Introduction to coordination chemistry / / Geoffrey A. Lawrance

• Autore: Lawrance Geoffrey A
• Pubblicazione: Chichester, West Sussex, : Wiley, 2010
• Edizione: 2nd ed.
• Descrizione fisica: xiii, 290 p. : ill
• Disciplina: 541/.2242
• Soggetto topico: Coordination compounds; Complex compounds
• Classificazione: 431.13; 541/.2242
• Note generali: Includes bibliographical references and index
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- Introduction to Coordination Chemistry -- Contents -- Preface -- Preamble -- 1 The Central Atom -- 1.1 Key Concepts in Coordination Chemistry -- 1.2 A Who's Who of Metal Ions -- 1.2.1 Commoners and 'Uncommoners' -- 1.2.2 Redefining Commoners -- 1.3 Metals in Molecules -- 1.3.1 Metals in the Natural World -- 1.3.2 Metals in Contrived Environments -- 1.3.3 Natural or Made-to-Measure Complexes -- 1.4 The Road Ahead -- Concept Keys -- Further Reading -- 2 Ligands -- 2.1 Membership: Being a Ligand -- 2.1.1 What Makes a Ligand? -- 2.1.2 Making Attachments - Coordination -- 2.1.3 Putting the Bite on Metals - Chelation -- 2.1.4 Do I Look Big on That? - Chelate Ring Size -- 2.1.5 Different Tribes - Donor Group Variation -- 2.1.6 Ligands with More Bite - Denticity -- 2.2 Monodentate Ligands - The Simple Type -- 2.2.1 Basic Binders -- 2.2.2 Amines Ain't Ammines - Ligand Families -- 2.2.3 Meeting More Metals - Bridging Ligands -- 2.3 Greed is Good - Polydentate Ligands -- 2.3.1 The Simple Chelate -- 2.3.2 More Teeth, Stronger Bite - Polydentates -- 2.3.3 Many-Armed Monsters - Introducing Ligand Shape -- 2.4 Polynucleating Species - Molecular Bigamists -- 2.4.1 When One is Not Enough -- 2.4.2 Vive la Difference - Mixed-metal Complexation -- 2.4.3 Supersized - Binding to Macromolecules -- 2.5 A Separate Race - Organometallic Species -- Concept Keys -- Further Reading -- 3 Complexes -- 3.1 The Central Metal Ion -- 3.2 Metal-Ligand Marriage -- 3.2.1 The Coordinate Bond -- 3.2.2 The Foundation of Coordination Chemistry -- 3.2.3 Complex Shape - Not Just Any Which Way -- 3.3 Holding On - The Nature of Bonding in Metal Complexes -- 3.3.1 An Ionic Bonding Model - Introducing Crystal Field Theory -- 3.3.2 A Covalent Bonding Model - Embracing Molecular Orbital Theory -- 3.3.3 Ligand Field Theory - Making Compromises -- 3.3.4 Bonding Models Extended. ; 3.4 Coupling - Polymetallic Complexes -- 3.5 Making Choices -- 3.5.1 Selectivity - Of all the Molecules in all the World, Why This One? -- 3.5.2 Preferences - Do You Like What I Like? -- 3.5.3 Complex Lifetimes - Together, Forever? -- 3.6 Complexation Consequences -- Concept Keys -- Further Reading -- 4 Shape -- 4.1 Getting in Shape -- 4.2 Forms of Complex Life - Coordination Number and Shape -- 4.2.1 One Coordination (ML) -- 4.2.2 Two Coordination (ML2) -- 4.2.3 Three Coordination (ML3) -- 4.2.4 Four Coordination (ML4) -- 4.2.5 Five Coordination (ML5) -- 4.2.6 Six Coordination (ML6) -- 4.2.7 Higher Coordination Numbers (ML7 to ML9) -- 4.3 Influencing Shape -- 4.3.1 Metallic Genetics - Metal Ion Influences -- 4.3.2 Moulding a Relationship - Ligand Influences -- 4.3.3 Chameleon Complexes -- 4.4 Isomerism - Real 3D Effects -- 4.4.1 Introducing Stereoisomers -- 4.4.2 Constitutional (Structural) Isomerism -- 4.4.3 Stereoisomerism: in Place - Positional Isomers -- in Space - Optical Isomers -- 4.4.4 What's Best? - Isomer Preferences -- 4.5 Sophisticated Shapes -- 4.5.1 Compounds of Polydentate Ligands -- 4.5.2 Encapsulation Compounds -- 4.5.3 Host-Guest Molecular Assemblies -- 4.6 Defining Shape -- Concept Keys -- Further Reading -- 5 Stability -- 5.1 The Makings of a Stable Relationship -- 5.1.1 Bedded Down - Thermodynamic Stability -- 5.1.2 Factors Influencing Stability of Metal Complexes -- 5.1.3 Overall Stability Constants -- 5.1.4 Undergoing Change - Kinetic Stability -- 5.2 Complexation - Will It Last? -- 5.2.1 Thermodynamic and Kinetic Stability -- 5.2.2 Kinetic Rate Constants -- 5.2.3 Lability and Inertness in Octahedral Complexes -- 5.3 Reactions -- 5.3.1 A New Partner - Substitution -- 5.3.2 A New Body - Stereochemical Change -- 5.3.3 A New Face - Oxidation-Reduction -- 5.3.4 A New Suit - Ligand-centred Reactions -- Concept Keys. ; Further Reading -- 6 Synthesis -- 6.1 Molecular Creation - Ways to Make Complexes -- 6.2 Core Metal Chemistry - Periodic Table Influences -- 6.2.1 s Block: Alkali and Alkaline Earth Metals -- 6.2.2 p Block: Main Group Metals -- 6.2.3 d Block: Transition Metals -- 6.2.4 f Block: Inner Transition Metals (Lanthanoids and Actinoids) -- 6.2.5 Beyond Natural Elements -- 6.3 Reactions Involving the Coordination Shell -- 6.3.1 Ligand Substitution Reactions in Aqueous Solution -- 6.3.2 Substitution Reactions in Nonaqueous Solvents -- 6.3.3 Substitution Reactions without using a Solvent -- 6.3.4 Chiral Complexes -- 6.3.5 Catalysed Reactions -- 6.4 Reactions Involving the Metal Oxidation State -- 6.5 Reactions Involving Coordinated Ligands -- 6.5.1 Metal-directed Reactions -- 6.5.2 Reactions of Coordinated Ligands -- 6.6 Organometallic Synthesis -- Concept Keys -- Further Reading -- 7 Properties -- 7.1 Finding Ways to Make Complexes Talk - Investigative Methods -- 7.2 Getting Physical - Methods and Outcomes -- 7.3 Probing the Life of Complexes - Using Physical Methods -- 7.3.1 Peak Performance - Illustrating Selected Physical Methods -- 7.3.2 Pretty in Red? - Colour and the Spectrochemical Series -- 7.3.3 A Magnetic Personality? - Paramagnetism and Diamagnetism -- 7.3.4 Ligand Field Stabilization -- Concept Keys -- Further Reading -- 8 A Complex Life -- 8.1 Life's a Metal Ion -- 8.1.1 Biological Ligands -- 8.1.2 Metal Ions in Biology -- 8.1.3 Classes of Metallobiomolecules -- 8.2 Metalloproteins and Metalloenzymes -- 8.2.1 Iron-containing Biomolecules -- 8.2.2 Copper-containing Biomolecules -- 8.2.3 Zinc-containing Biomolecules -- 8.2.4 Other Metal-containing Biomolecules -- 8.2.5 Mixed-Metal Proteins -- 8.3 Doing What Comes Unnaturally - Synthetic Biomolecules -- 8.4 A Laboratory-free Approach - In Silico Prediction -- Concept Keys -- Further Reading. ; 9 Complexes and Commerce -- 9.1 Kill or Cure? - Complexes as Drugs -- 9.1.1 Introducing Metallodrugs -- 9.1.2 Anticancer Drugs -- 9.1.3 Other Metallodrugs -- 9.2 How Much? - Analysing with Complexes -- 9.2.1 Fluoroimmunoassay -- 9.2.2 Fluoroionophores -- 9.3 Profiting from Complexation -- 9.3.1 Metal Extraction -- 9.3.2 Industrial Roles for Ligands and Coordination Complexes -- 9.4 Being Green -- 9.4.1 Complexation in Remediation -- 9.4.2 Better Ways to Synthesize Fine Organic Chemicals -- 9.5 Complex Futures -- 9.5.1 Taking Stock -- 9.5.2 Crystal Ball Gazing -- Concept Keys -- Further Reading -- Appendix A: Nomenclature -- Appendix B: Molecular Symmetry: The Point Group -- Index.
• Sommario/riassunto: ""Recommended. Lower-and upper-division undergraduates, two-year technical program students, and general readers." (Choice, 1 March 2011) "Overall then, I applaud this attempt to produce a slightly different and distinctive introduction to a major area of modern chemistry." (Reviews, December 2010).
• Titolo autorizzato: Introduction to coordination chemistry
• ISBN: 0470687134; 9780470687130
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910821141403321
• Lo trovi qui: Univ. Federico II