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Handbook of reagents for organic synthesis : reagents for heteroarene functionalization / / edited by André B. Charette
| Handbook of reagents for organic synthesis : reagents for heteroarene functionalization / / edited by André B. Charette |
| Pubbl/distr/stampa | West Sussex, England : , : Wiley, , 2015 |
| Descrizione fisica | 1 online resource (829 p.) |
| Disciplina | 547/.2 |
| Collana | Hdbk of Reagents for Organic Synthesis |
| Soggetto topico |
Organic compounds - Synthesis
Heterocyclic chemistry Chemical tests and reagents |
| ISBN |
1-118-72657-X
1-118-72655-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Handbook of Reagents for Organic Synthesis: Reagents for Heteroarene Functionalization; Contents; Preface; Introduction; Recent Review Articles and Monographs; Short Note on InChIs and InChIKeys; Acetic Anhydride; Acetyl Chloride; Aluminum Chloride; Aluminum Trifluoromethanesulfonate; Antimony Trifluoromethanesulfonate; Bathophenanthroline; 1,2-Benzodiazine; Benzopyrazole; Benzotriazole; Bis(allyl)di-μ-chlorodipalladium; Bis(benzonitrile)dichloropalladium(II); Bis(dibenzylideneacetone)palladium(0); Bis(1,10-phenanthroline)palladium Hexafluorophosphate
Bis[tris(1,1-dimethylethyl)-phosphine]palladiumBromine; N-Bromosuccinimide; n-Butyllithium; sec-Butyllithium; tert-Butyllithium; Butyllithium-Potassium tert-Butoxide; Cesium Acetate; N-Chlorosuccinimide; Copper(II) Acetate; Copper(II) Bromide; Copper(I) Chloride; Copper(II) Chloride; Copper(I) Iodide; Copper(II) Trifluoroacetate; Copper(II) Trifluoromethanesulfonate; N-Cyano-4-methyl-N-phenylbenzenesulfonamide; Dibenzofuran; Dibenzothiophene; 1,1-Di-tert-butyl Peroxide; Di-tert-butyl(methyl)phosphine; Di-tert-butyl(methyl)phosphonium Tetrafluoroborate; Dichlorobis(acetonitrile) Palladium Dichlorobis(triphenylphosphine)-palladium(II)Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]diiridium; Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I); Dimethyl Diazomalonate; (2S,5S)-2-(1,1-Dimethylethyl)-3-methyl-5-(phenylmethyl)-4-imidazolidinone; Diphenyliodonium Hexafluorophosphate; Diphenyliodonium Triflate; Dysprosium Trifluoromethanesulfonate; N-fluoro-N-(phenylsulfonyl)-benzenesulfonamide; 1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate; Furan; Gallium(III) Trifluoromethanesulfonate (Gallium Triflate); Hafnium(IV) Trifluoromethanesulfonate; Hypofluorous Acid-Acetonitrile Complex Indium(III) TriflateIndolizine; Iron, Bis(pyridine)bis(2-pyridinecarboxylato-N1,O2); Isoindole; Isoquinoline; Lithium t-Butoxide; Lithium Dichloro(1-methylethyl)-magnesate; Lithium Dichloro(2,2,6,6-tetramethylpiperidinato)-zincate; Magnesium tert-butoxide; Manganese(III) Acetate; 4-Methoxypyridine N-oxide; 6-Methoxyquinoline-N-oxide; 2-Methylbenzothiazole; N-Methylimidazole; N-Methylindole; 1-[[(4-Methylphenyl)sulfonyl]amino]-pyridinium inner salt; Methyltrioxorhenium; Nitric Acid; 4,4,4,́4,́5,5,5,́5-́Octamethyl-2,2-́bi-1,3,2-dioxaborolane; 1,2,5-Oxadiazole; Oxalyl Chloride-Dimethylformamide OxazolePalladium(II) Acetate; Palladium(II) Bromide; Palladium(II) Chloride; Palladium(π-cinnamyl) Chloride Dimer; Palladium Pivalate; Pentamethylcyclopentadienylrhodium(III) chloride dimer; 1,10-Phenanthroline; 1,10-Phenanthroline, 1-Oxide; (1,10-Phenanthroline)(trifluoromethyl) (triphenylphosphine)copper; Pinacolborane; Pivalic Acid; Potassium Acetate; Propanoic acid, 2-Diazo-, 2-Methyl-1-(1-methylethyl)propyl ester; Pyridazine; Pyridazine N-Oxide; Pyridine; Pyridine N-Oxide; Pyrrole; Quinoline; Ruthenium Dodecacarbonyltri Triangulo; Scandium Trifluoromethanesulfonate; Silver(I) Acetate Silver(I) Carbonate |
| Record Nr. | UNINA-9910797481303321 |
| West Sussex, England : , : Wiley, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of reagents for organic synthesis : reagents for heteroarene functionalization / / edited by André B. Charette
| Handbook of reagents for organic synthesis : reagents for heteroarene functionalization / / edited by André B. Charette |
| Pubbl/distr/stampa | West Sussex, England : , : Wiley, , 2015 |
| Descrizione fisica | 1 online resource (829 p.) |
| Disciplina | 547/.2 |
| Collana | Hdbk of Reagents for Organic Synthesis |
| Soggetto topico |
Organic compounds - Synthesis
Heterocyclic chemistry Chemical tests and reagents |
| ISBN |
1-118-72657-X
1-118-72655-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Handbook of Reagents for Organic Synthesis: Reagents for Heteroarene Functionalization; Contents; Preface; Introduction; Recent Review Articles and Monographs; Short Note on InChIs and InChIKeys; Acetic Anhydride; Acetyl Chloride; Aluminum Chloride; Aluminum Trifluoromethanesulfonate; Antimony Trifluoromethanesulfonate; Bathophenanthroline; 1,2-Benzodiazine; Benzopyrazole; Benzotriazole; Bis(allyl)di-μ-chlorodipalladium; Bis(benzonitrile)dichloropalladium(II); Bis(dibenzylideneacetone)palladium(0); Bis(1,10-phenanthroline)palladium Hexafluorophosphate
Bis[tris(1,1-dimethylethyl)-phosphine]palladiumBromine; N-Bromosuccinimide; n-Butyllithium; sec-Butyllithium; tert-Butyllithium; Butyllithium-Potassium tert-Butoxide; Cesium Acetate; N-Chlorosuccinimide; Copper(II) Acetate; Copper(II) Bromide; Copper(I) Chloride; Copper(II) Chloride; Copper(I) Iodide; Copper(II) Trifluoroacetate; Copper(II) Trifluoromethanesulfonate; N-Cyano-4-methyl-N-phenylbenzenesulfonamide; Dibenzofuran; Dibenzothiophene; 1,1-Di-tert-butyl Peroxide; Di-tert-butyl(methyl)phosphine; Di-tert-butyl(methyl)phosphonium Tetrafluoroborate; Dichlorobis(acetonitrile) Palladium Dichlorobis(triphenylphosphine)-palladium(II)Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]diiridium; Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I); Dimethyl Diazomalonate; (2S,5S)-2-(1,1-Dimethylethyl)-3-methyl-5-(phenylmethyl)-4-imidazolidinone; Diphenyliodonium Hexafluorophosphate; Diphenyliodonium Triflate; Dysprosium Trifluoromethanesulfonate; N-fluoro-N-(phenylsulfonyl)-benzenesulfonamide; 1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate; Furan; Gallium(III) Trifluoromethanesulfonate (Gallium Triflate); Hafnium(IV) Trifluoromethanesulfonate; Hypofluorous Acid-Acetonitrile Complex Indium(III) TriflateIndolizine; Iron, Bis(pyridine)bis(2-pyridinecarboxylato-N1,O2); Isoindole; Isoquinoline; Lithium t-Butoxide; Lithium Dichloro(1-methylethyl)-magnesate; Lithium Dichloro(2,2,6,6-tetramethylpiperidinato)-zincate; Magnesium tert-butoxide; Manganese(III) Acetate; 4-Methoxypyridine N-oxide; 6-Methoxyquinoline-N-oxide; 2-Methylbenzothiazole; N-Methylimidazole; N-Methylindole; 1-[[(4-Methylphenyl)sulfonyl]amino]-pyridinium inner salt; Methyltrioxorhenium; Nitric Acid; 4,4,4,́4,́5,5,5,́5-́Octamethyl-2,2-́bi-1,3,2-dioxaborolane; 1,2,5-Oxadiazole; Oxalyl Chloride-Dimethylformamide OxazolePalladium(II) Acetate; Palladium(II) Bromide; Palladium(II) Chloride; Palladium(π-cinnamyl) Chloride Dimer; Palladium Pivalate; Pentamethylcyclopentadienylrhodium(III) chloride dimer; 1,10-Phenanthroline; 1,10-Phenanthroline, 1-Oxide; (1,10-Phenanthroline)(trifluoromethyl) (triphenylphosphine)copper; Pinacolborane; Pivalic Acid; Potassium Acetate; Propanoic acid, 2-Diazo-, 2-Methyl-1-(1-methylethyl)propyl ester; Pyridazine; Pyridazine N-Oxide; Pyridine; Pyridine N-Oxide; Pyrrole; Quinoline; Ruthenium Dodecacarbonyltri Triangulo; Scandium Trifluoromethanesulfonate; Silver(I) Acetate Silver(I) Carbonate |
| Record Nr. | UNINA-9910810855803321 |
| West Sussex, England : , : Wiley, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
How to Solve Organic Reaction Mechanisms : A Stepwise Approach
| How to Solve Organic Reaction Mechanisms : A Stepwise Approach |
| Autore | Moloney Mark G |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York : , : John Wiley & Sons, Incorporated, , 2015 |
| Descrizione fisica | 1 online resource (245 pages) |
| Disciplina | 547/.2 |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
9781118698525
9781118401590 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cover -- Title Page -- Copyright -- Contents -- Preface -- Abbreviations -- About the companion website -- Introduction -- Chapter 1 Nucleophilic substitution and elimination -- Nucleophilic substitution: SN1 and SN2 reactions -- Elimination: E1 and E2 eliminations -- Chapter 2 Alkene and alkyne chemistry -- Alkene and alkyne bonding -- Electrophilic addition -- Nucleophilic addition to C = C bonds conjugated to a C = O -- Other types of additions -- Chapter 3 Nucleophilic additions to carbonyl groups -- Chapter 4 Enolate chemistry -- Halogenation -- Deuteriation -- Alkylation -- Condensation reactions -- Chapter 5 Aromatic chemistry -- Bonding in aromatic compounds -- Electrophilic aromatic substitution (SEAr) -- Nucleophilic aromatic substitution (SNAr) -- Oxidation -- Chapter 6 Rearrangements -- Chapter 7 Ligand coupling processes -- Index -- EULA. |
| Record Nr. | UNINA-9910795986103321 |
Moloney Mark G
|
||
| New York : , : John Wiley & Sons, Incorporated, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
How to Solve Organic Reaction Mechanisms : A Stepwise Approach
| How to Solve Organic Reaction Mechanisms : A Stepwise Approach |
| Autore | Moloney Mark G |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York : , : John Wiley & Sons, Incorporated, , 2015 |
| Descrizione fisica | 1 online resource (245 pages) |
| Disciplina | 547/.2 |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
9781118698525
9781118401590 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cover -- Title Page -- Copyright -- Contents -- Preface -- Abbreviations -- About the companion website -- Introduction -- Chapter 1 Nucleophilic substitution and elimination -- Nucleophilic substitution: SN1 and SN2 reactions -- Elimination: E1 and E2 eliminations -- Chapter 2 Alkene and alkyne chemistry -- Alkene and alkyne bonding -- Electrophilic addition -- Nucleophilic addition to C = C bonds conjugated to a C = O -- Other types of additions -- Chapter 3 Nucleophilic additions to carbonyl groups -- Chapter 4 Enolate chemistry -- Halogenation -- Deuteriation -- Alkylation -- Condensation reactions -- Chapter 5 Aromatic chemistry -- Bonding in aromatic compounds -- Electrophilic aromatic substitution (SEAr) -- Nucleophilic aromatic substitution (SNAr) -- Oxidation -- Chapter 6 Rearrangements -- Chapter 7 Ligand coupling processes -- Index -- EULA. |
| Record Nr. | UNINA-9910813811503321 |
|
Moloney Mark G
|
||
| New York : , : John Wiley & Sons, Incorporated, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910145691703321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNISA-996197710203316 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910831031203321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910840598603321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis acids in organic synthesis
| Lewis acids in organic synthesis |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2000 |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61830-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910144376503321 |
| [Place of publication not identified], : Wiley VCH, 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis acids in organic synthesis
| Lewis acids in organic synthesis |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2000 |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61830-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910677072703321 |
| [Place of publication not identified], : Wiley VCH, 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
