Porphyrin-Based Composites : Materials and Applications

• Autore: Dar Umar Ali
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2025; ©2025
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (630 pages)
• Altri autori: ShahnawazMohd GuptaPuja
• Nota di contenuto: Cover -- Series Page -- Title Page -- Copyright Page -- Contents -- Preface -- Part I: Overview of Porphyrins -- Chapter 1 Composite Materials Utilizing Porphyrin Template: An Overview -- 1.1 Introduction -- 1.2 Development and Construction of Porphyrin Composites -- 1.2.1 Porphyrin Synthesis and Functionalization -- 1.2.2 Synthesis of Porphyrin Composites -- 1.3 Applications of Porphyrin-Based Composites -- 1.3.1 Energy -- 1.3.2 Device Materials -- 1.3.3 Remediation -- 1.3.4 Nanotechnology -- 1.3.5 Agriculture -- 1.3.6 Catalysis -- 1.4 Future Perspectives -- 1.5 Conclusion -- References -- Chapter 2 Physical and Mechanical Properties of Porphyrin Composite Materials -- 2.1 Introduction -- 2.2 Synthesis Methods for Porphyrin Composites -- 2.2.1 Chemical Vapor Deposition (CVD) Techniques -- 2.2.2 Sol-Gel Methodology -- 2.2.3 Electrospinning and Electrochemical Deposition -- 2.2.4 Green Synthesis Approaches -- 2.2.5 Organometallic Methodologies for Synthesis -- 2.2.6 Comparative Analysis of Synthesis Techniques -- 2.3 Characterization Techniques -- 2.3.1 Scanning Electron Microscopy (SEM) for Morphological Analysis -- 2.3.2 X-Ray Diffraction (XRD) for Structural Investigation -- 2.3.3 Spectroscopic Techniques (UV-Vis and FTIR) for Chemical Analysis -- 2.3.4 Mechanical Testing Methods (Tensile, Compression, and Flexural) -- 2.4 Physical Properties of Porphyrin Composite Materials -- 2.4.1 Thermal Conductivity and Stability -- 2.4.2 Optical Properties and Light Absorption -- 2.4.3 Electrical Conductivity and Dielectric Properties -- 2.4.4 Magnetic Properties and Spin Dynamics -- 2.5 Mechanical Properties of Porphyrin Composite Materials -- 2.5.1 Tensile Strength and Elastic Modulus -- 2.5.2 Flexural Strength and Toughness -- 2.5.3 Impact Resistance and Fracture Toughness -- 2.5.4 Fatigue Behavior and Endurance Limit. ; 2.6 Influence of Porphyrin Functionalization on Properties -- 2.6.1 Impact of Peripheral Substitution -- 2.6.2 Functional Groups and Surface Modification -- 2.6.3 Doping and Alloying Effects -- 2.6.4 Interfacial Interactions in Composite Systems -- 2.7 Applications of Porphyrin Composite Materials -- 2.7.1 Photovoltaics and Solar Cells -- 2.7.2 Sensing and Detection Technologies -- 2.7.3 Biomedical and Drug Delivery Applications -- 2.7.4 Catalysis and Environmental Remediation -- 2.8 Challenges and Future Perspectives -- 2.9 Conclusion -- References -- Chapter 3 Porphyrin Composite Materials Analysis, Design, Manufacturing and Production -- 3.1 Introduction -- 3.2 Porphyrin Aspects -- 3.2.1 Methods for Obtaining & -- Producing Porphyrins -- 3.2.1.1 Synthesis -- 3.2.1.2 Trans-Substituted Porphyrins -- 3.2.1.3 Obtaining A2BC Tetra-Substituted Porphyrins -- 3.3 The Analogs Design of Porphyrins -- 3.3.1 Analogs of Porphyrins -- 3.3.1.1 Chlorines and Bacteriochlorines -- 3.4 Composites -- 3.4.1 Porphyrin-Based Composites -- 3.4.2 Nano Porphyrin-Based Composites -- 3.4.3 (GQDs) and Porphyrin Composites -- 3.4.4 Graphene Oxide-Porphyrin Composites -- 3.4.5 Metalloporphyrins -- 3.5 Types of Porphyrin-Based Composites Framework -- 3.5.1 Porphyrin-Based MOFs -- 3.5.2 Porphyrin-Based COFs -- 3.5.3 Porphyrin-Based HOFs -- 3.6 Few Important Methods for Analysis of Porphyrins -- 3.6.1 Spectrophotometric Methods -- 3.6.2 Voltammetric Analysis -- 3.6.3 Analysis by HPLC Method -- 3.7 Conclusion -- References -- Chapter 4 Advanced Characterization Methods and Characterization Types for Porphyrins -- 4.1 Introduction -- 4.2 Types of Characterization Techniques Utilized for Porphyrins Analysis -- 4.2.1 UV-Vis Analysis and Spectrometric Properties -- 4.2.2 NMR Analysis of Porphyrins -- 4.2.3 Raman Spectroscopic Analysis of Porphyrins. ; 4.3 HOMO-LUMO Relations for Porphyrins -- 4.4 Optical and Electro-Field Analysis -- 4.5 Applications in Solar Cells -- 4.6 DLS Analysis for Porphyrins -- 4.7 AFM Analysis for Porphyrins -- 4.8 Conclusion -- References -- Part II: Source, Design, Manufacturing, Properties and Fundamentals -- Chapter 5 Spectroscopic Nonlinear Optical Characteristics of Porphyrin-Functionalized Nanocomposite Materials -- 5.1 Introduction -- 5.2 Porphyrins -- 5.2.1 Chemical Characteristics of Porphyrins -- 5.3 Synthesis of Porphyrin -- 5.3.1 Adler-Longo Process of Porphyrin -- 5.3.2 Porphyrin Synthesis in Two Steps with a Single Flask at Ambient Temperature -- 5.4 Porphyrin-Functionalized Nanocomposites Materials -- 5.4.1 Porphyrin-Functionalized Nanocomposite Materials with Metal and Oxide Nanomaterials -- 5.4.2 Porphyrin-Functionalized Nanocomposite Materials with Polymers -- 5.4.3 Porphyrin-Functionalized Nanocomposite Materials with Biological Materials -- 5.4.4 Porphyrin-Functionalized Nanocomposite Materials with CNT or Carbon Fibers -- 5.5 Properties of Porphyrin-Functionalized Nanocomposite Materials -- 5.5.1 Spectral Properties -- 5.5.1.1 UV-Vis Spectroscopy -- 5.5.1.2 FTIR Spectroscopy -- 5.5.1.3 XRD Analysis -- 5.5.1.4 Fluorescence Spectroscopy -- 5.5.2 Nonlinear Optical Characteristics -- 5.6 Conclusion -- References -- Chapter 6 Electrochemical Advancements in Porphyrin Materials: From Fundamentals to Electrocatalytic Applications -- 6.1 Introduction -- 6.2 Electrochemical Fundamentals of Porphyrin-Based Materials -- 6.2.1 Electrochemical Behavior of Porphyrin -- 6.2.2 Key Parameters Influencing Porphyrin Electrochemistry -- 6.2.3 Electrochemical Porphyrin-Based Materials -- 6.3 Porphyrin-Based Materials for Electrocatalysis Applications -- 6.3.1 Electrocatalysis Fundamentals -- 6.3.2 Porphyrin-Based Materials for CO2 Reduction. ; 6.3.3 Porphyrin-Based Materials for Electrocatalytic Water Splitting -- 6.3.3.1 Electrocatalytic Hydrogen Evolution Reaction -- 6.3.3.2 Electrocatalytic Oxygen Evolution Reaction -- 6.3.3.3 Overall Electrochemical Water Spilling -- 6.4 Conclusion and Outlooks -- References -- Chapter 7 Manifestation of Porphyrin Composites in Variety of Photocatalytic Processes -- 7.1 Introduction -- 7.2 Porphyrin Composites -- 7.3 Synthesis of Porphyrin Composites -- 7.4 Photocatalytic Applications of Porphyrin Composites -- 7.4.1 Photocatalytic Production of Hydrogen Fuel by Water Splitting -- 7.4.1.1 Metal Oxides-Porphyrin Composites -- 7.4.1.2 Carbon Material-Porphyrin Composites -- 7.4.2 Photocatalytic Degradation of Dyes and Organic Pollutants -- 7.4.2.1 Conversion of CO2 to Value-Added Chemicals -- 7.5 Conclusions -- References -- Chapter 8 The Use of Porphyrin Composite Materials as Catalyst in a Variety of Application Sectors -- 8.1 Introduction -- 8.2 Related Works -- 8.3 Porphyrin-Based MOFs: Synthesis Methods, Structural Characteristics, and Characterization Techniques -- 8.3.1 Synthesis Methods -- 8.3.2 Structural Characteristics and Characterization Techniques -- 8.4 Design and Construction of Porphyrin-Based MOFs -- 8.4.1 Design of Porphyrin-Based MOFs -- 8.4.2 Porphyrin-Based MOF Construction -- 8.4.2.1 Porphyrin-Based MOFs with Carboxylic Acid Linkers -- 8.4.2.2 Porphyrin-Based MOFs with Nitrogen- Containing Heterocyclic Linkers -- 8.5 Application of Porphyrin-Based MOFs -- 8.5.1 PhotoCatalytic Evolution of Hydrogen -- 8.5.2 Catalytic Photolysis of CO2 -- 8.5.3 Photocatalytic Fixation of Nitrogen -- 8.5.4 Photocatalytic Removal of Pollutants -- 8.5.5 Photocatalytic Synthesis of Organic Compounds -- 8.5.6 Biosensing -- 8.5.7 Photodynamic Therapy with Porphyrin-Based MOFs -- 8.5.8 Advances in Fluorescence Imaging for Targeted Therapy. ; 8.5.9 Sensing of pH -- 8.6 Conclusion and Future Scope -- References -- Part III: Advantages and Applications of Porphyrin Composites Materials -- Chapter 9 Porphyrin Composites Provide New Design and Building Construction Options -- 9.1 Introduction -- 9.2 The Design Idea of Porphyrin Compound Material -- 9.2.1 Design and Synthesis of Porphyrins MOFs -- 9.2.2 Design and Synthesis of Porphyrin COFs -- 9.2.3 Design and Synthesis of Porphyrins HOFs -- 9.2.4 Design and Synthesis of Other Porphyrin-Based Composites -- 9.3 Construction of Porphyrin Electrochemiluminescence Molecules -- 9.3.1 Introduction to Electrochemiluminescence -- 9.3.2 Electrochemiluminescence Mechanism -- 9.3.3 Electrochemical Luminescence of Porphyrin Molecules Constructed by Molecular Regulation -- 9.3.4 Electrochemical Luminescence of Porphyrin Nanocomposites -- 9.3.5 Interfacial Electron-Induced Electrochemiluminescence -- 9.4 Construction and Characterization of Porphyrin Surface Interface Transport Molecules -- 9.4.1 Study of the Electron Transfer Process of Porphyrin at the Liquid/Liquid Interface -- 9.4.2 Study and Regulation of Photosensitized Materials and Their Models of Porphyrins -- 9.4.3 Regulation of the Porphyrin Interface -- 9.5 Composite of Porphyrins with Carbon-Based Materials -- 9.5.1 Construction of Porphyrin Functionalized Graphene Nanomaterials -- 9.5.2 Construction of Porphyrin-Functionalized Carbon Nanotubes -- 9.5.3 Construction of Porphyrin Functionalized g-C3N4 -- 9.5.4 Construction of Porphyrin-Functionalized Fullerenes -- 9.6 Porphyrin-Based MOFs, COFs, HOFs Porous Materials and Properties -- 9.6.1 Introduction and Application of Porphyrin MOFs -- 9.6.2 Introduction and Application of Porphyrin COFs -- 9.6.3 Brief Introduction and Application of Porphyrin HOFs -- 9.6.4 Brief Introduction and Application of Porphyrin POPs. ; 9.7 Construction of Composite Materials of Porphyrins and Metal Nanoparticles.
• Sommario/riassunto: Discover the transformative potential of porphyrin-based composites in Porphyrin-Based Composites where readers will learn how these innovative materials enhance industrial sectors by combining multiple porphyrin components to create durable, sensitive, and efficient technologies that outperform traditional materials. This book highlights the benefits of adopting porphyrin composites and discusses how they are used in different industrial sectors. Combining multiple porphyrin components is used to create materials with properties that are not possible with individual components, remove restrictions of water-insolubility, and ultimately lead to the development of durable and more sensitive technological materials. Composite materials have been essential to human life for thousands of years, beginning with the construction of houses by the first civilizations and advancing to modern technologies. Originating in the mid-twentieth century, composite materials show promise as a class of engineering materials that offer new opportunities for contemporary technology and have been beneficially incorporated into practically every sector due to their ability to choose elements, tune them to achieve the desired qualities, and efficiently use those features through design. Additionally, composite materials offer greater strength- and modulus-to-weight ratios than standard engineering materials. Materials based on porphyrin composites are used in a wide range of applications, including sensors, molecular probes, electrical gadgets, electronic devices, construction materials, catalysis, medicine, and environmental and energy applications. Readers will find the book: Provides an overview of several porphyrin composites as model materials for commercial settings; Discusses fundamental, experimental, and theoretical research on structural and physicochemical properties of porphyrin composites; Demonstrates how complementary and alternative material designs that use porphyrin composites have evolved; Emphasizes important uses for cutting-edge, multipurpose materials that might contribute to a more sustainable society; Opens new possibilities by examining the role of developing unique hybrid, composite, and higher-order hierarchical materials that may be utilized to make valuable chemicals. Audience Researchers, academicians, chemists, industry experts, and students working in the fields of materials and environmental sciences, engineering, textiles, biology, and medicine.
• Titolo autorizzato: Porphyrin-Based Composites
• ISBN: 1-394-21444-8; 1-394-21443-X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911019164503321
• Lo trovi qui: Univ. Federico II