Iron Catalysis II [[electronic resource] /] / edited by Eike Bauer

• Pubblicazione: Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015
• Edizione: 1st ed. 2015.
• Descrizione fisica: 1 online resource (IX, 361 p. 515 illus., 6 illus. in color.)
• Disciplina: 669.1
• Soggetto topico: Organometallic chemistry ; Catalysis; Chemical engineering; Organometallic Chemistry; Industrial Chemistry/Chemical Engineering
• Persona (resp. second.): BauerEike
• Note generali: Bibliographic Level Mode of Issuance: Monograph
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- Preface -- Contents -- Iron Catalysis: Historic Overview and Current Trends -- 1 Introduction -- 2 Abundance and Low Toxicity -- 3 Historic Development -- 4 Overview of Main Reactions That Are Catalyzed Under Homogeneous Conditions by Iron Complexes -- 4.1 C-C Bond-Forming Reactions -- 4.2 C-Heteroatom and Heteroatom-Heteroatom Bond-Forming Reactions -- 4.3 Oxidation Reactions -- 4.4 Reduction Reactions -- 4.5 Polymerization Reactions -- 4.6 Enantioselective Iron Catalysis and Stoichiometric Considerations -- 5 Impurities in Iron Metal as the Actual Catalyst? -- 6 Recent Heterogeneous Applications of Iron -- 7 Outlook -- References -- The Development of Iron Catalysts for Cross-Coupling Reactions -- 1 Introduction -- 1.1 Background -- 1.2 Scope -- 2 Iron Catalysts for the Cross-Coupling of Grignard Reagents -- 2.1 Oxygen, Nitrogen and Sulphur Donor Ligands -- 2.2 Phosphines and Related Ligands -- 2.3 N-Heterocyclic Carbene Ligands -- 3 Iron Catalysts for the Cross-Coupling of Softer Nucleophiles -- 3.1 Zinc-Based Nucleophiles -- 3.2 Boron-Based Nucleophiles -- 3.3 Aluminium-, Gallium-, Indium- and Thallium-Based Nucleophiles -- 4 Summary and Outlook -- References -- Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions -- 1 Introduction -- 2 Csp3-Csp3 CDC Reaction -- 3 Csp3-Csp2 CDC Reactions -- 4 Csp3-Csp CDC Reaction -- 5 Other C-C CDC Reaction -- 6 E-E CDC Reaction -- 7 Conclusion -- References -- Iron-Catalyzed Carbon-Nitrogen, Carbon-Phosphorus, and Carbon-Sulfur Bond Formation and Cyclization Reactions -- 1 Introduction -- 2 Iron-Catalyzed C-N Bond Formations -- 2.1 Cross-Coupling Reactions -- 2.2 Allylic Substitution Reactions -- 2.3 C-H Functionalization -- 2.3.1 Cross-Dehydrogenative Coupling Reactions -- 2.3.2 N-Arylation via C-H Activation -- 2.3.3 Decomposition of Azide Generation of Nitrenes. ; 2.4 Synthesis of Nitrogenated Heterocycles -- 2.4.1 Aziridination of Olefins -- 2.4.2 Construction of Five-Membered Cycles Containing Nitrogen Atoms -- Csp2-H or Csp3-H Functionalization Reactions -- [2+2+1]-Cycloaddition -- [3+2]-Cycloaddition Reactions -- [4+1]-Cycloaddition -- Intermolecular Aminohydroxylation of Olefins -- Hydroamination of Alkenes -- Synthesis of Indoles -- 2.4.3 Construction of Six-Membered Cycles -- Synthesis of Pyridines -- Synthesis of Tetrahydroquinolines and Dihydroquinazolines -- Synthesis of Quinolines -- 2.5 Miscellaneous -- 2.5.1 Ring Opening of Epoxides -- 2.5.2 Amide Derivative Synthesis -- 2.5.3 Synthesis of Allenyl Triazoles -- 2.5.4 Azidation of beta-Ketoesters -- 2.5.5 Rearrangement of Allyl and Propargyl Sulfides -- 2.5.6 Synthesis of Oximes -- 3 Iron-Catalyzed C-S Bond Formations -- 3.1 Michael Additions -- 3.2 Cross-Coupling Reactions -- 3.3 Addition on Alkynes -- 3.4 Allylic Substitution -- 3.5 Synthesis of Benzothiazoles -- 3.6 Miscellaneous Reactions -- 4 Iron-Catalyzed C-P Bond Formation -- 5 Conclusion -- References -- High-Valent Iron in Biomimetic Alkane Oxidation Catalysis -- 1 Iron-Based Enzymes -- 2 Metal-Ion Catalysed Autooxidation -- 3 Fenton Chemistry -- 4 Oxidation Catalysis with Synthetic Mononuclear Nonheme Fe(II) Complexes -- 4.1 Tetradentate Ligands -- 4.2 Pentadentate Ligands -- 5 Mechanistic Discussions -- 6 Summary and Conclusions -- References -- Iron-Catalyzed Reduction and Hydroelementation Reactions -- 1 Reduction of Alkynes and Alkenes -- 1.1 Hydrogenation and Transfer Hydrogenation -- 1.2 Hydrosilylation -- 2 Reduction of Aldehydes and Ketones -- 2.1 Hydrogenation Reactions -- 2.2 Transfer Hydrogenation -- 2.3 Hydrosilylation Reactions -- 3 Reduction of Imines and Nitro-derivatives and Reductive Amination of Carbonyl Compounds -- 3.1 Reduction of Imines. ; 3.2 Reduction of Nitrile and Nitro-compounds En Route to Primary Amines -- 3.3 Direct Reductive Amination (DRA) -- 4 Reduction of Carboxylic Acid Derivatives and Carbon Dioxide -- 4.1 Amides -- 4.2 Nitriles -- 4.3 Carboxylic Esters -- 4.4 Carboxylic Acids -- 4.5 Ureas -- 4.6 Carbon Dioxide and Formic Acid -- 5 Reduction of Sulfoxides -- 6 Hydroboration of Alkenes and Alkynes -- 7 Conclusion -- References -- Iron-Catalyzed Oligomerization and Polymerization Reactions -- 1 Introduction and Scope -- 2 Ethylene Oligomerization and Polymerization -- 2.1 Nitrogen-Based Architectures for Ligand Development -- 2.1.1 Neutral Tridentate Ligands -- 2.1.2 Neutral Bidentate Ligands -- 2.1.3 Anionic Ligands -- 2.1.4 Repeated Unit Ligands -- 2.2 Comprehension and Characterization -- 2.3 Supported Homogeneous Iron Catalysts for Oligomerization and Polymerization of Ethylene -- 2.3.1 Impregnation -- 2.3.2 Iron Catalyst Anchoring -- 2.3.3 Self-Immobilization -- 3 Multiple Single-Site Catalysis -- 3.1 Reactor Blending -- 3.2 Tandem Catalysis -- 4 Diene Polymerization -- 4.1 Iron-Based Catalysts for Polymerization of Conjugated Dienes -- 4.1.1 Bidentate Nitrogen-Based Ligands -- 4.1.2 Tridentate Nitrogen-Based Ligands -- 4.2 Iron-Based Catalysts for Homo- and Copolymerization of Olefins and Nonconjugated Dienes -- 5 Conclusion and Outlook -- References -- Enantioselective Iron Catalysts -- 1 Introduction -- 2 Chiral Iron Porphyrins -- 3 Chiral Iron Bipyridines -- 4 Chiral Schiff Base-Salen-Salan Catalysts -- 4.1 Schiff Base Catalysts -- 4.2 Salen Catalysts -- 4.3 Salan Catalysts -- 5 Bis(oxazoline) Catalysts -- 6 Pyridine bis(Oxazoline) Catalysts -- 7 Diamine-Derived Catalysts -- 8 Diphosphine-Derived Catalysts -- 9 Binaphthyl-Derived Catalysts -- 10 Planar-Chiral Ferrocenyl Catalysts -- 11 Other Catalysts -- 12 Summary and Overview -- References. ; Molecular Iron-Based Oxidants and Their Stoichiometric Reactions -- 1 Trends in the Use of Iron in Catalysis -- 2 Iron-Based Oxidations and Iron-Oxidant Species -- 3 Iron in Biological Oxidations -- 4 Activation of Dioxygen by Biomimetic Iron Complexes -- 4.1 Reactions of Iron(III)-Substrate Adducts with Dioxygen -- 4.2 Binding of Dioxygen to Iron(II) Complexes -- 5 Nucleophilic Reactions of Iron Peroxide Adducts -- 5.1 Reactions with Aldehydes -- 5.2 Hydroxylation of Alkanes and Aromatic Compounds -- 6 Electrophilic Reactions of Iron-Oxo Intermediates -- 6.1 High-Valent Nonheme Iron(IV)-Oxo Complexes -- 6.2 Iron(V)Oxo and Iron(IV)Oxo-(Oxidized Radical Ligand) Complexes -- 7 Halogenation Reactions of Iron-Halide and Iron-Hypohalide Adducts -- 8 Electrophilic Reactions of Iron-Nitrido and Iron-Imido Intermediates -- 9 Intramolecular Ligand Oxidations -- 10 Conclusions and Outlook -- References -- Index.
• Sommario/riassunto: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
• Titolo autorizzato: Iron Catalysis II
• ISBN: 3-319-19396-1
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910768456503321
• Lo trovi qui: Univ. Federico II
• Serie: Topics in Organometallic Chemistry, . 1436-6002 ; ; 50