High-throughput screening in heterogeneous [i.e. chemical] catalysis [[electronic resource] /] / edited by Alfred Hagemeyer, Peter Strasser, Anthony F. Volpe, Jr

• Pubblicazione: Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
• Descrizione fisica: 1 online resource (341 p.)
• Disciplina: 541.395
• Soggetto topico: Heterogeneous catalysis; Catalysis
• Altri autori: HagemeyerAlfred StrasserPeter VolpeAnthony F
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: High-Throughput Screening in Heterogeneous Catalysis; Foreword; Preface; Contents; List of Contributors; 1 Impact of High-Throughput Screening Technologies on Chemical Catalysis; 1.1 Introduction; 1.2 Application of HT-R&D Methods in Heterogeneous Catalysis; 1.3 Application of HT-R&D Methods in Homogeneous Catalysis; 1.4 Conclusions; 1.5 References; 2 Mastering the Challenges of Catalyst Screening in High-Throughput Experimentation for Heterogeneously Catalyzed Gas-phase Reactions; 2.1 Challenges Connected to Catalyst Screening in Gas-phase Catalysis; 2.2 Preparative Aspects ; 2.3 Analytical Aspects2.3.1 Stage I Screening; 2.3.2 Stage II Screening; 2.3.3 King-System: Saving Analysis Time via Intelligent Use of Analysis Techniques; 2.4 Case Studies of Selected Examples in Gas-phase Catalysis in Stage II Screening; 2.4.1 Bulk Chemicals and Intermediates: Partial Oxidation; 2.4.2 Refinery Catalysis: High-pressure Reactions; 2.4.3 Environmental Catalysis: DeNOx Catalysis; 2.5 The Challenge of Ultrahigh-Throughput Screening; 2.5.1 Catalyst Synthesis: the Split & Pool Principle; 2.5.2 Catalyst Testing: Integrated Reactor Formats as Critical Key Components ; 2.6 Summary and Outlook2.7 References; 3 High-Throughput Workflow Development: Strategies and Examples in Heterogeneous Catalysis; 3.1 Introduction; 3.2 High-Throughput Methods; 3.2.1 DOE - Designing Experiments Based on Statistics; 3.2.2 Constrained Optimization - Independent Variables; 3.2.3 Constrained Optimization - Dependent Variables; 3.2.4 Methods to Include Synthesis Hardware Constraints; 3.2.5 Process Simulation for Hardware Bottleneck Identification; 3.3 Workflow Components; 3.3.1 Primary Synthesis; 3.3.2 Primary Synthesis: Wafer-based Sol-gel and Evaporative Synthesis ; 3.3.3 Primary Synthesis: Wafer-based Impregnation Synthesis3.3.4 Primary Screening: Scanning Mass Spectrometer; 3.3.5 Primary Screening: Massively Parallel Microfluidic Reactor; 3.3.6 Secondary Synthesis: Bulk Impregnation; 3.3.7 Secondary Synthesis: Bulk Evaporation/Precipitation; 3.3.8 Secondary Synthesis: Hydrothermal; 3.3.9 Secondary Screening: 48-Channel Fixed-bed Reactor; 3.3.10 High-Throughput Catalyst Characterization; 3.3.11 Tertiary Screening; 3.4 Example: Ethane to Ethylene; 3.5 Example: Ethane to Acetic Acid; 3.6 Example: Propane to Acrylonitrile; 3.7 Summary; 3.8 References ; 4 Integrated Microreactor Set-ups for High-Throughput Screening and Methods for the Evaluation of "Low-density" Screening Data4.1 Introduction; 4.1.1 Pellet-type and Ceramic Reactors; 4.1.2 Multiple Microchannel Array Reactors; 4.1.3 Chip-type Reactors; 4.1.4 Well-type Reactors; 4.2 Steady-state Reactor Set-ups; 4.2.1 Methanol Steam Reforming; 4.2.2 Propane Steam Reforming; 4.2.3 Catalytic Methane Combustion and Methods for Sample Preparation; 4.2.3.1 Wet Chemical Procedure (Washcoating/Flow Impregnation); 4.2.3.2 Experimental and Discussion; 4.3 Transient-state Reactor Set-ups ; 4.3.1 Introduction
• Sommario/riassunto: Alfred Hagemeyer received his diploma degrees in chemistry, 1985, and physics, 1987, from the university of Dortmund, Germany, did his Ph.D. at the Max-Planck-Institute fuer Polymerforschung in Mainz, Germany, 1987-1989, was postdoc at the university of Bologna, Italy, 1990, was employed at BASF, corporate research, ammonia laboratory, Ludwigshafen, Germany, 1991-1996, and at Hoechst/Aventis, corporate research, department of heterogeneous catalysis, Frankfurt, Germany, 1996-1998, and joined Symyx Technologies, heterogeneous catalysis group, Santa Clara, CA, in 1998 where he is a Distinguished
• Titolo autorizzato: High-throughput screening in heterogeneous catalysis
• ISBN: 1-280-51965-7; 3-527-60410-3
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910830770403321
• Lo trovi qui: Univ. Federico II