Progress in inorganic chemistry . Volume 59 / / edited by Kenneth D. Karlin

• Pubblicazione: Hoboken, New Jersey : , : John Wiley & Sons, Inc., , 2014; ©2014
• Descrizione fisica: 1 online resource (593 p.)
• Disciplina: 546.851
• Soggetto topico: Chemistry, Inorganic - Experiments; Chemistry, Inorganic
• Persona (resp. second.): KarlinKenneth D.
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and indexes.
• Nota di contenuto: Progress in Inorganic Chemistry; Contents; Chapter 1: Iron Catalysis in Synthetic Chemistry; I. INTRODUCTION; II. ADDITION REACTIONS; A. Cycloadditions; 1. The [2+2] Cycloaddition; 2. The [3+2] Cycloaddition; 3. The [2+2+2] Cycloaddition; 4. The [4+2] Cycloaddition; B. Cyclopropanation; C. Aziridination and Aziridine Ring-Opening Reactions; D. Carbometalation of C-C Unsaturated Bond; E. Michael Addition; F. Barbier-Type Reaction; G. Kharasch Reaction; III. THE C-C BOND FORMATIONS VIA C-H FUNCTIONALIZATION; A. The C-H Arylation; 1. Direct Arylation With Organometallic Reagents ; 2. Direct Arylation With Aryl HalidesB. The C-C Bond Formation Via Cross-Dehydrogenative Coupling; 1. The CDC Between Two sp3 C-H Bonds; 2. The CDC Between sp3 and sp2 C-H Bonds; 3. The CDC Between sp3 and sp C-H Bonds; C. The C-C Bond Formation via Cross-Decarboxylative Coupling; D. The C-C Bond Formation via Alkene Insertion; E. Oxidative Coupling of Two C-H Bonds; IV. THE C-H BOND OXIDATION; A. Hydroxylation; B. Epoxidation; C. cis-Dihydroxylation; V. CROSS-COUPLING REACTIONS; A. Alkenyl Derivatives as Coupling Partners; B. Aryl Derivatives as Coupling Partners ; C. Alkyl Derivatives as Coupling Partners1. Low-Valent Iron Complex in Cross-Coupling Reactions; D. Acyl Derivatives as Coupling Partners; E. Iron-Catalyzed C-O, C-S, and C-N Cross-Coupling Reaction; F. Iron-Catalyzed Mizoraki-Heck Reaction; G. Iron-Catalyzed Negishi Coupling Reaction; H. Suzuki-Miyaura Coupling Reaction; I. Sonogashira Reaction; J. Mechanism of Cross-Coupling Reactions; K. Hydrocarboxylation; L. Enyne Cross-Coupling Reaction; VI. DIRECT C-N BOND FORMATION VIA C-H OXIDATION; VII. IRON-CATALYZED AMINATION; A. Allylic Aminations; B. Intramolecular Allylic Amination ; VIII. SULFOXIDATIONS AND SYNTHESIS OF SULFOXIMINES, SULFIMIDES, AND SULFOXIMIDESA. Sulfoxidation; B. Synthesis of Sulfoximines, Sulfimides, and Sulfoximides; 1. Mechanism; IX. REDUCTION REACTIONS; A. Hydrosilylation of Alkenes; B. Hydrosilylation of Aldehydes and Ketones; C. Hydrogenation of C-C Unsaturated Bonds; D. Hydrogenation of Ketones; E. Hydrogenation of Imines; F. Reduction of Nitroarene to Anilines; G. Hydrogenation of Carbon Dioxide and Bicarbonate; H. Amide Reduction; I. Reductive Aminations; X. TRIFLUOROMETHYLATION; XI. CONCLUSION; ACKNOWLEDGMENTS; ABBREVIATIONS; REFERENCES ; Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive SitesI. INTRODUCTION; A. Scope and Limitations; B. Cancer; C. Deoxyribonucleic Acid as a Target; II. PHOTODYNAMIC THERAPY; A. Requirements; B. Traditional PDT Agents; C. Ruthenium(II) Light Absorbers as PDT Agents; III. PLATINUM AND RHODIUM CENTERS AS BIOACTIVE SITES; A. Platinum(II) Based Chemotherapeutics; 1. Cisplatin; 2. Second and Third Generation Pt(II) Drugs ; B. Rhodium as a Bioactive Site
• Sommario/riassunto: This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers. The chapters of this volume are devoted to the following topics: Iron Catalysis in Synthetic Chemistry A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled t
• Titolo autorizzato: Progress in inorganic chemistry
• ISBN: 1-118-87003-4; 1-118-86999-0; 1-118-86988-5
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910830249403321
• Lo trovi qui: Univ. Federico II
• Serie: Progress in Inorganic Chemistry