New and future developments in catalysis Activation of carbon dioxide / / edited by Steven L. Suib, Department of Chemistry and Chemical Engineering and Institute of Materials Science, The University of Connecticut, Storrs, CT 06269-3060

• Pubblicazione: Amsterdam, : Elsevier, 2013; Amsterdam : , : Elsevier, , 2013
• Descrizione fisica: 1 online resource (xiii, 644 pages) : illustrations (some color)
• Disciplina: 665.89
• Soggetto topico: Carbon dioxide; Catalysis
• Persona (resp. second.): SuibSteven L. <1953->
• Note generali: Description based upon print version of record.
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Half Title; Title Page; Copyright; Contents; Introduction; Contributors; 1 Catalytic Processes for Activation of CO2; 1.1 Introduction; 1.2 Reactions of CO2 with hydrogen; 1.2.1 Hydrogenation of CO2 to Methanol; 1.2.2 Dimethyl Ether Synthesis; 1.2.3 Formic Acid Synthesis; 1.2.4 CO2 Hydrogenation to CH4; 1.2.5 CO Production via the Reverse Water-Gas Shift Reaction (RWGS); 1.2.6 Higher Hydrocarbon Synthesis; 1.2.7 CO2 Hydrogenation to Higher Alcohols; 1.3 CO2-assisted reactions; 1.3.1 CO2 Reforming of Methane; 1.3.2 CO2 Reforming of Ethanol and Higher Alcohols ; 1.3.3 Oxidative Dehydrogenation in the Presence of CO21.4 CO2 insertion reactions; 1.4.1 Organic Carbonates; 1.4.2 Carboxylic Acids; 1.5 Concluding remarks and outlook; References; 2 Surface Science Studies of Carbon Dioxide Chemistry; 2.1 Introduction-why study CO2 adsorption on surfaces?; 2.2 Metal surfaces; 2.2.1 Copper; 2.2.2 Antimony; 2.2.3 Chromium; 2.3 Metal oxides; 2.3.1 TiO2; 2.3.2 ZnO; 2.3.3 CaO; 2.3.3.1 Why Are Alkaline Earth Oxides Particularly Interesting?; 2.3.3.2 Co2 Adsorption And Carbonate Formation On CaO Single Crystals; 2.2.4 CrxOy; 2.4 Non-metals; 2.5 Bimetallic systems ; 2.6 Cluster systems 2.6.1 Copper Clusters on Zinc Oxide; 2.6.2 Iron Oxide Clusters on Graphite; 2.7 Nanostructured catalysts; 2.8 Theoretical studies; 2.9 Appendix; 2.9.1 Standard Adsorption Dynamics Models; 2.9.2 A Few Surface Science Measuring Techniques; Acknowledgments; References; 3 Mechanistic Understanding of Catalytic CO2 Activation from First Principles Theory; 3.1 Background; 3.2 CO2 activation and hydrogenation on transition metal surface; 3.2.1 Methanol from CO2 Hydrogenation on Cu Surfaces; 3.2.2 Methanol from CO2 Hydrogenation on Modified Cu Surfaces ; 3.2.3 CO2 Hydrogenation on Ni(1 1 0) and Ni(1 1 1)3.3 CO2 activation and hydrogenation on oxide supports; 3.4 CO2 activation and hydrogenation on oxide supported metal catalysts; 3.5 Concluding Remarks; Acknowledgment; References; 4 Catalytic Activation and Conversion of Carbon Dioxide into Fuels/Value-Added Chemicals Through C-C Bond Formation; 4.1 Introduction; 4.2 Chemical activation of carbon dioxide; 4.2.1 Coordination Chemistry of CO2 and Metals; 4.2.1.1 Molecular Geometry and Spectroscopic Properties of CO2; 4.2.1.2 Interaction of CO2 with Metals ; 4.2.2 Synthesis and Characterization of Stable Complexes of CO2 with Metals 4.2.2.1 General Characterization Methods; 4.2.2.2 Synthesis of Stable CO2-Metal Complexes; 4.2.2.3 Stable Complexes of CO2 Coordinated to Metals; 4.2.2.3.1 Coordination via a CE0B8;O double bond; 4.2.2.3.2 Coordination via carbon only; 4.2.2.3.3 Coordination via oxygen only; 4.2.2.3.4 CO2 as Bridging Ligand; 4.2.3 Reactivity of Complexes of CO2 with Metals; 4.2.3.1 C-O Bond Cleavage and Oxygen Transfer; 4.2.3.2 Reactions with Electrophiles; 4.2.3.3 Reactions with Nucleophiles ; 4.2.4 Activation of CO2 Using N-Heterocyclic Carbenes and FLPs
• Sommario/riassunto: New and Future Developments in Catalysis is a package of books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes. This volume presents a complete picture of all carbon dioxide (CO2) sources, outlines the environmental concerns regarding CO2, and
• Titolo autorizzato: New and future developments in catalysis
• ISBN: 0-444-53883-6
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910813019403321
• Lo trovi qui: Univ. Federico II