspects of metal-catalyzed C, C- and C, X-bond-forming reactions / Antonio M. Echavarren and Diego J. Cárdenas -- Metal-catalyzed cross-coupling reactions of organoboron compounds with organic halides / Norio Miyaura -- Organotin reagents in cross-coupling reactions / Terence N. Mitchell -- Organosilicon compounds in cross-coupling reactions / Scott E. Denmark and Ramzi F. Sweis -- Cross-coupling of organyl halides with alkenes: the Heck reaction / Stefan Bräse and Armin de Meijere -- Cross-coupling reactions to sp carbon atoms / Jeremiah A. Marsden and Michael M. Haley -- Carbometallation reactions / Ilan Marek, Nicka Chinkov, and Daniella Banon-Tenne -- Palladium-catalyzed 1,4-additions to conjugated dienes / Jan-E. Bäckvall -- Cross-coupling reactions via [pi]-allylmetal intermediates / Uli Kazmaier and Matthias Pohlman -- Palladium-catalyzed coupling reactions of propargyl compounds / Jiro Tsuji and Tadakatsu Mandai -- Carbon-carbon bond-forming reactions mediated by organozinc reagents / Paul Knochel, M. Isabel Calaza, and Eike Hupe -- Carbon-carbon bond-forming reactions mediated by organomagnesium reagents / Paul Knochel, Ioannis Sapountzis, and Nina Gommermann -- Palladium-catalyzed aromatic carbon-nitrogen bond formation / Lei Jiang and Stephen L. Buchwald -- The directed ortho-metallation (DoM) cross-coupling nexus, synthetic methodology for the formation of aryl-aryl and aryl-heteroatom-aryl bonds / Eric J.-G. Anctil and Victor Snieckus -- Palladium- or nickel-catalyzed cross-coupling with organometals containing zinc, aluminum, and zirconium: the Negishi coupling / Ei-ichi Negishi, Xingzhong Zeng, Ze Tan, Mingxing Qian, Qian Hu, and Zhihong Huang. |
| Record Nr. | UNINA-9910841264603321 |
|
Meijere A. de
|
||
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microwave-assisted organic synthesis : a green chemical approach / / edited by Suresh C. Ameta, PhD, Pinki B. Punjabi, PhD, Rakshit Ameta, PhD, and Chetna Ameta, PhD
| Microwave-assisted organic synthesis : a green chemical approach / / edited by Suresh C. Ameta, PhD, Pinki B. Punjabi, PhD, Rakshit Ameta, PhD, and Chetna Ameta, PhD |
| Pubbl/distr/stampa | Oakville, ON : , : Apple Academic Press, Inc. |
| Descrizione fisica | 1 online resource (400 p.) |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Microwave heating Green chemistry |
| ISBN |
1-77463-355-8
0-429-16249-9 1-77188-039-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | 1. Introduction / Suresh C. Ameta -- 2. Instrumentation / Chetna Ameta, Purnima Dashora, and Ritu Vyas -- 3. Oxidation / Chetna Ameta, Poonam Kumawat, and Abhilasha Tripathi -- 4. Reduction / Sangeeta Kalal, Kiran Meghwal, Meenakshi Joshi, and Pinki B. Punjabi -- 5. Substitution / Meenakshi Shingh Solanki, Shikha Panchal, and Ritu Vyas -- 6. Alkylation and arylation / Sanyogita Sharma, Neelam Kunwar, and Suresh C. Ameta -- 7. Addition / Abhilasha Jain, Priya Parsoya, and Dipti Soni -- 8. Cycloaddition / Abhilasha Jain, K.L. Ameta, Pinki B. Punjabi, and Suresh C. Ameta -- 9. Elimination / Chetna Ameta, Kumudini Bhanat, Arpit Kumar Pathak, and Pinki B. Punjabi -- 10. Condensation / Sanyogita Sharma, Abhilasha Jain, and Rakshit Ameta -- 11. Rearrangement / Paras Tak, Nirmala Jangid, and Pinki B. Punjabi -- 12. Coupling / Surbhi Benjamin, Neelam Kunwar, Kumudini Bhanat, and Suresh C. Ameta -- 13. Synthesis of heterocycles / Chetna Ameta, Rajat Ameta, and Seema Kothari -- 14. Nanomaterials / Surbhi Benjamin, Shweta Sharma, and Rakshit Ameta -- 15. Polymerization / Dipti Soni, Monika Trivedi, and Rakshit Ameta -- 16. Other reactions / Surbhi Benjamin, Paras Tak, and Rakshit Ameta -- 17. Industrial applications / Dipti Soni, Jitendra Vardia, and Rakshit Ameta -- 18. Future prospects / Rakshit Ameta. |
| Record Nr. | UNINA-9910787847003321 |
| Oakville, ON : , : Apple Academic Press, Inc. | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microwave-assisted organic synthesis : a green chemical approach / / edited by Suresh C. Ameta, PhD, Pinki B. Punjabi, PhD, Rakshit Ameta, PhD, and Chetna Ameta, PhD
| Microwave-assisted organic synthesis : a green chemical approach / / edited by Suresh C. Ameta, PhD, Pinki B. Punjabi, PhD, Rakshit Ameta, PhD, and Chetna Ameta, PhD |
| Pubbl/distr/stampa | Oakville, ON : , : Apple Academic Press, Inc. |
| Descrizione fisica | 1 online resource (400 p.) |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Microwave heating Green chemistry |
| ISBN |
1-77463-355-8
0-429-16249-9 1-77188-039-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | 1. Introduction / Suresh C. Ameta -- 2. Instrumentation / Chetna Ameta, Purnima Dashora, and Ritu Vyas -- 3. Oxidation / Chetna Ameta, Poonam Kumawat, and Abhilasha Tripathi -- 4. Reduction / Sangeeta Kalal, Kiran Meghwal, Meenakshi Joshi, and Pinki B. Punjabi -- 5. Substitution / Meenakshi Shingh Solanki, Shikha Panchal, and Ritu Vyas -- 6. Alkylation and arylation / Sanyogita Sharma, Neelam Kunwar, and Suresh C. Ameta -- 7. Addition / Abhilasha Jain, Priya Parsoya, and Dipti Soni -- 8. Cycloaddition / Abhilasha Jain, K.L. Ameta, Pinki B. Punjabi, and Suresh C. Ameta -- 9. Elimination / Chetna Ameta, Kumudini Bhanat, Arpit Kumar Pathak, and Pinki B. Punjabi -- 10. Condensation / Sanyogita Sharma, Abhilasha Jain, and Rakshit Ameta -- 11. Rearrangement / Paras Tak, Nirmala Jangid, and Pinki B. Punjabi -- 12. Coupling / Surbhi Benjamin, Neelam Kunwar, Kumudini Bhanat, and Suresh C. Ameta -- 13. Synthesis of heterocycles / Chetna Ameta, Rajat Ameta, and Seema Kothari -- 14. Nanomaterials / Surbhi Benjamin, Shweta Sharma, and Rakshit Ameta -- 15. Polymerization / Dipti Soni, Monika Trivedi, and Rakshit Ameta -- 16. Other reactions / Surbhi Benjamin, Paras Tak, and Rakshit Ameta -- 17. Industrial applications / Dipti Soni, Jitendra Vardia, and Rakshit Ameta -- 18. Future prospects / Rakshit Ameta. |
| Record Nr. | UNINA-9910821793603321 |
| Oakville, ON : , : Apple Academic Press, Inc. | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich
| The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
| Autore | Oestreich Martin |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (609 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | OestreichMartin |
| Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
| ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
| Record Nr. | UNINA-9910146128703321 |
|
Oestreich Martin
|
||
| Chichester, U.K., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich
| The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
| Autore | Oestreich Martin |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (609 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | OestreichMartin |
| Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
| ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
| Record Nr. | UNINA-9910830440403321 |
|
Oestreich Martin
|
||
| Chichester, U.K., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich
| The Mizoroki-Heck reaction [[electronic resource] /] / edited by Martin Oestreich |
| Autore | Oestreich Martin |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (609 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | OestreichMartin |
| Soggetto topico |
Heck reaction
Palladium catalysts Organic compounds - Synthesis |
| ISBN |
1-282-02242-3
9786612022425 0-470-71607-X 0-470-71606-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Mizoroki-Heck Reaction; Contents; Foreword; Preface; Contributors; 1 Mechanisms of the Mizoroki-Heck Reaction; 1.1 Introduction; 1.2 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 in the Absence of Ligand; 1.3 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Monophosphine Ligands; 1.3.1 Pd(0) Formation from Pd(OAc)2 in the Presence of a Monophosphine Ligand; 1.3.2 Oxidative Addition; 1.3.2.1 Oxidative Addition of Aryl Iodides; 1.3.2.2 Oxidative Addition of Aryl Triflates
1.3.3 Complexation/Insertion of the Alkene1.3.4 Multiple Role of the Base; 1.3.5 Catalytic Cycle; 1.3.5.1 Factors Controlling the Efficiency of a Catalytic Reaction; 1.4 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is Pd(OAc)2 Associated with Bisphosphine Ligands; 1.4.1 Pd(0) Formation from Precursor; 1.4.2 Oxidative Addition; 1.4.3 Complexation/Insertion of the Alkene Regioselectivity; 1.4.4 Catalytic Cycles; 1.5 Mechanism of the Mizoroki-Heck Reaction when the Catalytic Precursor is a P,C-Palladacycle; 1.5.1 Pd(0) Formation from a P,C-Palladacycle 1.5.2 Catalytic Cycle1.6 Mechanism of the Mizoroki-Heck Reaction when the Ligand is an N-Heterocyclic Carbene; 1.6.1 Oxidative Addition; 1.6.2 Complexation/Insertion of the Alkene; 1.6.3 Catalytic Cycles; 1.7 Mechanism of the Mizoroki-Heck Reaction when the Ligand is a Bulky and Electron-Rich Monophosphine; 1.7.1 Oxidative Addition; 1.7.2 Complexation/Insertion of the Alkene; 1.7.3 Role of the Base in the Recycling of the Pd(0) Complex; 1.7.4 Catalytic Cycle; 1.8 Conclusion; References; 2 Focus on Catalyst Development and Ligand Design; 2.1 Introduction 2.2 General Considerations: Types of Catalytic System2.2.1 Substrate Dependence; 2.2.2 Ancillary Ligands; 2.2.3 Bases; 2.2.4 Additives; 2.2.5 Media; 2.2.6 Temperature; 2.3 Four Types of Intermolecular Mizoroki-Heck Catalytic System; 2.3.1 The Type 1 Catalytic System; 2.3.2 The Type 2 Catalytic System; 2.3.3 The Type 3 Catalytic System; 2.3.4 The Type 4 Catalytic System; 2.4 Palladium Precatalysts in Type 1 and Type 2 Mizoroki-Heck Reactions; 2.4.1 SRPCs; 2.4.2 Nanoparticles; 2.4.3 Supported Catalysts: Leaching versus Recycling; 2.4.4 Carbene Complexes 2.4.4.1 N-Heterocyclic Carbene-based Complexes2.4.4.2 N-Heterocyclic Carbene-Based Pincer Complexes; 2.4.4.3 Carbocyclic Carbene-based Complexes; 2.4.5 Palladacycles; 2.4.5.1 C,P-, C,S- and C,N-Palladacycles; 2.4.5.2 Pincer Palladacycles; 2.4.5.3 Palladacycle-Phosphine Complexes; 2.4.6 Nonphosphine Complexes; References; 3 Focus on Regioselectivity and Product Outcome in Organic Synthesis; 3.1 Introduction; 3.2 Mechanistic Aspects; 3.2.1 Oxidative Addition; 3.2.2 -Complex Formation and Migratory Insertion; 3.2.3 -H-Elimination and Palladium(0) Recycling 3.2.4 Cyclic Alkenes and Double-Bond Migration |
| Record Nr. | UNINA-9910840874903321 |
|
Oestreich Martin
|
||
| Chichester, U.K., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organic synthesis : an introduction / / George S. Zweifel, Michael H. Nantz, Peter Somfai
| Modern organic synthesis : an introduction / / George S. Zweifel, Michael H. Nantz, Peter Somfai |
| Autore | Zweifel George S. |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2017 |
| Descrizione fisica | 1 online resource (407 pages) |
| Disciplina | 547/.2 |
| Soggetto topico | Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-119-08672-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910466198803321 |
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Zweifel George S.
|
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| Hoboken, New Jersey : , : Wiley, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Modern organic synthesis : an introduction / / George S. Zweifel, Michael H. Nantz, Peter Somfai
| Modern organic synthesis : an introduction / / George S. Zweifel, Michael H. Nantz, Peter Somfai |
| Autore | Zweifel George S. |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2017 |
| Descrizione fisica | 1 online resource (xiii, 390 pages) : illustrations |
| Disciplina | 547/.2 |
| Soggetto topico | Organic compounds - Synthesis |
| ISBN |
1-119-08672-8
1-119-08676-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910795939903321 |
|
Zweifel George S.
|
||
| Hoboken, New Jersey : , : Wiley, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
