Organic chemistry : structure, mechanism, and synthesis / / Robert J. Ouellette and J. David Rawn

• Autore: Ouellette Robert J. <1938->
• Pubblicazione: San Diego, California ; ; Waltham, Maryland : , : Elsevier, , 2014; ©2014
• Descrizione fisica: 1 online resource (1241 p.)
• Disciplina: 547
• Soggetto topico: Chemistry, Organic
• Persona (resp. second.): RawnJ. David <1944->
• Note generali: Includes index.
• Nota di contenuto: Front Cover; Organic Chemistry:Structure, Mechanism, and Synthesis; Copyright; Dedication; Contents; Acknowledgments; Preface; Chapter 1: Structure and Bonding in Organic Compounds; 1.1 Brief Review of Atomic Structure; 1.2 Atomic Properties; 1.3 Ionic and Covalent Bonds; 1.4 Strategies for Writing Lewis Structures; 1.5 Formal Charge; 1.6 Molecular Geometry; 1.7 Resonance Structures; 1.8 Valence Shell Electron Pair Repulsion Theory; 1.9 Dipole Moments; 1.10 Molecular Orbital Theory; 1.11 The Hydrogen Molecule; 1.12 Bonding in Carbon Compounds; 1.13 SP3 Hybridization of Carbon in Methane ; 1.14 SP3 Hybridization of Carbon in Ethane1.15 SP2 Hybridization of Carbon in Ethene; 1.16 SP Hybridization of Carbon in Ethyne; 1.17 Effect of Hybridization on Bond Length and Bond Strength; 1.18 Hybridization of Nitrogen; 1.19 Hybridization of Oxygen; Exercises; Chapter 2 : Part I: Functional Groups and Their Properties; 2.1 Introduction to Functional Groups: Hydrocarbons and Haloalkanes; 2.2 Functional Groups that Contain Oxygen; 2.3 Functional Groups that Contain Nitrogen; 2.4 Functional Groups that Contain Sulfur; 2.5 Structural Formulas; 2.6 Bond-Line Structures; 2.7 Isomers ; Part II: Identification of Functional Groups by Infrared Spectroscopy2.8 Spectroscopy; 2.9 Infrared Spectroscopy; 2.10 Identifying Hydrocarbons; 2.11 Identifying Oxygen-Containing Compounds; 2.12 Identifying Nitrogen-Containing Compounds; 2.13 Bending Deformations; End-of-Chapter Exercises; Chapter 3: Introduction to Organic Reaction Mechanisms; 3.1 Acid-Base Reactions; 3.2 Chemical Equilibrium and Equilibrium Constants; 3.3 PH and PK Values; 3.4 Effect of Structure on Acidity; 3.5 Standard Free Energy Changes in Chemical Reactions; 3.6 Enthalpy Changes in Chemical Reactions ; 3.7 Bond Dissociation Energies3.8 Introduction to Reaction Mechanisms; 3.9 Structures and Stabilities of Carbon Radicals, Carbocations, and Carbanions; 3.10 Factors that Influence Reaction Rates; 3.11 Reaction Rate Theory; 3.12 Stability and Reactivity; End-of-Chapter Exercises; Chapter 4: Alkanes and Cycloalkanes: Structures and Reactions; 4.1 Classes of Hydrocarbons; 4.2 Alkanes; 4.3 Nomenclature of Alkanes; 4.4 Conformations of Alkanes; 4.5 Cycloalkanes; 4.6 Conformations of Cycloalkanes; 4.7 Conformational Mobility of Cyclohexane; 4.8 Monosubstituted Cyclohexanes ; 4.9 Disubstituted Cyclohexanes4.10 Polycyclic Molecules; 4.11 Physical Properties of Alkanes; 4.12 Stabilities of Alkyl Radicals; 4.13 Chlorination of an Alkane-A Radical Reaction; Exercises; Chapter 5: Alkenes Structures and Properties; 5.1 Alkenes; 5.2 Structure and Bonding of Alkenes; 5.3 Unsaturation Number; 5.4 Geometric Isomerism; 5.5 E,Z Nomenclature of Geometrical Isomers; 5.6 Nomenclature of Alkenes; 5.7 Physical Properties of Alkenes; 5.8 Stability of Alkenes; 5.9 Reduction of Alkenes; 5.10 Mechanism of Catalytic Hydrogenation; 5.11 Heats of Hydrogenation of Alkenes; Exercises ; Chapter 6: Alkenes: Addition Reactions
• Titolo autorizzato: Organic chemistry
• ISBN: 0-12-801082-7
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910808337003321
• Lo trovi qui: Univ. Federico II