Nanometal Catalysis in Organic Synthesis

• Autore: Bao Ming
• Pubblicazione: Singapore : , : Springer, , 2024; ©2024
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (228 pages)
• Altri autori: WangJiasheng FengXiujuan LuoJingjie SunJian
• Nota di contenuto: Intro -- Contents -- 1 Introduction -- 1.1 Catalysts and Catalytic Reactions -- 1.2 Classification of Catalysts -- 1.3 Homogeneous Catalysts -- 1.3.1 Effectivity -- 1.3.2 Property -- 1.3.3 Mechanism -- 1.3.4 Application Fields -- 1.4 Heterogeneous Catalysts -- 1.4.1 Effectivity -- 1.4.2 Property -- 1.4.3 Mechanism -- 1.4.4 Application Fields -- 1.5 Some Famous Industrial Catalysts -- 1.5.1 Catalyst for Synthesis of Sulfuric Acid -- 1.5.2 Catalyst for Synthesis of Ammonia -- 1.5.3 Catalyst for Fischer-Tropsch Synthesis -- 1.5.4 Catalyst for Petroleum Refining -- 1.5.5 Catalyst for Olefin Polymerization: Ziegler-Natta Catalyst -- 1.5.6 Three-Way Catalyst for Treatment of Automobile Tail Gases -- 1.5.7 Catalyst for Asymmetric Synthesis -- 1.6 Nobel Prize in Chemistry for Catalytic Organic Synthesis -- 1.7 Conclusion -- 2 Organic Synthesis Catalyzed by Metal Nanoparticles -- 2.1 Metal Colloid and Ex-Situ Synthesis of Supported Metal Particles -- 2.1.1 Synthesis and Characteristics of Metal Colloid -- 2.1.2 Metal Colloid as Catalyst Precursor for Heterogeneous Reactions -- 2.2 In Situ Self-Growth of Supported Metal Particles -- 2.2.1 Impregnation Method -- 2.2.2 Deposition-Precipitation and Co-precipitation -- 2.2.3 So-Gel Method -- 2.2.4 Atomic Layer Deposition -- 2.2.5 Thermal Treatment After Synthesis -- 2.3 Essential Roles for Catalytic Performances -- 2.3.1 Characterization -- 2.3.2 Chemical Composition and Surface States -- 2.3.3 Morphology and Spatial Structure of Active Sites -- 2.3.4 In Situ FTIR Spectra for Studying Kinetics and Mechanism -- 2.3.5 Thermoanalysis Technology -- 2.3.6 Evaluation of the Supported Nanoparticles -- 2.4 Organic Reactions -- 2.4.1 Supported Gold Nanoparticles -- 2.4.2 Platinum Group Metal -- 2.4.3 Rhenium Nanoparticles for Petroleum Refining -- 2.4.4 Non-precious Transition Metal Nanoparticles. ; 2.5 Summary and Outlooks -- References -- 3 Organic Synthesis Catalyzed by Metal Nanoclusters -- 3.1 Synthesis Methods of MNCs -- 3.1.1 Direct Synthesis Method -- 3.1.2 Ligand-Exchange Method -- 3.1.3 Chemical Etching Method -- 3.1.4 Metal-Exchange Method -- 3.1.5 Separation Method -- 3.1.6 Electrochemical Synthesis Method -- 3.1.7 Support Method -- 3.1.8 Atomic Layer Deposition Method -- 3.1.9 Photo-Induction Reduction Method -- 3.2 Characterizations of MNCs -- 3.2.1 UV-Vis Spectroscopy -- 3.2.2 Fourier Transform Infrared (FT-IR) Spectroscopy -- 3.2.3 X-ray Diffraction (XRD) Spectroscopy -- 3.2.4 X-Ray Photoelectron Spectroscopy (XPS) -- 3.2.5 Electron Microscopy -- 3.2.6 Mass Spectrometry (MS) -- 3.2.7 Nuclear Magnetic Resonance (NMR) Spectroscopy -- 3.2.8 Thermogravimetric Analysis (TGA) -- 3.2.9 X-Ray Absorption Spectroscopy (XAS) -- 3.3 Organic Reactions Catalyzed by MNCs -- 3.3.1 MNCs of Monometallic -- 3.3.2 MNCs of Bimetallic Alloy -- 3.3.3 MNCs of Trimetallic Alloy -- 3.4 Conclusion and Outlook -- References -- 4 Organic Synthesis Catalyzed by Supported Metal Single-Atom Catalysts -- 4.1 Introduction -- 4.2 Preparation of Supported Metal SACs -- 4.2.1 Mass-Selected Soft-Landing Techniques -- 4.2.2 Atomic Layer Deposition (ALD) -- 4.2.3 Wet-Chemistry Approaches -- 4.2.4 High-Temperature Pyrolysis -- 4.2.5 Ball Milling -- 4.2.6 Metal Leaching Method -- 4.2.7 Photoreduction Method -- 4.3 Characterization -- 4.3.1 Aberration-Corrected High-Resolution Transmission Electron Microscopy -- 4.3.2 X-Ray Absorption Fine Structure Spectroscopy (XAFS) -- 4.3.3 Fourier Transform Infrared (FTIR) Spectroscopy -- 4.3.4 X-Ray Photoelectron Spectroscopy (XPS) -- 4.4 Catalysis -- 4.4.1 Oxidation -- 4.4.2 Hydrogenation -- 4.4.3 Addition -- 4.4.4 Coupling -- 4.4.5 Hydroformylation of Olefins -- 4.5 Conclusion and Outlook -- References. ; 5 Organic Synthesis Catalyzed by Nanoporous Metals -- 5.1 Nanoporous Au Catalyst -- 5.1.1 Oxidation Reactions -- 5.1.2 Reduction Reactions -- 5.1.3 Other Reactions -- 5.2 Nanoporous Pd Catalyst -- 5.2.1 Cross-Coupling Reactions -- 5.2.2 Reduction Reactions -- 5.3 Nanoporous Ag Catalyst -- 5.4 Nanoporous Ru Catalyst -- 5.5 Nanoporous Ni Catalyst -- 5.6 Nanoporous Cu Catalyst -- 5.7 Nanoporous AuPd Catalyst -- 5.8 Nanoporous PtRu Catalyst -- 5.9 Nanoporous PtFe Catalyst -- 5.9.1 Nanoporous PtCo/Co3O4 Catalyst -- 5.9.2 Nanoporous Au Functionalized with Ce-TiOx or Pr-TiOx Catalyst -- 5.10 Summary and Outlooks -- References -- 6 Conclusions and Outlook.
• Titolo autorizzato: Nanometal Catalysis in Organic Synthesis
• ISBN: 9789819745739; 9789819745722
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910874667803321
• Lo trovi qui: Univ. Federico II
• Serie: Molecular Catalysis Series