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Practical functional group synthesis / / Robert A. Stockland, Jr
Practical functional group synthesis / / Robert A. Stockland, Jr
Autore Stockland Robert, Jr., <1971->
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley, , 2016
Descrizione fisica 1 online resource (700 p.)
Disciplina 547/.2
Soggetto topico Chemical bonds
Functional groups
Chemistry, Organic
ISBN 1-119-01577-4
1-119-01584-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910813489303321
Stockland Robert, Jr., <1971->  
Hoboken, New Jersey : , : Wiley, , 2016
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Practical synthetic organic chemistry [[electronic resource] ] : reactions, principles, and techniques / / edited by Stéphane Caron
Practical synthetic organic chemistry [[electronic resource] ] : reactions, principles, and techniques / / edited by Stéphane Caron
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2011
Descrizione fisica 1 online resource (xii, 856 p.)
Disciplina 547/.2
Altri autori (Persone) CaronStéphane
Soggetto topico Organic compounds - Synthesis
ISBN 9786613176608
1-118-09357-7
1-118-09355-0
1-283-17660-2
1-118-09356-9
Classificazione SCI013040
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface. Chapter 1: Aliphatic Nucleophilic Substitution ( Jade D. Nelson ). Chapter 2: Addition to Carbon-Heteroatom Multiple Bonds ( Rajappa Vaidyanathan and Carrie Brockway Wager ). Chapter 3: Addition to Carbon Carbon Multiple Bonds ( John A. Ragan ). Chapter 4: Nucleophilic Aromatic Substitution ( Stephane Caron and Arun Ghosh ). Chapter 5: Electrophilic Aromatic Substitution ( Stephane Caron ). Chapter 6: Selected Metal-mediated cross-coupling reactions ( Stephane Caron, Arun Ghosh, Sally Gut Ruggeri, Nathan D. Ide, Jade D. Nelson, and John A. Ragan ). Chapter 7: Rearrangements ( David H. B. Ripin ). Chapter 8: Eliminations ( Sally Gut Ruggeri ). Chapter 9: Reductions ( Sally Gut Ruggeri, Stephane Caron, Pascal Dube, Nathan D. Ide, Kristin E. Price, John A. Ragan, and Shu Yu ). Chapter 10: Oxidations ( David H. Brown Ripin ). Chapter 11: Selected Free Radical Reactions ( Nathan D. Ide ). Chapter 12: Synthesis of "Nucleophilic" Organometallic Reagents ( David H. Brown Ripin ). Chapter 13: Synthesis of Common Aromatic Heterocycles ( Stephane Caron ). Chapter 14: Access to Chirality ( Robert W. Dugger ). Chapter 15: Synthetic Route Development of Selected Contemporary Pharmaceutical Drugs ( Stephane Caron ). Chapter 16: Green Chemistry ( Juan C. Colberg ). Chapter 17: Naming Carbocycles and Heterocycles ( Heather N. Frost and David H. B. Ripin ). Chapter 18: pKa ( David H. Brown Ripin ). Chapter 19: General Solvent Properties ( Stephane Caron ). Chapter 20: Practical Chemistry Concepts Tips for the Practicing Chemist or Things They Don't Teach You in School ( Sally Gut Ruggeri ).
Record Nr. UNINA-9910791599703321
Hoboken, N.J., : Wiley, 2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Practical synthetic organic chemistry : reactions, principles, and techniques / / edited by Stéphane Caron
Practical synthetic organic chemistry : reactions, principles, and techniques / / edited by Stéphane Caron
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2011
Descrizione fisica 1 online resource (xii, 856 p.)
Disciplina 547/.2
Altri autori (Persone) CaronStéphane
Soggetto topico Organic compounds - Synthesis
ISBN 9786613176608
1-118-09357-7
1-118-09355-0
1-283-17660-2
1-118-09356-9
Classificazione SCI013040
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface. Chapter 1: Aliphatic Nucleophilic Substitution ( Jade D. Nelson ). Chapter 2: Addition to Carbon-Heteroatom Multiple Bonds ( Rajappa Vaidyanathan and Carrie Brockway Wager ). Chapter 3: Addition to Carbon Carbon Multiple Bonds ( John A. Ragan ). Chapter 4: Nucleophilic Aromatic Substitution ( Stephane Caron and Arun Ghosh ). Chapter 5: Electrophilic Aromatic Substitution ( Stephane Caron ). Chapter 6: Selected Metal-mediated cross-coupling reactions ( Stephane Caron, Arun Ghosh, Sally Gut Ruggeri, Nathan D. Ide, Jade D. Nelson, and John A. Ragan ). Chapter 7: Rearrangements ( David H. B. Ripin ). Chapter 8: Eliminations ( Sally Gut Ruggeri ). Chapter 9: Reductions ( Sally Gut Ruggeri, Stephane Caron, Pascal Dube, Nathan D. Ide, Kristin E. Price, John A. Ragan, and Shu Yu ). Chapter 10: Oxidations ( David H. Brown Ripin ). Chapter 11: Selected Free Radical Reactions ( Nathan D. Ide ). Chapter 12: Synthesis of "Nucleophilic" Organometallic Reagents ( David H. Brown Ripin ). Chapter 13: Synthesis of Common Aromatic Heterocycles ( Stephane Caron ). Chapter 14: Access to Chirality ( Robert W. Dugger ). Chapter 15: Synthetic Route Development of Selected Contemporary Pharmaceutical Drugs ( Stephane Caron ). Chapter 16: Green Chemistry ( Juan C. Colberg ). Chapter 17: Naming Carbocycles and Heterocycles ( Heather N. Frost and David H. B. Ripin ). Chapter 18: pKa ( David H. Brown Ripin ). Chapter 19: General Solvent Properties ( Stephane Caron ). Chapter 20: Practical Chemistry Concepts Tips for the Practicing Chemist or Things They Don't Teach You in School ( Sally Gut Ruggeri ).
Record Nr. UNINA-9910809996003321
Hoboken, N.J., : Wiley, 2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Autore Lin Guo-Qiang <1943->
Pubbl/distr/stampa New York, : Wiley-Interscience, c2001
Descrizione fisica 1 online resource (535 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950->
Soggetto topico Asymmetric synthesis
Organic compounds - Synthesis
Soggetto genere / forma Electronic books.
ISBN 1-280-36767-9
9786610367672
0-470-24631-6
0-471-46524-0
0-471-22042-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds
1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition
2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions
3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions
3.6.1 The Roush Reaction
Record Nr. UNINA-9910142500303321
Lin Guo-Qiang <1943->  
New York, : Wiley-Interscience, c2001
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Autore Lin Guo-Qiang <1943->
Pubbl/distr/stampa New York, : Wiley-Interscience, c2001
Descrizione fisica 1 online resource (535 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950->
Soggetto topico Asymmetric synthesis
Organic compounds - Synthesis
ISBN 1-280-36767-9
9786610367672
0-470-24631-6
0-471-46524-0
0-471-22042-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds
1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition
2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions
3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions
3.6.1 The Roush Reaction
Record Nr. UNISA-996201196203316
Lin Guo-Qiang <1943->  
New York, : Wiley-Interscience, c2001
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Autore Lin Guo-Qiang <1943->
Pubbl/distr/stampa New York, : Wiley-Interscience, c2001
Descrizione fisica 1 online resource (535 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950->
Soggetto topico Asymmetric synthesis
Organic compounds - Synthesis
ISBN 1-280-36767-9
9786610367672
0-470-24631-6
0-471-46524-0
0-471-22042-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds
1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition
2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions
3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions
3.6.1 The Roush Reaction
Record Nr. UNINA-9910830879503321
Lin Guo-Qiang <1943->  
New York, : Wiley-Interscience, c2001
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles and applications of asymmetric synthesis / / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Principles and applications of asymmetric synthesis / / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan
Autore Lin Guo-Qiang <1943->
Pubbl/distr/stampa New York, : Wiley-Interscience, c2001
Descrizione fisica 1 online resource (535 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950->
Soggetto topico Asymmetric synthesis
Organic compounds - Synthesis
ISBN 1-280-36767-9
9786610367672
0-470-24631-6
0-471-46524-0
0-471-22042-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds
1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition
2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions
3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions
3.6.1 The Roush Reaction
Record Nr. UNINA-9910877612503321
Lin Guo-Qiang <1943->  
New York, : Wiley-Interscience, c2001
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Quinone methides [[electronic resource] /] / edited by Steven E. Rokita
Quinone methides [[electronic resource] /] / edited by Steven E. Rokita
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2009
Descrizione fisica 1 online resource (460 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) RokitaSteven Edward
Collana Wiley series on reactive intermediates in chemistry and biology
Soggetto topico Intermediates (Chemistry)
ISBN 1-282-68959-2
9786612689598
0-470-45288-9
0-470-45287-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINONE METHIDES; CONTENTS; Preface to Series; Introduction; Contributors; 1 Photochemical Generation and Characterization of Quinone Methides; 1.1 Introduction; 1.2 Quinone Methides from Benzylic Photoelimination; 1.2.1 Photoelimination of Fluoride; 1.2.2 Photodehydration; 1.2.3 Photoelimination of Quaternary Ammonium Salts; 1.2.4 Photoelimination of Alcohols and Esters; 1.3 Quinone Methides from ESIPT to Unsaturated Systems; 1.3.1 Quinone Methides from ESIPT to Carbonyls; 1.3.2 Quinone Methides from ESIPT to Alkenes and Alkynes; 1.3.3 Quinone Methides from ESIPT to Aromatic Carbon
1.4 Other Photochemical Routes to Quinone Methides1.5 Conclusions and Outlook; References; 2 Modeling Properties and Reactivity of Quinone Methides by DFT Calculations; 2.1 Introduction; 2.2 QM Reactivity as Alkylating Agents; 2.2.1 Computational Models; 2.2.1.1 Basis Set Choice; 2.2.1.2 Energetics of the Benzylation by o-QM in the Gas Phase and in Aqueous Solution; 2.2.2 H-Bonding and Solvent Effects in the Benzylation of Purine and Pyrimidine Bases; 2.2.2.1 Cytosine Benzylation under Kinetic Control; 2.2.2.2 Stability/Reactivity of the QM-Cytosine Conjugates
2.2.2.3 Purine Bases Benzylation: Kinetic and Thermodynamic Aspects2.3 Reactivity as Heterodiene; 2.4 Tautomerizations Involving Quinones and Quinone Methides; 2.4.1 QM Versus Quinone Stability: Substituent Effects; 2.5 o-Quinone Methide Metal Complexes; 2.5.1 Geometries and Reactivity as Function of the Metal and the Structural Features; 2.6 Generation of o-QM; 2.6.1 Generation of o-QM Tethered to Naphthalene Diimides by Mild Activation; 2.6.2 Thermal Generation of o-QM in Oxidative Processes in the Gas Phase; 2.7 Thermal Decomposition of o-QM in the Gas Phase
2.8 QM Generation in Lignin Formation2.9 Conclusion and Perspective; References; 3 Quinone Methide Stabilization by Metal Complexation; 3.1 Introduction; 3.2 QM-Based Pincer Complexes; 3.2.1 Formation; 3.2.2 Reactivity and Modifications; 3.2.3 Os-Based, p-QM Complexes; 3.3 One-Site Coordinated QM Complexes; 3.3.1 η(2)-ortho-QM Complexes; 3.3.1.1 Formation; 3.3.1.2 Release and Reactivity of η(2)-o-QMs; 3.3.2 η(2)-p-QM Complexes; 3.3.2.1 Formation; 3.3.2.2 Controlled Release and Modification of η(2)-p-QMs; 3.4 η(4)-Coordinated QM Complexes; 3.4.1 Formation of η(4)-Coordinated QM Complexes
3.4.2 Reactivity of η(4)-Coordinated QM Complexes3.4.3 η(4)-Coordinated QM Complexes of Mn; 3.5 Characterization of QM Complexes; 3.5.1 IR; 3.5.2 (1)H and (13)C {(1)H} NMR; 3.5.3 X-Ray; 3.6 Conclusion and Future Applications; Acknowledgments; References; 4 Intermolecular Applications of o-Quinone Methides (o-QMs) Anionically Generated at Low Temperatures: Kinetic Conditions; 4.1 Introduction to o-QMs; 4.2 Thermal Generation Conditions; 4.3 Low-Temperature Kinetic Generation of o-QMs; 4.3.1 Formation of the o-QMs Triggered by Fluoride Ion; 4.3.2 Stepwise Formation of o-QMs
4.3.3 Kinetically Controlled Cycloadditions
Record Nr. UNINA-9910146086703321
Hoboken, N.J., : Wiley, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Quinone methides / / edited by Steven E. Rokita
Quinone methides / / edited by Steven E. Rokita
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2009
Descrizione fisica 1 online resource (460 p.)
Disciplina 547.2
547/.2
Altri autori (Persone) RokitaSteven Edward
Collana Wiley series on reactive intermediates in chemistry and biology
Soggetto topico Intermediates (Chemistry)
ISBN 1-282-68959-2
9786612689598
0-470-45288-9
0-470-45287-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto QUINONE METHIDES; CONTENTS; Preface to Series; Introduction; Contributors; 1 Photochemical Generation and Characterization of Quinone Methides; 1.1 Introduction; 1.2 Quinone Methides from Benzylic Photoelimination; 1.2.1 Photoelimination of Fluoride; 1.2.2 Photodehydration; 1.2.3 Photoelimination of Quaternary Ammonium Salts; 1.2.4 Photoelimination of Alcohols and Esters; 1.3 Quinone Methides from ESIPT to Unsaturated Systems; 1.3.1 Quinone Methides from ESIPT to Carbonyls; 1.3.2 Quinone Methides from ESIPT to Alkenes and Alkynes; 1.3.3 Quinone Methides from ESIPT to Aromatic Carbon
1.4 Other Photochemical Routes to Quinone Methides1.5 Conclusions and Outlook; References; 2 Modeling Properties and Reactivity of Quinone Methides by DFT Calculations; 2.1 Introduction; 2.2 QM Reactivity as Alkylating Agents; 2.2.1 Computational Models; 2.2.1.1 Basis Set Choice; 2.2.1.2 Energetics of the Benzylation by o-QM in the Gas Phase and in Aqueous Solution; 2.2.2 H-Bonding and Solvent Effects in the Benzylation of Purine and Pyrimidine Bases; 2.2.2.1 Cytosine Benzylation under Kinetic Control; 2.2.2.2 Stability/Reactivity of the QM-Cytosine Conjugates
2.2.2.3 Purine Bases Benzylation: Kinetic and Thermodynamic Aspects2.3 Reactivity as Heterodiene; 2.4 Tautomerizations Involving Quinones and Quinone Methides; 2.4.1 QM Versus Quinone Stability: Substituent Effects; 2.5 o-Quinone Methide Metal Complexes; 2.5.1 Geometries and Reactivity as Function of the Metal and the Structural Features; 2.6 Generation of o-QM; 2.6.1 Generation of o-QM Tethered to Naphthalene Diimides by Mild Activation; 2.6.2 Thermal Generation of o-QM in Oxidative Processes in the Gas Phase; 2.7 Thermal Decomposition of o-QM in the Gas Phase
2.8 QM Generation in Lignin Formation2.9 Conclusion and Perspective; References; 3 Quinone Methide Stabilization by Metal Complexation; 3.1 Introduction; 3.2 QM-Based Pincer Complexes; 3.2.1 Formation; 3.2.2 Reactivity and Modifications; 3.2.3 Os-Based, p-QM Complexes; 3.3 One-Site Coordinated QM Complexes; 3.3.1 η(2)-ortho-QM Complexes; 3.3.1.1 Formation; 3.3.1.2 Release and Reactivity of η(2)-o-QMs; 3.3.2 η(2)-p-QM Complexes; 3.3.2.1 Formation; 3.3.2.2 Controlled Release and Modification of η(2)-p-QMs; 3.4 η(4)-Coordinated QM Complexes; 3.4.1 Formation of η(4)-Coordinated QM Complexes
3.4.2 Reactivity of η(4)-Coordinated QM Complexes3.4.3 η(4)-Coordinated QM Complexes of Mn; 3.5 Characterization of QM Complexes; 3.5.1 IR; 3.5.2 (1)H and (13)C {(1)H} NMR; 3.5.3 X-Ray; 3.6 Conclusion and Future Applications; Acknowledgments; References; 4 Intermolecular Applications of o-Quinone Methides (o-QMs) Anionically Generated at Low Temperatures: Kinetic Conditions; 4.1 Introduction to o-QMs; 4.2 Thermal Generation Conditions; 4.3 Low-Temperature Kinetic Generation of o-QMs; 4.3.1 Formation of the o-QMs Triggered by Fluoride Ion; 4.3.2 Stepwise Formation of o-QMs
4.3.3 Kinetically Controlled Cycloadditions
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Hoboken, N.J., : Wiley, 2009
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Reaktionen der organischen Chemie [[electronic resource] /] / Helmut Krauch, Werner Kunz
Reaktionen der organischen Chemie [[electronic resource] /] / Helmut Krauch, Werner Kunz
Autore Krauch Helmut
Edizione [6., neubearbeitete Aufl.]
Pubbl/distr/stampa Heidelberg, : Wiley-VCH, 1997
Descrizione fisica 1 online resource (778 p.)
Disciplina 547.139
547/.2
Altri autori (Persone) KunzWerner <1922->
Soggetto topico Chemical reactions
Chemistry, Organic
Soggetto genere / forma Electronic books.
ISBN 1-282-27872-X
9786612278723
3-527-62511-9
3-527-62512-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione ger
Nota di contenuto Reaktionen der organischen Chemie; Inhaltsverzeichnis
Record Nr. UNINA-9910139928303321
Krauch Helmut  
Heidelberg, : Wiley-VCH, 1997
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui