Condensed-phase molecular spectroscopy and photophysics / / Anne Myers Kelley

• Autore: Kelley Anne Myers <1958->
• Pubblicazione: Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2023]; ©2023
• Edizione: Second edition.
• Descrizione fisica: 1 online resource (432 pages)
• Disciplina: 543.54
• Soggetto topico: Condensed matter - Spectra
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- Preface to Second Edition -- Preface to First Edition -- About the Companion Website -- Part I Background -- Chapter 1 Review of Time-Independent Quantum Mechanics -- 1.1 States, Operators, and Representations -- 1.2 Eigenvalue Problems and the Schrödinger Equation -- 1.3 Expectation Values, Uncertainty Relations -- 1.4 The Particle in a Box -- 1.5 Harmonic Oscillator -- 1.6 The Rigid Rotor and Angular Momentum -- 1.7 The Hydrogen Atom -- 1.8 Approximation Methods -- 1.9 Electron Spin -- 1.10 The Born-Oppenheimer Approximation -- 1.11 Molecular Orbitals -- 1.12 Energies and Time Scales -- Separation of Motions -- Problems -- References -- Chapter 2 Classical Description of Electromagnetic Radiation -- 2.1 Maxwell's Equations, Plane Waves, Electric and Magnetic Fields, Polarization -- 2.2 Fourier Transform Relationships Between Time and Frequency -- 2.3 Blackbody Radiation -- 2.4 Light Sources for Spectroscopy -- Problems -- References -- Chapter 3 Statistical Mechanics -- 3.1 The Partition Function -- 3.2 The Boltzmann Distribution -- Problems -- Chapter 4 Group Theory -- 4.1 Qualitative Aspects of Molecular Symmetry -- 4.2 Introductory Group Theory -- 4.3 Finding the Symmetries of Vibrational Modes of a Certain Type -- 4.4 Finding the Symmetries of All Vibrational Modes -- Problems -- References -- Part II Fundamentals of Spectroscopy -- Chapter 5 Radiation-Matter Interactions -- 5.1 The Time-Dependent Schrödinger Equation -- 5.2 Time-Dependent Perturbation Theory -- 5.3 Interaction of Matter with the Classical Radiation Field -- 5.4 Quantum-Mechanical Description of Radiation -- 5.5 Interaction of Matter with the Quantized Radiation Field -- Problems -- References -- Chapter 6 Absorption and Emission of Light -- 6.1 Einstein Coefficients for Absorption and Emission. ; 6.2 Other Measures of Absorption Strength -- 6.3 Radiative Lifetimes -- 6.4 Oscillator Strengths -- 6.5 Local Fields -- Problems -- References -- Chapter 7 System-Bath Interactions -- 7.1 Phenomenological Treatment of Relaxation and Lineshapes -- 7.2 The Density Matrix -- 7.3 Density Matrix Methods in Spectroscopy -- 7.4 Exact Density Matrix Solution for a Two-Level System -- Problems -- References -- Chapter 8 Atomic Spectroscopy -- 8.1 Electron Configuration -- 8.2 Addition of Angular Momenta -- 8.3 Term Symbols -- 8.4 Angular Momentum Coupling Schemes -- 8.5 Spin-Orbit Coupling -- 8.6 Energies and Selection Rules -- 8.7 Zeeman Effect -- 8.8 Hyperfine Splitting -- Problems -- References -- Chapter 9 Rotational Spectroscopy -- 9.1 Rotational Transitions of Diatomic Molecules -- 9.2 Rotational Transitions of Polyatomic Molecules - Spherical, Symmetric, Near-Symmetric, and Asymmetric Tops -- Problems -- Chapter 10 Molecular Vibrations and Infrared Spectroscopy -- 10.1 Vibrational and Rovibrational Transitions -- 10.2 Diatomic Vibrations -- 10.3 Anharmonicity -- 10.4 Polyatomic Molecular Vibrations -- Normal Modes -- 10.5 Vibration-Rotation Transitions -- 10.6 Symmetry Considerations -- 10.7 Isotopic Shifts -- 10.8 Solvent Effects on Vibrational Spectra -- Problems -- References -- Chapter 11 Electronic Spectroscopy -- 11.1 Electronic Transitions -- 11.2 Spin and Orbital Selection Rules -- 11.2.1 Electric Dipole Transitions -- 11.2.2 Electric Quadrupole Transitions -- 11.2.3 Magnetic Dipole Transitions -- 11.3 Vibronic Structure -- 11.4 Vibronic Coupling -- 11.5 The Jahn-Teller Effect -- 11.6 Considerations in Large Molecules -- 11.7 Solvent Effects on Electronic Spectra -- Problems -- Chapter 12 Photophysical Processes -- 12.1 Jablonski Diagrams -- 12.2 Quantum Yields and Lifetimes -- 12.3 Fermi's Golden Rule for Radiationless Transitions. ; 12.4 Internal Conversion and Intersystem Crossing -- 12.5 Bright State-Dark State Coupling and Intramolecular Vibrational Relaxation -- 12.6 Energy Transfer -- 12.7 Polarization and Molecular Reorientation in Solution -- Problems -- References -- Chapter 13 Light Scattering -- 13.1 Rayleigh Scattering from Particles -- 13.2 Classical Treatment of Molecular Raman and Rayleigh Scattering -- 13.3 Quantum Mechanical Treatment of Molecular Raman and Rayleigh Scattering -- 13.4 Nonresonant Raman Scattering -- 13.5 Symmetry Considerations and Depolarization Ratios in Raman Scattering -- 13.6 Resonance Raman Spectroscopy -- Problems -- References -- Part III Advanced and Specialized Topics in Spectroscopy -- Chapter 14 Nonlinear and Pump-Probe Spectroscopies -- 14.1 Linear and Nonlinear Susceptibilities -- 14.2 Multiphoton Absorption -- 14.3 Pump-Probe Spectroscopy: Transient Absorption and Stimulated Emission -- 14.4 Vibrational Oscillations and Impulsive Stimulated Scattering -- 14.5 Second Harmonic and Sum Frequency Generation -- 14.6 Four-Wave Mixing -- 14.7 Photon Echoes -- 14.8 Hyper-Raman Scattering -- 14.9 Broadband Stimulated Raman Scattering -- Problems -- References -- Chapter 15 Two-dimensional Spectroscopies -- 15.1 The Basics of Two-Dimensional Spectroscopy -- 15.2 Fourier Transform Spectroscopy -- 15.3 Implementation of Fourier Transform 2D Spectroscopy -- Problems -- References -- Chapter 16 Electron Transfer Processes -- 16.1 Charge-Transfer Transitions -- 16.2 Marcus Theory -- 16.3 Spectroscopy of Anions and Cations -- Problems -- References -- Chapter 17 Collections of Molecules -- 17.1 Van der Waals Molecules -- 17.2 Dimers and Aggregates -- 17.3 Localized and Delocalized Excited States -- 17.4 Conjugated Polymers -- Problems -- References -- Chapter 18 Metals and Plasmons -- 18.1 Dielectric Function of a Metal -- 18.2 Plasmons. ; 18.3 Spectroscopy of Metal Nanoparticles -- 18.4 Surface-Enhanced Raman and Fluorescence -- Problems -- References -- Chapter 19 Crystals -- 19.1 Crystal Lattices -- 19.2 Phonons in Crystals -- 19.3 Infrared and Raman Spectra -- 19.4 Phonons in Nanocrystals -- Problems -- References -- Chapter 20 Electronic Spectroscopy of Semiconductors -- 20.1 Band Structure -- 20.2 Direct and Indirect Transitions -- 20.3 Excitons -- 20.4 Defects -- 20.5 Semiconductor Nanocrystals -- Problems -- References -- Chapter 21 Single-Molecule Spectroscopy -- 21.1 Detection of Single-Molecule Signals -- 21.2 Verification of Single-Molecule Signals -- 21.3 Frequency Selection -- 21.4 Spatial Selection Using Far-Field Optics -- 21.5 Spatial Selection Using Near-Field Optics -- 21.6 What Can Be Learned from Studying One Molecule at a Time? -- Problems -- References -- Chapter 22 Time-Domain Treatment of Steady-State Spectroscopies -- 22.1 Time-Correlation Function Approach to IR and Raman Lineshapes -- 22.2 Time-Dependent Wavepacket Picture of Electronic Spectroscopy -- 22.3 Time-Dependent Wavepacket Picture of Resonance Raman Intensities -- Problems -- Appendix A Physical Constants, Unit Systems, and Conversion Factors -- A.1 Unit Systems Used in Chemistry and Physics -- A.2 Values of Physical Constants -- A.3 Useful Conversion Factors -- Appendix B Miscellaneous Mathematics Review -- B.1 Vectors -- B.2 Vector Operators -- B.3 Series Expansions -- Appendix C Matrices and Determinants -- C.1 Matrices -- C.2 Determinants -- C.3 Eigenvalue Problems -- Appendix D Character Tables for Some Common Point Groups -- Appendix E Fourier Transforms -- Index -- EULA.
• Sommario/riassunto: "This book comprehensively covers radiation-matter interactions for molecules in condensed phases along with metallic and semiconductor nanostructures. Organized and appropriate for both researchers and advanced students, the text differs from others through its emphasis on the molecule-environment interactions that strongly influence spectra in condensed phases alongside including spectroscopy and photophysics of molecular aggregates and molecular solids and of metals and semiconductors, as well as more modern topics such as two-dimensional and single-molecule spectroscopy. In this new 2nd edition, the author adds basic rotational spectroscopy and statistical mechanics; sections on some Raman scattering, two-dimensional spectroscopies, and single-molecule spectroscopies; and a chapter on time-domain pictures of steady-state spectroscopies"--
• Titolo autorizzato: Condensed-phase molecular spectroscopy and photophysics
• ISBN: 1-119-82927-5; 1-119-82929-1; 1-119-82928-3
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910830734203321
• Lo trovi qui: Univ. Federico II