Nitrile oxides, nitrones, and nitronates in organic synthesis [[electronic resource] ] : novel strategies in synthesis / / edited by Henry Feuer |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2008 |
Descrizione fisica | 1 online resource (767 p.) |
Disciplina | 547/.2 |
Altri autori (Persone) |
FeuerHenry <1912->
TorssellKurt <1926-> |
Collana | Organic Nitro Chemistry |
Soggetto topico |
Nitrogen oxides
Organic compounds - Synthesis |
ISBN |
1-281-20380-7
9786611203801 0-470-19155-4 0-470-19154-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | NITRILE OXIDES, NITRONES, AND NITRONATES IN ORGANIC SYNTHESIS; CONTENTS; Series Foreword; List of Abbreviations; 1 Nitrile Oxides; 2 Nitrones: Novel Strategies in Synthesis; 3 Nitronates; Index |
Record Nr. | UNINA-9910811949203321 |
Hoboken, N.J., : Wiley-Interscience, c2008 | ||
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Lo trovi qui: Univ. Federico II | ||
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The nitro group in organic synthesis [[electronic resource] /] / Noboru Ono |
Autore | Ono Noboru |
Pubbl/distr/stampa | New York, : Wiley-VCH, c2001 |
Descrizione fisica | 1 online resource (390 p.) |
Disciplina |
547.040459
547/.2 |
Collana | Organic nitro chemistry series |
Soggetto topico |
Organic compounds - Synthesis
Nitro compounds |
Soggetto genere / forma | Electronic books. |
ISBN |
1-280-36618-4
9786610366187 0-470-25024-0 0-471-45846-5 0-471-22448-0 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
THE NITRO GROUP IN ORGANIC SYNTHESIS; CONTENTS; Series Foreword; Preface; Acknowledgments; Abbreviations; 1. Introduction; 2. Preparation of Nitro Compounds; 2.1 Nitration of Hydrocarbons; 2.1.1 Aromatic Compounds; 2.1.2 Alkanes; 2.1.3 Activated C-H Compounds; 2.1.4 Alkenes; 2.1.5 Synthesis of a-Nitro Ketones; 2.1.6 Nitration of Alkyl Halides; 2.2 Synthesis of Nitro Compounds by Oxidation; 2.2.1 Oxidation of Amines; 2.2.2 Oxidation of Oximes; 3.The Nitro-Aldol (Henry) Reaction; 3.1 Preparation of b-Nitro Alcohols; 3.2 Derivatives from b-Nitro Alcohols; 3.2.1 Nitroalkenes; 3.2.2 Nitroalkanes
3.2.3 a-Nitro Ketones3.2.4 b-Amino Alcohols; 3.2.5 Nitro Sugars and Amino Sugars; 3.3 Stereoselective Henry Reactions and Applications to Organic Synthesis; 4. Michael Addition; 4.1 Addition to Nitroalkenes; 4.1.1 Conjugate Addition of Heteroatom-Centered Nucleophiles; 4.1.2 Conjugate Addition of Heteroatom Nucleophiles and Subsequent Nef Reaction; 4.1.3 Conjugate Addition of Carbon-Centered Nucleophiles; 4.2 Addition and Elimination Reaction of b-Heterosubstituted Nitroalkenes; 4.3 Michael Addition of Nitroalkanes; 4.3.1 Intermolecular Addition; 4.3.2 Intramolecular Addition 4.4 Asymmetric Michael Addition4.4.1 Chiral Alkenes and Chiral Nitro Compounds; 4.4.2 Chiral Catalysts; 5. Alkylation, Acylation, and Halogenation of Nitro Compounds; 5.1 Alkylation of Nitro Compounds; 5.2 Acylation of Nitroalkanes; 5.3 Ring Cleavage of Cyclic a-Nitro Ketones (Retro-Acylation); 5.4 Alkylation of Nitro Compounds via Alkyl Radicals; 5.5 Alkylation of Nitro Compounds Using Transition Metal Catalysis; 5.5.1 Butadiene Telomerization; 5.5.2 Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds; 5.6 Arylation of Nitro Compounds; 5.7 Introduction of Heteroatoms to Nitroalkanes 6. Conversion of Nitro Compounds into Other Compounds6.1 Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids); 6.1.1 Treatment With Acid (Classical Procedure); 6.1.2 Oxidative Method; 6.1.3 Reductive Method; 6.1.4 Direct Conversion of Nitroalkenes to Carbonyl Compounds; 6.2 Nitrile Oxides and Nitriles; 6.3 Reduction of Nitro Compounds into Amines; 6.3.1 Ar-NH(2) From Ar-NO(2); 6.3.2 R-NH(2) from R-NO(2); 6.3.3 Oximes, Hydroxylamines, and Other Nitrogen Derivatives; 7. Substitution and Elimination of NO(2) in R-NO(2); 7.1 R-Nu from R-NO(2); 7.1.1 Radical Reactions (S(RN)1) 7.1.2 Ionic Process7.1.3 Intramolecular Nucleophilic Substitution Reaction; 7.1.4 Allylic Rearrangement; 7.2 R-H from R-NO(2); 7.2.1 Radical Denitration; 7.2.2 Ionic Denitration; 7.3 Alkenes from R-NO(2); 7.3.1 Radical Elimination; 7.3.2 Ionic Elimination of Nitro Compounds; 8. Cycloaddition Chemistry of Nitro Compounds; 8.1 Diels-Alder Reactions; 8.1.1 Nitroalkenes Using Dienophiles; 8.1.2 Asymmetric Diels-Alder Reaction; 8.2 1,3-Dipolar Cycloaddition; 8.2.1 Nitrones; 8.2.2 Nitrile Oxides; 8.2.3 Nitronates; 8.3 Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition 8.3.1 Nitroalkenes as Heterodienes |
Record Nr. | UNINA-9910146072203321 |
Ono Noboru
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||
New York, : Wiley-VCH, c2001 | ||
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Lo trovi qui: Univ. Federico II | ||
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The nitro group in organic synthesis [[electronic resource] /] / Noboru Ono |
Autore | Ono Noboru |
Pubbl/distr/stampa | New York, : Wiley-VCH, c2001 |
Descrizione fisica | 1 online resource (390 p.) |
Disciplina |
547.040459
547/.2 |
Collana | Organic nitro chemistry series |
Soggetto topico |
Organic compounds - Synthesis
Nitro compounds |
ISBN |
1-280-36618-4
9786610366187 0-470-25024-0 0-471-45846-5 0-471-22448-0 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
THE NITRO GROUP IN ORGANIC SYNTHESIS; CONTENTS; Series Foreword; Preface; Acknowledgments; Abbreviations; 1. Introduction; 2. Preparation of Nitro Compounds; 2.1 Nitration of Hydrocarbons; 2.1.1 Aromatic Compounds; 2.1.2 Alkanes; 2.1.3 Activated C-H Compounds; 2.1.4 Alkenes; 2.1.5 Synthesis of a-Nitro Ketones; 2.1.6 Nitration of Alkyl Halides; 2.2 Synthesis of Nitro Compounds by Oxidation; 2.2.1 Oxidation of Amines; 2.2.2 Oxidation of Oximes; 3.The Nitro-Aldol (Henry) Reaction; 3.1 Preparation of b-Nitro Alcohols; 3.2 Derivatives from b-Nitro Alcohols; 3.2.1 Nitroalkenes; 3.2.2 Nitroalkanes
3.2.3 a-Nitro Ketones3.2.4 b-Amino Alcohols; 3.2.5 Nitro Sugars and Amino Sugars; 3.3 Stereoselective Henry Reactions and Applications to Organic Synthesis; 4. Michael Addition; 4.1 Addition to Nitroalkenes; 4.1.1 Conjugate Addition of Heteroatom-Centered Nucleophiles; 4.1.2 Conjugate Addition of Heteroatom Nucleophiles and Subsequent Nef Reaction; 4.1.3 Conjugate Addition of Carbon-Centered Nucleophiles; 4.2 Addition and Elimination Reaction of b-Heterosubstituted Nitroalkenes; 4.3 Michael Addition of Nitroalkanes; 4.3.1 Intermolecular Addition; 4.3.2 Intramolecular Addition 4.4 Asymmetric Michael Addition4.4.1 Chiral Alkenes and Chiral Nitro Compounds; 4.4.2 Chiral Catalysts; 5. Alkylation, Acylation, and Halogenation of Nitro Compounds; 5.1 Alkylation of Nitro Compounds; 5.2 Acylation of Nitroalkanes; 5.3 Ring Cleavage of Cyclic a-Nitro Ketones (Retro-Acylation); 5.4 Alkylation of Nitro Compounds via Alkyl Radicals; 5.5 Alkylation of Nitro Compounds Using Transition Metal Catalysis; 5.5.1 Butadiene Telomerization; 5.5.2 Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds; 5.6 Arylation of Nitro Compounds; 5.7 Introduction of Heteroatoms to Nitroalkanes 6. Conversion of Nitro Compounds into Other Compounds6.1 Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids); 6.1.1 Treatment With Acid (Classical Procedure); 6.1.2 Oxidative Method; 6.1.3 Reductive Method; 6.1.4 Direct Conversion of Nitroalkenes to Carbonyl Compounds; 6.2 Nitrile Oxides and Nitriles; 6.3 Reduction of Nitro Compounds into Amines; 6.3.1 Ar-NH(2) From Ar-NO(2); 6.3.2 R-NH(2) from R-NO(2); 6.3.3 Oximes, Hydroxylamines, and Other Nitrogen Derivatives; 7. Substitution and Elimination of NO(2) in R-NO(2); 7.1 R-Nu from R-NO(2); 7.1.1 Radical Reactions (S(RN)1) 7.1.2 Ionic Process7.1.3 Intramolecular Nucleophilic Substitution Reaction; 7.1.4 Allylic Rearrangement; 7.2 R-H from R-NO(2); 7.2.1 Radical Denitration; 7.2.2 Ionic Denitration; 7.3 Alkenes from R-NO(2); 7.3.1 Radical Elimination; 7.3.2 Ionic Elimination of Nitro Compounds; 8. Cycloaddition Chemistry of Nitro Compounds; 8.1 Diels-Alder Reactions; 8.1.1 Nitroalkenes Using Dienophiles; 8.1.2 Asymmetric Diels-Alder Reaction; 8.2 1,3-Dipolar Cycloaddition; 8.2.1 Nitrones; 8.2.2 Nitrile Oxides; 8.2.3 Nitronates; 8.3 Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition 8.3.1 Nitroalkenes as Heterodienes |
Record Nr. | UNINA-9910830330503321 |
Ono Noboru
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||
New York, : Wiley-VCH, c2001 | ||
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Lo trovi qui: Univ. Federico II | ||
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The nitro group in organic synthesis [[electronic resource] /] / Noboru Ono |
Autore | Ono Noboru |
Pubbl/distr/stampa | New York, : Wiley-VCH, c2001 |
Descrizione fisica | 1 online resource (390 p.) |
Disciplina |
547.040459
547/.2 |
Collana | Organic nitro chemistry series |
Soggetto topico |
Organic compounds - Synthesis
Nitro compounds |
ISBN |
1-280-36618-4
9786610366187 0-470-25024-0 0-471-45846-5 0-471-22448-0 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
THE NITRO GROUP IN ORGANIC SYNTHESIS; CONTENTS; Series Foreword; Preface; Acknowledgments; Abbreviations; 1. Introduction; 2. Preparation of Nitro Compounds; 2.1 Nitration of Hydrocarbons; 2.1.1 Aromatic Compounds; 2.1.2 Alkanes; 2.1.3 Activated C-H Compounds; 2.1.4 Alkenes; 2.1.5 Synthesis of a-Nitro Ketones; 2.1.6 Nitration of Alkyl Halides; 2.2 Synthesis of Nitro Compounds by Oxidation; 2.2.1 Oxidation of Amines; 2.2.2 Oxidation of Oximes; 3.The Nitro-Aldol (Henry) Reaction; 3.1 Preparation of b-Nitro Alcohols; 3.2 Derivatives from b-Nitro Alcohols; 3.2.1 Nitroalkenes; 3.2.2 Nitroalkanes
3.2.3 a-Nitro Ketones3.2.4 b-Amino Alcohols; 3.2.5 Nitro Sugars and Amino Sugars; 3.3 Stereoselective Henry Reactions and Applications to Organic Synthesis; 4. Michael Addition; 4.1 Addition to Nitroalkenes; 4.1.1 Conjugate Addition of Heteroatom-Centered Nucleophiles; 4.1.2 Conjugate Addition of Heteroatom Nucleophiles and Subsequent Nef Reaction; 4.1.3 Conjugate Addition of Carbon-Centered Nucleophiles; 4.2 Addition and Elimination Reaction of b-Heterosubstituted Nitroalkenes; 4.3 Michael Addition of Nitroalkanes; 4.3.1 Intermolecular Addition; 4.3.2 Intramolecular Addition 4.4 Asymmetric Michael Addition4.4.1 Chiral Alkenes and Chiral Nitro Compounds; 4.4.2 Chiral Catalysts; 5. Alkylation, Acylation, and Halogenation of Nitro Compounds; 5.1 Alkylation of Nitro Compounds; 5.2 Acylation of Nitroalkanes; 5.3 Ring Cleavage of Cyclic a-Nitro Ketones (Retro-Acylation); 5.4 Alkylation of Nitro Compounds via Alkyl Radicals; 5.5 Alkylation of Nitro Compounds Using Transition Metal Catalysis; 5.5.1 Butadiene Telomerization; 5.5.2 Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds; 5.6 Arylation of Nitro Compounds; 5.7 Introduction of Heteroatoms to Nitroalkanes 6. Conversion of Nitro Compounds into Other Compounds6.1 Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids); 6.1.1 Treatment With Acid (Classical Procedure); 6.1.2 Oxidative Method; 6.1.3 Reductive Method; 6.1.4 Direct Conversion of Nitroalkenes to Carbonyl Compounds; 6.2 Nitrile Oxides and Nitriles; 6.3 Reduction of Nitro Compounds into Amines; 6.3.1 Ar-NH(2) From Ar-NO(2); 6.3.2 R-NH(2) from R-NO(2); 6.3.3 Oximes, Hydroxylamines, and Other Nitrogen Derivatives; 7. Substitution and Elimination of NO(2) in R-NO(2); 7.1 R-Nu from R-NO(2); 7.1.1 Radical Reactions (S(RN)1) 7.1.2 Ionic Process7.1.3 Intramolecular Nucleophilic Substitution Reaction; 7.1.4 Allylic Rearrangement; 7.2 R-H from R-NO(2); 7.2.1 Radical Denitration; 7.2.2 Ionic Denitration; 7.3 Alkenes from R-NO(2); 7.3.1 Radical Elimination; 7.3.2 Ionic Elimination of Nitro Compounds; 8. Cycloaddition Chemistry of Nitro Compounds; 8.1 Diels-Alder Reactions; 8.1.1 Nitroalkenes Using Dienophiles; 8.1.2 Asymmetric Diels-Alder Reaction; 8.2 1,3-Dipolar Cycloaddition; 8.2.1 Nitrones; 8.2.2 Nitrile Oxides; 8.2.3 Nitronates; 8.3 Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition 8.3.1 Nitroalkenes as Heterodienes |
Record Nr. | UNINA-9910840864203321 |
Ono Noboru
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New York, : Wiley-VCH, c2001 | ||
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Lo trovi qui: Univ. Federico II | ||
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Organic preparations and procedures international [[electronic resource]] |
Pubbl/distr/stampa | [Newton Highlands, MA, : Organic Preparations and Procedures] |
Disciplina |
547/.2
547.2 |
Soggetto topico | Organic compounds - Synthesis |
ISSN | 1945-5453 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Periodico |
Lingua di pubblicazione | eng |
Record Nr. | UNISA-996216848603316 |
[Newton Highlands, MA, : Organic Preparations and Procedures] | ||
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Lo trovi qui: Univ. di Salerno | ||
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Organic preparations and procedures international |
Pubbl/distr/stampa | [Newton Highlands, MA, : Organic Preparations and Procedures] |
Disciplina |
547/.2
547.2 |
Soggetto topico | Organic compounds - Synthesis |
ISSN | 1945-5453 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Periodico |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910231851003321 |
[Newton Highlands, MA, : Organic Preparations and Procedures] | ||
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Lo trovi qui: Univ. Federico II | ||
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Organic reaction mechanisms 2008 [[electronic resource] /] / edited by A. C. Knipe |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, : John Wiley & Sons, c2011 |
Descrizione fisica | 1 online resource (549 p.) |
Disciplina |
547.139
547.2 547/.2 |
Altri autori (Persone) | KnipeA. C |
Collana | Organic reaction mechanisms |
Soggetto topico |
Organic reaction mechanisms
Chemical reactions |
Soggetto genere / forma | Electronic books. |
ISBN |
1-119-95688-9
1-283-37402-1 9786613374028 0-470-97953-4 0-470-97952-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ORGANIC REACTION MECHANISMS · 2008; CONTENTS; 1. Reactions of Aldehydes and Ketones and their Derivatives; 2. Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives; 3. Oxidation and Reduction; 4. Carbenes and Nitrenes; 5. Nucleophilic Aromatic Substitution; 6. Electrophilic Aromatic Substitution; 7. Carbocations; 8. Nucleophilic Aliphatic Substitution; 9. Carbanions and Electrophilic Aliphatic Substitution; 10. Elimination Reactions; 11. Addition Reactions: Polar Addition; 12. Addition Reactions: Cycloaddition
13. Molecular Rearrangements: Part 1. Pericyclic Molecular Rearrangements14. Molecular Rearrangements: Part 2. Other Reactions; Author Index; Subject Index |
Record Nr. | UNINA-9910130967103321 |
Hoboken, : John Wiley & Sons, c2011 | ||
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Lo trovi qui: Univ. Federico II | ||
|
Organic reaction mechanisms 2008 [[electronic resource] /] / edited by A. C. Knipe |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, : John Wiley & Sons, c2011 |
Descrizione fisica | 1 online resource (549 p.) |
Disciplina |
547.139
547.2 547/.2 |
Altri autori (Persone) | KnipeA. C |
Collana | Organic reaction mechanisms |
Soggetto topico |
Organic reaction mechanisms
Chemical reactions |
ISBN |
1-119-95688-9
1-283-37402-1 9786613374028 0-470-97953-4 0-470-97952-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ORGANIC REACTION MECHANISMS · 2008; CONTENTS; 1. Reactions of Aldehydes and Ketones and their Derivatives; 2. Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives; 3. Oxidation and Reduction; 4. Carbenes and Nitrenes; 5. Nucleophilic Aromatic Substitution; 6. Electrophilic Aromatic Substitution; 7. Carbocations; 8. Nucleophilic Aliphatic Substitution; 9. Carbanions and Electrophilic Aliphatic Substitution; 10. Elimination Reactions; 11. Addition Reactions: Polar Addition; 12. Addition Reactions: Cycloaddition
13. Molecular Rearrangements: Part 1. Pericyclic Molecular Rearrangements14. Molecular Rearrangements: Part 2. Other Reactions; Author Index; Subject Index |
Record Nr. | UNINA-9910829912903321 |
Hoboken, : John Wiley & Sons, c2011 | ||
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Lo trovi qui: Univ. Federico II | ||
|
Organic reaction mechanisms 2008 [[electronic resource] /] / edited by A. C. Knipe |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, : John Wiley & Sons, c2011 |
Descrizione fisica | 1 online resource (549 p.) |
Disciplina |
547.139
547.2 547/.2 |
Altri autori (Persone) | KnipeA. C |
Collana | Organic reaction mechanisms |
Soggetto topico |
Organic reaction mechanisms
Chemical reactions |
ISBN |
1-119-95688-9
1-283-37402-1 9786613374028 0-470-97953-4 0-470-97952-6 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ORGANIC REACTION MECHANISMS · 2008; CONTENTS; 1. Reactions of Aldehydes and Ketones and their Derivatives; 2. Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives; 3. Oxidation and Reduction; 4. Carbenes and Nitrenes; 5. Nucleophilic Aromatic Substitution; 6. Electrophilic Aromatic Substitution; 7. Carbocations; 8. Nucleophilic Aliphatic Substitution; 9. Carbanions and Electrophilic Aliphatic Substitution; 10. Elimination Reactions; 11. Addition Reactions: Polar Addition; 12. Addition Reactions: Cycloaddition
13. Molecular Rearrangements: Part 1. Pericyclic Molecular Rearrangements14. Molecular Rearrangements: Part 2. Other Reactions; Author Index; Subject Index |
Record Nr. | UNINA-9910841796803321 |
Hoboken, : John Wiley & Sons, c2011 | ||
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Lo trovi qui: Univ. Federico II | ||
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Organic reactions in water [[electronic resource] ] : principles, strategies and applications / / edited by U. Marcus Lindström |
Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 |
Descrizione fisica | 1 online resource (424 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) | LindströmU. Marcus <1971-> (Ulf Marcus) |
Soggetto topico |
Water chemistry
Solvents - Environmental aspects Organic compounds - Synthesis - Environmental aspects |
ISBN |
1-281-32026-9
9786611320263 0-470-98881-9 0-470-99424-X |
Classificazione |
35.52
35.51 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Organic Reactions in Water : Principles, Strategies and Applications; Contents; Contributors; Preface; Foreword; 1 A Fifty-Year Perspective on Chemistry in Water; 1.1 Enzyme mimics and models; 1.1.1 Thiamine; 1.1.2 Cyclodextrins; 1.1.3 Cyclodextrins with bound metal ions; 1.1.4 Cyclodextrin dimers; 1.1.5 Ribonuclease mimics; 1.1.6 Transaminase mimics; 1.1.7 Cytochrome P-450 mimics; 1.2 Reactions in water promoted by hydrophobic binding of small molecules; 1.2.1 Diels-Alder reactions; 1.2.2 The benzoin condensation; 1.2.3 Atom transfer reactions
1.3 Quantitative antihydrophobic effects in water and the geometries of transition states1.4 The importance of water as a reaction solvent; References; 2 Structure and Properties of Water; 2.1 Water, the molecule and the liquid; 2.1.1 The single water molecule; 2.1.2 Liquid water; 2.2 Properties of water; 2.2.1 Solvent properties and parameters; 2.2.2 Thermodynamics of hydration; 2.2.3 Hydrophobic interactions; 2.3 Kinetic solvent effects in aqueous solution; References; 3 Acid Catalysis in Water; 3.1 Homogeneous catalysis; 3.1.1 Bronsted acid catalysis; 3.1.2 Lewis acid catalysis 3.1.3 Asymmetric catalysis3.2 Heterogeneous catalysis; 3.2.1 Polymer-supported Bronsted catalysis; 3.2.2 Polymer-supported metal catalysis; 3.3 Micellar catalysis; 3.3.1 LASC (Lewis acid-surfactant-combined catalysts); 3.3.2 BASC (Bronsted acid-surfactant-combined catalyst); 3.4 Conclusion; References; 4 Metal-Mediated C-C Bond Formations in Aqueous Media; 4.1 Introduction; 4.2 Reactivity of organometallic compounds with water; 4.2.1 C-M bonding; 4.2.2 C-M hydrolysis; 4.2.3 C M-reactions; 4.2.4 C-C bond formations via C-M reactions in water; 4.3 Allylation of carbonyls and imines 4.3.1 Alyllation of carbonyl compounds4.3.2 Allylation of imines and related compounds; 4.4 Propargylation/allenylation of carbonyls, imines, and related compounds; 4.5 Metal-mediated benzylation of carbonyls and imines; 4.6 Arylation and vinylation of carbonyls and imines; 4.6.1 Arylation and vinylation of aldehydes; 4.6.2 Arylation and vinylation of imines and related compounds; 4.7 Alkynylation of carbonyls, imines, and related compounds; 4.7.1 Alkynylation of aldehydes; 4.7.2 Alkynylation of imines and related compounds; 4.7.3 Asymmetric alkynylation 4.8 Metal-mediated aldol and Reformatsky-type reactions4.9 Metal-mediated alkylation of carbonyls and imines; 4.9.1 Alkylation of aldehydes; 4.9.2 Alkylation of imines; 4.10 Metal-mediated conjugate addition reactions; 4.10.1 Addition of alkyl groups; 4.10.2 Addition of vinyl and aryl groups; 4.10.3 Addition of alkynes; 4.11 Metal-mediated coupling reactions; 4.11.1 Pinacol coupling; 4.11.2 Other reductive couplings; 4.11.3 Cross-dehydrogenative coupling; 4.12 Conclusion; References; 5 Pericyclic Reactions in Aqueous Media; 5.1 Diels-Alder cycloaddition reactions 5.1.1 Carbo Diels-Alder reactions |
Record Nr. | UNINA-9910145417103321 |
Oxford ; ; Ames, Iowa, : Blackwell Pub., 2007 | ||
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Lo trovi qui: Univ. Federico II | ||
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