Classical and geometrical theory of chemical and phase thermodynamics / / Frank Weinhold

• Autore: Weinhold Frank <1941->
• Pubblicazione: Hoboken, N.J., : Wiley, c2009
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (506 p.)
• Disciplina: 541.369
• Soggetto topico: Phase rule and equilibrium; Thermodynamics; Thermodynamics - Mathematics
• Classificazione: UG 3800; VE 6000
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: CLASSICAL AND GEOMETRICAL THEORY OF CHEMICAL AND PHASE THERMODYNAMICS; CONTENTS; PREFACE; PART I INDUCTIVE FOUNDATIONS OF CLASSICAL THERMODYNAMICS; 1. Mathematical Preliminaries: Functions and Differentials; 1.1 Physical Conception of Mathematical Functions and Differentials; 1.2 Four Useful Identities; 1.3 Exact and Inexact Differentials; 1.4 Taylor Series; 2. Thermodynamic Description of Simple Fluids; 2.1 The Logic of Thermodynamics; 2.2 Mechanical and Thermal Properties of Gases: Equations of State; 2.3 Thermometry and the Temperature Concept; 2.4 Real and Ideal Gases ; 2.4.1 Compressibility Factor and Ideal Gas Deviations2.4.2 Van der Waals and Other Model Equations of State; 2.4.3 The Virial Equation of State; 2.5 Condensation and the Gas-Liquid Critical Point; 2.6 Van der Waals Model of Condensation and Critical Behavior; 2.7 The Principle of Corresponding States; 2.8 Newtonian Dynamics in the Absence of Frictional Forces; 2.9 Mechanical Energy and the Conservation Principle; 2.10 Fundamental Definitions: System, Property, Macroscopic, State; 2.10.1 System; 2.10.2 Property; 2.10.3 Macroscopic; 2.10.4 State; 2.11 The Nature of the Equilibrium Limit ; 3. General Energy Concept and the First Law3.1 Historical Background of the First Law; 3.2 Reversible and Irreversible Work; 3.3 General Forms of Work; 3.3.1 Pressure-Volume Work; 3.3.2 Surface Tension Work; 3.3.3 Elastic Work; 3.3.4 Electrical (emf) Work; 3.3.5 Electric Polarization Work; 3.3.6 Magnetic Polarization Work; 3.3.7 Overview of General Work Forms; 3.4 Characterization and Measurement of Heat; 3.5 General Statements of the First Law; 3.6 Thermochemical Consequences of the First Law; 3.6.1 Heat Capacity and the Enthalpy Function; 3.6.2 Joule's Experiment ; 3.6.3 Joule-Thomson Porous Plug Experiment3.6.4 Ideal Gas Thermodynamics; 3.6.5 Thermochemistry: Enthalpies of Chemical Reactions; 3.6.6 Temperature Dependence of Reaction Enthalpies; 3.6.7 Heats of Solution; 3.6.8 Other Aspects of Enthalpy Decompositions; 4. Engine Efficiency, Entropy, and the Second Law; 4.1 Introduction: Heat Flow, Spontaneity, and Irreversibility; 4.2 Heat Engines: Conversion of Heat to Work; 4.3 Carnot's Analysis of Optimal Heat-Engine Efficiency; 4.4 Theoretical Limits on Perpetual Motion: Kelvin's and Clausius' Principles; 4.5 Kelvin's Temperature Scale ; 4.6 Carnot's Theorem and the Entropy of Clausius4.7 Clausius' Formulation of the Second Law; 4.8 Summary of the Inductive Basis of Thermodynamics; PART II GIBBSIAN THERMODYNAMICS OF CHEMICAL AND PHASE EQUILIBRIA; 5. Analytical Criteria for Thermodynamic Equilibrium; 5.1 The Gibbs Perspective; 5.2 Analytical Formulation of the Gibbs Criterion for a System in Equilibrium; 5.3 Alternative Expressions of the Gibbs Criterion; 5.4 Duality of Fundamental Equations: Entropy Maximization versus Energy Minimization; 5.5 Other Thermodynamic Potentials: Gibbs and Helmholtz Free Energy ; 5.6 Maxwell Relations
• Sommario/riassunto: Because it is grounded in math, chemical thermodynamics is often perceived as a difficult subject and many students are never fully comfortable with it. The first authoritative textbook presentation of equilibrium chemical and phase thermodynamics in a reformulated geometrical framework, Chemical and Phase Thermodynamics shows how this famously difficult subject can be accurately expressed with only elementary high-school geometry concepts. Featuring numerous suggestions for research-level extensions, this simplified alternative to standard calculus-based thermodynamics expositions is perfect
• Titolo autorizzato: Classical and geometrical theory of chemical and phase thermodynamics
• ISBN: 1-282-02793-X; 9786612027932; 0-470-43506-2; 0-470-43505-4
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910810806803321
• Lo trovi qui: Univ. Federico II