Principles of polymerization / / George Odian

• Pubblicazione: Hoboken, N.J., : Wiley, c2004; Hoboken, N.J. : , : Wiley, , 2004
• Edizione: 4th ed
• Descrizione fisica: 1 online resource (838 p.)
• Disciplina: 547.28
• Soggetto topico: Polymerization
• Classificazione: 431.9; 434.5
• Note generali: "A Wiley-Interscience publication"; Includes bibliographical references and index
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: PRINCIPLES OF POLYMERIZATION Fourth Edition; CONTENTS; PREFACE; 1 INTRODUCTION; 1-1 Types of Polymers and Polymerizations; 1-1a Polymer Composition and Structure; 1-1b Polymerization Mechanism; 1-2 Nomenclature of Polymers; 1-2a Nomenclature Based on Source; 1-2b Nomenclature Based on Structure (Non-IUPAC); 1-2c IUPAC Structure-Based Nomenclature System; 1-2d Trade Names and Nonnames; 1-3 Linear, Branched, and Crosslinked Polymers; 1-4 Molecular Weight; 1-5 Physical State; 1-5a Crystalline and Amorphous Behavior; 1-5b Determinants of Polymer Crystallinity; 1-5c Thermal Transitions ; 1-6 Applications of Polymers1-6a Mechanical Properties; 1-6b Elastomers, Fibers, and Plastics; References; 2 STEP POLYMERIZATION; 2-1 Reactivity of Functional Groups; 2-1a Basis for Analysis of Polymerization Kinetics; 2-1b Experimental Evidence; 2-1c Theoretical Considerations; 2-1d Equivalence of Groups in Bifunctional Reactants; 2-2 Kinetics of Step Polymerization; 2-2a Self-Catalyzed Polymerization; 2-2a-1 Experimental Observations; 2-2a-2 Reasons for Nonlinearity in Third-Order Plot; 2-2a-3 Molecular Weight of Polymer; 2-2b External Catalysis of Polymerization ; 2-2c Step Polymerizations Other than Polyesterification: Catalyzed versus Uncatalyzed2-2d Nonequivalence of Functional Groups in Polyfunctional Reagents; 2-2d-1 Examples of Nonequivalence; 2-2d-2 Kinetics; 2-3 Accessibility of Functional Groups; 2-4 Equilibrium Considerations; 2-4a Closed System; 2-4b Open, Driven System; 2-4c Kinetics of Reversible Polymerization; 2-5 Cyclization versus Linear Polymerization; 2-5a Possible Cyclization Reactions; 2-5b Cyclization Tendency versus Ring Size; 2-5c Reaction Conditions; 2-5d Thermodynamic versus Kinetic Control; 2-5e Other Considerations ; 2-6 Molecular Weight Control in Linear Polymerization2-6a Need for Stoichiometric Control; 2-6b Quantitative Aspects; 2-6c Kinetics of Nonstoichiometric Polymerization; 2-7 Molecular Weight Distribution in Linear Polymerization; 2-7a Derivation of Size Distributions; 2-7b Breadth of Molecular Weight Distribution; 2-7c Interchange Reactions; 2-7d Alternate Approaches for Molecular-Weight Distribution; 2-7e Effect of Reaction Variables on MWD; 2-7e-1 Unequal Reactivity of Functional Groups; 2-7e-2 Change in Reactivity on Reaction; 2-7e-3 Nonstoichiometry of Functional Groups ; 2-8 Process Conditions2-8a Physical Nature of Polymerization Systems; 2-8b Different Reactant Systems; 2-8c Interfacial Polymerization; 2-8c-1 Description of Process; 2-8c-2 Utility; 2-8d Polyesters; 2-8e Polycarbonates; 2-8f Polyamides; 2-8g Historical Aspects; 2-9 Multichain Polymerization; 2-9a Branching; 2-9b Molecular Weight Distribution; 2-10 Crosslinking; 2-10a Carothers Equation: X(n); 2-10a-1 Stoichiometric Amounts of Reactants; 2-10a-2 Extension to Nonstoichiometric Reactant Mixtures; 2-10b Statistical Approach to Gelation: X(w); 2-10c Experimental Gel Points ; 2-10d Extensions of Statistical Approach
• Sommario/riassunto: The new edition of a classic text and referenceThe large chains of molecules known as polymers are currently used in everything from ""wash and wear"" clothing to rubber tires to protective enamels and paints. Yet the practical applications of polymers are only increasing; innovations in polymer chemistry constantly bring both improved and entirely new uses for polymers onto the technological playing field. Principles of Polymerization, Fourth Edition presents the classic text on polymer synthesis, fully updated to reflect today's state of the art. New and expanded coverage in the Fourth E
• Titolo autorizzato: Principles of polymerization
• ISBN: 1-280-34490-3; 9786610344901; 0-470-35149-7; 0-471-47874-1; 0-471-47875-X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910877312603321
• Lo trovi qui: Univ. Federico II