The nitro group in organic synthesis [[electronic resource] /] / Noboru Ono

• Autore: Ono Noboru
• Pubblicazione: New York, : Wiley-VCH, c2001
• Descrizione fisica: 1 online resource (390 p.)
• Disciplina: 547.040459; 547/.2
• Soggetto topico: Organic compounds - Synthesis; Nitro compounds
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: THE NITRO GROUP IN ORGANIC SYNTHESIS; CONTENTS; Series Foreword; Preface; Acknowledgments; Abbreviations; 1. Introduction; 2. Preparation of Nitro Compounds; 2.1 Nitration of Hydrocarbons; 2.1.1 Aromatic Compounds; 2.1.2 Alkanes; 2.1.3 Activated C-H Compounds; 2.1.4 Alkenes; 2.1.5 Synthesis of a-Nitro Ketones; 2.1.6 Nitration of Alkyl Halides; 2.2 Synthesis of Nitro Compounds by Oxidation; 2.2.1 Oxidation of Amines; 2.2.2 Oxidation of Oximes; 3.The Nitro-Aldol (Henry) Reaction; 3.1 Preparation of b-Nitro Alcohols; 3.2 Derivatives from b-Nitro Alcohols; 3.2.1 Nitroalkenes; 3.2.2 Nitroalkanes ; 3.2.3 a-Nitro Ketones3.2.4 b-Amino Alcohols; 3.2.5 Nitro Sugars and Amino Sugars; 3.3 Stereoselective Henry Reactions and Applications to Organic Synthesis; 4. Michael Addition; 4.1 Addition to Nitroalkenes; 4.1.1 Conjugate Addition of Heteroatom-Centered Nucleophiles; 4.1.2 Conjugate Addition of Heteroatom Nucleophiles and Subsequent Nef Reaction; 4.1.3 Conjugate Addition of Carbon-Centered Nucleophiles; 4.2 Addition and Elimination Reaction of b-Heterosubstituted Nitroalkenes; 4.3 Michael Addition of Nitroalkanes; 4.3.1 Intermolecular Addition; 4.3.2 Intramolecular Addition ; 4.4 Asymmetric Michael Addition4.4.1 Chiral Alkenes and Chiral Nitro Compounds; 4.4.2 Chiral Catalysts; 5. Alkylation, Acylation, and Halogenation of Nitro Compounds; 5.1 Alkylation of Nitro Compounds; 5.2 Acylation of Nitroalkanes; 5.3 Ring Cleavage of Cyclic a-Nitro Ketones (Retro-Acylation); 5.4 Alkylation of Nitro Compounds via Alkyl Radicals; 5.5 Alkylation of Nitro Compounds Using Transition Metal Catalysis; 5.5.1 Butadiene Telomerization; 5.5.2 Pd-Catalyzed Allylic C-Alkylation of Nitro Compounds; 5.6 Arylation of Nitro Compounds; 5.7 Introduction of Heteroatoms to Nitroalkanes ; 6. Conversion of Nitro Compounds into Other Compounds6.1 Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids); 6.1.1 Treatment With Acid (Classical Procedure); 6.1.2 Oxidative Method; 6.1.3 Reductive Method; 6.1.4 Direct Conversion of Nitroalkenes to Carbonyl Compounds; 6.2 Nitrile Oxides and Nitriles; 6.3 Reduction of Nitro Compounds into Amines; 6.3.1 Ar-NH(2) From Ar-NO(2); 6.3.2 R-NH(2) from R-NO(2); 6.3.3 Oximes, Hydroxylamines, and Other Nitrogen Derivatives; 7. Substitution and Elimination of NO(2) in R-NO(2); 7.1 R-Nu from R-NO(2); 7.1.1 Radical Reactions (S(RN)1) ; 7.1.2 Ionic Process7.1.3 Intramolecular Nucleophilic Substitution Reaction; 7.1.4 Allylic Rearrangement; 7.2 R-H from R-NO(2); 7.2.1 Radical Denitration; 7.2.2 Ionic Denitration; 7.3 Alkenes from R-NO(2); 7.3.1 Radical Elimination; 7.3.2 Ionic Elimination of Nitro Compounds; 8. Cycloaddition Chemistry of Nitro Compounds; 8.1 Diels-Alder Reactions; 8.1.1 Nitroalkenes Using Dienophiles; 8.1.2 Asymmetric Diels-Alder Reaction; 8.2 1,3-Dipolar Cycloaddition; 8.2.1 Nitrones; 8.2.2 Nitrile Oxides; 8.2.3 Nitronates; 8.3 Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition ; 8.3.1 Nitroalkenes as Heterodienes
• Sommario/riassunto: The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organ
• Titolo autorizzato: The nitro group in organic synthesis
• ISBN: 1-280-36618-4; 9786610366187; 0-470-25024-0; 0-471-45846-5; 0-471-22448-0
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910830330503321
• Lo trovi qui: Univ. Federico II
• Serie: Organic nitro chemistry.