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Photochemistry of organic compounds [[electronic resource] ] : from concepts to practice / / Petr Klán, Jakob Wirz
| Photochemistry of organic compounds [[electronic resource] ] : from concepts to practice / / Petr Klán, Jakob Wirz |
| Autore | Klán Petr |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (583 p.) |
| Disciplina |
541.35
572.435 |
| Altri autori (Persone) | WirzJakob |
| Collana | Postgraduate chemistry series |
| Soggetto topico |
Organic compounds - Synthesis
Organic photochemistry |
| ISBN |
1-282-01326-2
9786612013263 1-4443-0001-6 1-4443-0000-8 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Photochemistry Of Organic Compounds: From Concepts To Practice; Contents; Special Topics; Case Studies; Foreword; Preface; 1 Introduction; 1.1 Who's Afraid of Photochemistry?; 1.2 Electromagnetic Radiation; 1.3 Perception of Colour; 1.4 Electronic States: Elements of Molecular Quantum Mechanics; 1.5 Problems; 2 A Crash Course in Photophysics and a Classification of Primary Photoreactions; 2.1 Photophysical Processes; 2.1.1 State Diagrams; 2.1.2 Beer-Lambert Law; 2.1.3 Calculation of Fluorescence Rate Constants from Absorption Spectra; 2.1.4 Dipole and Transition Moments, Selection Rules
2.1.5 Rate Constants of Internal Conversion the Energy Gap Law; 2.1.6 Rate Constants of Intersystem Crossing, El Sayed Rules; 2.1.7 Quantum Yield: Definition; 2.1.8 Kasha and Vavilov Rules; 2.1.9 Franck-Condon Principle; 2.2 Energy Transfer, Quenching and Sensitization; 2.2.1 Diffusion-Controlled Reactions in Solution, Spin Statistics; 2.2.2 Energy Transfer; 2.2.3 Excimers and Exciplexes; 2.2.4 Delayed Fluorescence; 2.2.5 Dioxygen; 2.3 A Classification of Photochemical Reaction Pathways; 2.4 Problems; 3 Techniques and Methods; 3.1 Light Sources, Filters and Detectors 3.2 Preparative Irradiation3.3 Absorption Spectra; 3.4 Steady-State Emission Spectra and their Correction; 3.5 Time-Resolved Luminescence; 3.6 Absorption and Emission Spectroscopy with Polarized Light; 3.7 Flash Photolysis; 3.7.1 Kinetic Flash Photolysis; 3.7.2 Spectrographic Detection Systems; 3.7.3 Pump-Probe Spectroscopy; 3.7.4 Analysis of Kinetic Data; 3.7.5 Global Analysis of Transient Optical Spectra; 3.8 Time-Resolved IR and Raman Spectroscopy; 3.9 Quantum Yields; 3.9.1 Differential Quantum Yield; 3.9.2 Actinometry; 3.9.3 Spectrophotometric Determination of the Reaction Progress 3.9.4 Reversible Photoreactions3.9.5 Luminescence Quantum Yields; 3.9.6 Polychromatic Actinometry and Heterogeneous Systems; 3.9.7 Relating Quantum Yields to Rate Constants; 3.9.8 Stern-Volmer Analysis; 3.9.9 Quantum Yields of Triplet Formation; 3.9.10 Experimental Arrangements for Quantum Yield Measurements; 3.10 Low-Temperature Studies; Matrix Isolation; 3.11 Photoacoustic Calorimetry; 3.12 Two-Photon Absorption Spectroscopy; 3.13 Single-Molecule Spectroscopy; 3.14 Problems; 4 Quantum Mechanical Models of Electronic Excitation and Photochemical Reactivity 4.1 Boiling Down the Schrödinger Equation4.2 Hückel Molecular Orbital Theory; 4.3 HMO Perturbation Theory; 4.4 Symmetry Considerations; 4.5 Simple Quantum Chemical Models of Electronic Excitation; 4.6 Pairing Theorems and Dewar's PMO Theory; 4.7 The Need for Improvement; SCF, CI and DFT Calculations; 4.8 Spin-Orbit Coupling; 4.9 Theoretical Models of Photoreactivity, Correlation Diagrams; 4.10 Problems; 4.11 Appendix; 4.11.1 First-Order Perturbation; 4.11.2 Second-Order Perturbation; 5 Photochemical Reaction Mechanisms and Reaction Intermediates; 5.1 What is a Reaction Mechanism? 5.2 Electron Transfer |
| Record Nr. | UNINA-9910145822603321 |
Klán Petr
|
||
| Chichester, U.K., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Photochemistry of organic compounds [[electronic resource] ] : from concepts to practice / / Petr Klán, Jakob Wirz
| Photochemistry of organic compounds [[electronic resource] ] : from concepts to practice / / Petr Klán, Jakob Wirz |
| Autore | Klán Petr |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (583 p.) |
| Disciplina |
541.35
572.435 |
| Altri autori (Persone) | WirzJakob |
| Collana | Postgraduate chemistry series |
| Soggetto topico |
Organic compounds - Synthesis
Organic photochemistry |
| ISBN |
1-282-01326-2
9786612013263 1-4443-0001-6 1-4443-0000-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Photochemistry Of Organic Compounds: From Concepts To Practice; Contents; Special Topics; Case Studies; Foreword; Preface; 1 Introduction; 1.1 Who's Afraid of Photochemistry?; 1.2 Electromagnetic Radiation; 1.3 Perception of Colour; 1.4 Electronic States: Elements of Molecular Quantum Mechanics; 1.5 Problems; 2 A Crash Course in Photophysics and a Classification of Primary Photoreactions; 2.1 Photophysical Processes; 2.1.1 State Diagrams; 2.1.2 Beer-Lambert Law; 2.1.3 Calculation of Fluorescence Rate Constants from Absorption Spectra; 2.1.4 Dipole and Transition Moments, Selection Rules
2.1.5 Rate Constants of Internal Conversion the Energy Gap Law; 2.1.6 Rate Constants of Intersystem Crossing, El Sayed Rules; 2.1.7 Quantum Yield: Definition; 2.1.8 Kasha and Vavilov Rules; 2.1.9 Franck-Condon Principle; 2.2 Energy Transfer, Quenching and Sensitization; 2.2.1 Diffusion-Controlled Reactions in Solution, Spin Statistics; 2.2.2 Energy Transfer; 2.2.3 Excimers and Exciplexes; 2.2.4 Delayed Fluorescence; 2.2.5 Dioxygen; 2.3 A Classification of Photochemical Reaction Pathways; 2.4 Problems; 3 Techniques and Methods; 3.1 Light Sources, Filters and Detectors 3.2 Preparative Irradiation3.3 Absorption Spectra; 3.4 Steady-State Emission Spectra and their Correction; 3.5 Time-Resolved Luminescence; 3.6 Absorption and Emission Spectroscopy with Polarized Light; 3.7 Flash Photolysis; 3.7.1 Kinetic Flash Photolysis; 3.7.2 Spectrographic Detection Systems; 3.7.3 Pump-Probe Spectroscopy; 3.7.4 Analysis of Kinetic Data; 3.7.5 Global Analysis of Transient Optical Spectra; 3.8 Time-Resolved IR and Raman Spectroscopy; 3.9 Quantum Yields; 3.9.1 Differential Quantum Yield; 3.9.2 Actinometry; 3.9.3 Spectrophotometric Determination of the Reaction Progress 3.9.4 Reversible Photoreactions3.9.5 Luminescence Quantum Yields; 3.9.6 Polychromatic Actinometry and Heterogeneous Systems; 3.9.7 Relating Quantum Yields to Rate Constants; 3.9.8 Stern-Volmer Analysis; 3.9.9 Quantum Yields of Triplet Formation; 3.9.10 Experimental Arrangements for Quantum Yield Measurements; 3.10 Low-Temperature Studies; Matrix Isolation; 3.11 Photoacoustic Calorimetry; 3.12 Two-Photon Absorption Spectroscopy; 3.13 Single-Molecule Spectroscopy; 3.14 Problems; 4 Quantum Mechanical Models of Electronic Excitation and Photochemical Reactivity 4.1 Boiling Down the Schrödinger Equation4.2 Hückel Molecular Orbital Theory; 4.3 HMO Perturbation Theory; 4.4 Symmetry Considerations; 4.5 Simple Quantum Chemical Models of Electronic Excitation; 4.6 Pairing Theorems and Dewar's PMO Theory; 4.7 The Need for Improvement; SCF, CI and DFT Calculations; 4.8 Spin-Orbit Coupling; 4.9 Theoretical Models of Photoreactivity, Correlation Diagrams; 4.10 Problems; 4.11 Appendix; 4.11.1 First-Order Perturbation; 4.11.2 Second-Order Perturbation; 5 Photochemical Reaction Mechanisms and Reaction Intermediates; 5.1 What is a Reaction Mechanism? 5.2 Electron Transfer |
| Record Nr. | UNINA-9910818229403321 |
|
Klán Petr
|
||
| Chichester, U.K., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||