Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang
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| Autore: |
Yang Jaemoon
|
| Titolo: |
Six-membered transition states in organic synthesis [[electronic resource] /] / Jaemoon Yang
|
| Pubblicazione: | Hoboken, N.J., : Wiley-Interscience, c2008 |
| Descrizione fisica: | 1 online resource (222 p.) |
| Disciplina: | 547.2 |
| 547/.2 | |
| Soggetto topico: | Reaction mechanisms (Chemistry) |
| Stereochemistry | |
| Organic compounds - Synthesis | |
| Note generali: | Description based upon print version of record. |
| Nota di bibliografia: | Includes bibliographical references and indexes. |
| Nota di contenuto: | SIX-MEMBERED TRANSITION STATES IN ORGANIC SYNTHESIS; CONTENTS; Preface; Acknowledgments; Introduction; 1 [3,3]-Sigmatropic Rearrangements; General Considerations; Reactions; 1.1 Claisen Rearrangement; 1.2 Johnson-Claisen Rearrangement; 1.3 Ireland-Claisen Rearrangement; 1.4 Cope Rearrangement; 1.5 Anionic Oxy-Cope Rearrangement; 1.6 Aza-Cope-Mannich Reaction; 2 Aldol Reactions; General Considerations; Reactions; 2.1 Asymmetric Syn-Aldol Reaction; 2.2 Asymmetric Anti-Aldol Reaction; 2.3 Proline-Catalyzed Asymmetric Aldol Reaction; 3 Metal Allylation Reactions; General Considerations; Reactions |
| 3.1 Boron Allylation Reaction3.2 Silicon Allylation Reaction; 4 Stereoselective Reductions; General Considerations; Reactions; 4.1 Diastereoselective Syn-Reduction of β-Hydroxy Ketones; 4.2 Diastereoselective Anti-Reduction of β-Hydroxy Ketones; 4.3 Asymmetric Reduction; List of Copyrighted Materials; Abbreviations; Subject Index; Scheme Index of Natural Products | |
| Sommario/riassunto: | This book furthers readers' understanding of the amazing features of six-membered transition states in stereoselective organic reactions. Comprehensive and logically organized, it covers reactions classified in four categories: [3,3]-sigmatropic rearrangements, aldol reactions, metal allylation reactions, and stereoselective reductions. There is a thorough discussion of each reaction category, along with computational studies that support a proposal of a six-membered state. The book assists professors, researchers, and students in proposing reasonable transition states for the description of n |
| Titolo autorizzato: | Six-membered transition states in organic synthesis |
| ISBN: | 1-281-23726-4 |
| 9786611237264 | |
| 0-470-19905-9 | |
| 0-470-19904-0 | |
| Formato: | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione: | Inglese |
| Record Nr.: | 9910830049403321 |
| Lo trovi qui: | Univ. Federico II |
| Opac: | Controlla la disponibilità qui |