Biomimetic organic synthesis . Volume 1 Alkaloids [[electronic resource] /] / edited by Erwan Poupon and Bastien Nay

• Pubblicazione: Weinheim, : Wiley-VCH, c2011
• Descrizione fisica: 1 online resource (1012 p.)
• Disciplina: 547.2
• Soggetto topico: Biomimetics; Organic compounds - Synthesis
• Altri autori: PouponErwan NayBastien
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Biomimetic Organic Synthesis; Contents to Volume; Preface; List of Contributors; Biomimetic Organic Synthesis: an Introduction; Part I Biomimetic Total Synthesis of Alkaloids; 1 Biomimetic Synthesis of Ornithine/Arginine and Lysine-Derived Alkaloids: Selected Examples; 1.1 Ornithine/Arginine and Lysine: Metabolism Overview; 1.1.1 Introduction: Three Important Basic Amino Acids; 1.1.2 From Primary Metabolism to Alkaloid Biosynthesis; 1.1.2.1 l-Ornithine Entry into Secondary Metabolism; 1.1.2.2 l-Lysine Entry into Secondary Metabolism; 1.1.3 Closely Related Amino Acids ; 1.1.4 The Case of Polyamine Alkaloids1.1.5 Biomimetic Synthesis of Alkaloids; 1.2 Biomimetically Related Chemistry of Ornithine- and Lysine-Derived Reactive Units; 1.2.1 Ornithine-Derived Reactive Units; 1.2.1.1 Biomimetic Behavior of 4-Aminobutyraldehyde; 1.2.1.2 Dimerization; 1.2.2 Lysine-Derived Reactive Units; 1.2.2.1 Oxidative Degradation of Free l-Lysine; 1.2.2.2 Clemens Schöpf 's Heritage: 50 Years of Endocyclic Enamines and Tetrahydroanabasine Chemistry; 1.2.2.3 Spontaneous Formation of Alkaloid Skeletons from Glutaraldehyde; 1.2.3 Biomimetic Access to Pipecolic Acids ; 1.2.3.1 Pipecolic Acids: Biosynthesis and Importance1.2.3.2 Biomimetic Access to Pipecolic Acids; 1.3 Biomimetic Synthesis of Alkaloids Derived from Ornithine and Arginine; 1.3.1 Biomimetic Access to the Pyrrolizidine Ring; 1.3.2 Biomimetic Syntheses of Elaeocarpus Alkaloids; 1.3.3 Biomimetic Synthesis of Fissoldhimine; 1.3.4 Biomimetic Synthesis of Ficuseptine, Juliprosine, and Juliprosopine; 1.3.5 Biomimetic Synthesis of Arginine-Containing Alkaloids: Anchinopeptolides and Eusynstyelamide A; 1.3.5.1 Natural Products Overview; 1.3.5.2 Biomimetic Synthesis ; 1.3.6 A Century of Tropinone Chemistry1.4 Biomimetic Synthesis of Alkaloids Derived from Lysine; 1.4.1 Alkaloids Derived from Lysine: To What Extent?; 1.4.2 Lupine Alkaloids; 1.4.2.1 Overview and Biosynthesis Key Steps; 1.4.2.2 Biomimetic Synthesis of Lupine Alkaloids; 1.4.2.3 A Biomimetic Conversion of N-Methylcytisine into Kuraramine; 1.4.3 Biomimetic Synthesis of Nitraria and Myrioneuron Alkaloids; 1.4.3.1 Biomimetic Syntheses of Nitraramine; 1.4.3.2 Biomimetic Syntheses of Tangutorine; 1.4.3.3 Endocyclic Enamines Overview: Biomimetic Observations ; 1.4.4 Biomimetic Synthesis of Stenusine, the Spreading Agent of Stenus comma1.5 Pelletierine-Based Metabolism; 1.5.1 Pelletierine: A Small Alkaloid with a Long History; 1.5.2 Biomimetic Synthesis of Pelletierine and Pseudopelletierine; 1.5.2.1 Pelletierine (129); 1.5.2.2 Pseudopelletierine; 1.5.3 Lobelia and Sedum Alkaloids; 1.5.4 Lycopodium Alkaloids; 1.5.4.1 Overview, Classification, and Biosynthesis; 1.5.4.2 Biomimetic Rearrangement of Serratinine into Serratezomine A; 1.5.4.3 Biomimetic Conversion of Serratinine into Lycoposerramine B ; 1.5.4.4 Biomimetic Interrelations within the Lycoposerramine and Phlegmariurine Series
• Sommario/riassunto: In this exciting 2 volume set, the approach and methodology of bio-inspired synthesis of complex natural products is laid out, backed by abundant practical examples from the authors' own work as well as from the published literature. Volume 1 describes the biomimetic synthesis of alkaloids. Volume 2 covers terpenes, polyketides, and polyphenols. A discussion of the current challenges and frontiers in biomimetic synthesis concludes this comprehensive handbook. Key features:Biomimetic Strategies have become an every-day tool not only for chemists but also for
• Titolo autorizzato: Biomimetic organic synthesis
• ISBN: 1-283-87003-7; 3-527-63477-0; 3-527-63476-2; 3-527-63460-6
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910841532703321
• Lo trovi qui: Univ. Federico II