MXene Reinforced Polymer Composites : Fabrication, Characterization and Applications

• Autore: Deshmukh Kalim
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2024; ©2024
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (569 pages)
• Disciplina: 620.192
• Soggetto topico: MXenes; Polymeric composites
• Altri autori: PāṇḍeyaMayanka HussainChaudhery Mustansar
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Chapter 1 Two-Dimensional MXenes: Fundamentals, Characteristics, Synthesis Methods, Processing, Compositions, Structure, and Applications -- 1.1 Introduction -- 1.2 Fundamentals -- 1.2.1 Crystallographic Structure -- 1.2.2 Electronic Structure -- 1.2.3 Magnetic Structure -- 1.3 General Characteristics of the MXenes -- 1.3.1 Physical Properties -- 1.3.2 Chemical Properties -- 1.4 Synthesis Methods -- 1.4.1 Wet Chemical Etching -- 1.4.2 Urea Glass Route -- 1.4.3 Chemical Vapor Deposition -- 1.4.4 Molten Salt Etching -- 1.4.5 Hydrothermal Synthesis -- 1.4.6 Electrochemical Synthesis at Room Temperature -- 1.5 Applications -- 1.5.1 Nitrogen Reduction Reaction (NRR) -- 1.5.2 Oxygen Evolution Reaction (OER)/Oxygen Reduction Reaction (ORR) -- 1.5.3 Hydrogen Evolution Reaction (HER) -- 1.5.4 Energy Storages -- 1.5.4.1 Battery -- 1.5.4.2 Supercapacitor -- 1.5.4.3 Electromagnetic Interference Shielding -- 1.5.5 Biomedical Applications -- 1.6 Conclusion and Future Scope -- Acknowledgement -- References -- Chapter 2 Chemical Exfoliation and Delamination Methods of MXenes -- 2.1 Introduction -- 2.2 HF Etching Method -- 2.3 In Situ HF-Forming Etching Method -- 2.3.1 Fluoride Salts/Acids Etching Method -- 2.3.2 Bifluoride Salts Etching Method -- 2.4 Molten Salt Etching Method -- 2.4.1 Fluorine-Containing Molten Salt Etching Route -- 2.4.2 Fluorine-Free Molten Salt Etching Route -- 2.5 Electrochemical Etching Method -- 2.6 Hydrothermal Etching Method -- 2.7 Alkali Etching Method -- 2.8 Other Etching Methods -- 2.9 Exfoliation Strategies of Multilayered MXene -- 2.10 Conclusion -- Acknowledgement -- References -- Chapter 3 Surface Terminations and Surface Functionalization Strategies of MXenes -- 3.1 Introduction -- 3.2 Surface Termination Strategies in MXenes -- 3.2.1 Hydrofluoric Acid-Based Etching. ; 3.2.2 Molten Salt Etching -- 3.2.3 Alkali-Based Etching -- 3.2.4 Electrochemically-Assisted Etching -- 3.2.5 Manipulation of Terminations: Surface Modification and Doping in MXenes -- 3.3 Methods of Surface Functionalization in MXenes -- 3.3.1 Controlling Surface Terminations -- 3.3.2 Single Heteroatom Method -- 3.3.3 Small Molecules -- 3.3.4 Surface-Initiated Polymerization -- 3.3.5 Other Methods -- 3.4 Application of Surface Modified MXenes -- 3.4.1 Energy Generation and Storage -- 3.4.2 Biomedicine -- 3.4.2.1 Biosensing and Bioimaging -- 3.4.2.2 Photothermal Therapy -- 3.4.2.3 Drug Delivery -- 3.4.2.4 Antibacterial Activity -- 3.4.3 Catalysis -- 3.4.3.1 CO Oxidation -- 3.4.3.2 Activation and Conversion of CO2 -- 3.4.3.3 Water-Gas Shift (WGS) -- 3.4.4 Other Applications of Surface Modified MXenes -- 3.4.4.1 Sensors -- 3.4.4.2 Membrane-Based Separation -- 3.5 Conclusion and Future Perspectives -- References -- Chapter 4 Electronic, Electrical and Optical Properties of MXenes -- 4.1 Introduction -- 4.2 Structure of MXenes -- 4.3 An Overview of Various Methods of Synthesis of MXenes -- 4.3.1 Aqueous Acid Etching (AAE) Method -- 4.3.2 Chemical Vapor Deposition (CVD) Method -- 4.4 Electronic Properties -- 4.4.1 Density of States and Electronic Distribution -- 4.4.2 Band Structure and Bandgap Estimation -- 4.4.3 Methods to Enhance Electronic Properties -- 4.5 Electrical Properties -- 4.5.1 MXene Structure and Composition -- 4.5.2 Electrical Conductivity -- 4.5.3 Surface Functionalization -- 4.5.4 Methods to Enhance Electrical Properties -- 4.6 Optical Properties -- 4.6.1 Photoluminescence Response -- 4.6.2 Absorption Properties -- 4.6.3 Dielectric Properties -- 4.6.4 Non-Linear Optical Properties -- 4.6.5 Plasmonic Properties -- 4.6.6 Methods to Improve the Optical Properties -- 4.7 Conclusion -- References. ; Chapter 5 Magnetic, Mechanical and Thermal Properties of MXenes -- 5.1 Introduction -- 5.1.1 Applications of MXenes -- 5.1.2 Structure of MXenes -- 5.2 Magnetic Characteristics of MXenes -- 5.3 Mechanical Characteristics of MXenes -- 5.4 Thermal Characteristics of MXenes -- 5.5 Conclusion -- References -- Chapter 6 MXene-Reinforced Polymer Composites: Fabrication Methods, Processing, Properties and Applications -- 6.1 Introduction -- 6.2 Fabrication Methods and Processing -- 6.2.1 Direct Physical Mixing -- 6.2.2 Surface Modification -- 6.2.3 In Situ Polymerization -- 6.2.4 Others -- 6.3 Properties -- 6.3.1 Electrical Properties -- 6.3.2 Thermal Properties -- 6.3.3 Mechanical Properties -- 6.3.4 Photo Thermal Properties -- 6.3.5 Flame Retardant Properties -- 6.3.6 Others -- 6.4 Applications -- 6.4.1 Sensors -- 6.4.2 Energy Applications -- 6.4.3 Electromagnetic Interference Shielding -- 6.4.4 Catalytically Conversion -- 6.4.5 Oil/Water Separation -- 6.4.6 Others -- 6.5 Conclusion and Outlook -- Acknowledgment -- References -- Chapter 7 Structural, Morphological and Tribological Properties of Polymer/MXene Composites -- Abbreviations -- 7.1 Introduction -- 7.2 Overview of MXene -- 7.3 MXene/Polymer Nanocomposites -- 7.4 MXene/Polymer Nanocomposite Fabrication Methods -- 7.4.1 Solution Mixing -- 7.4.2 In Situ Polymerization Blending -- 7.4.3 Hot Press -- 7.4.4 Other Methods -- 7.5 Characteristics of Polymer/MXene Composites -- 7.5.1 Structural Properties -- 7.5.2 Tri-Biological Properties -- 7.5.3 Morphological Properties -- 7.5.4 Interfacial Strength -- 7.5.5 Other Properties -- 7.6 Novel Applications of Polymer/MXene Composites -- 7.7 Conclusion and Outlook -- References -- Chapter 8 MXene-Reinforced Polymer Composites for Dielectric Applications -- 8.1 Introduction -- 8.2 Synthesis of MXene -- 8.2.1 Etching of MAX Phases. ; 8.2.2 Modified Acid Etching Methods of MAX Phases -- 8.2.3 Fluoride Salts as Etchants -- 8.2.4 Fluoride-Free Synthesis Methods -- 8.3 Modification Strategies of MXene -- 8.3.1 Covalent Interaction -- 8.3.2 Non-Covalent Interaction -- 8.4 Synthesis Methods and Fabrication of MXene-Based Polymer Composites -- 8.4.1 Ex Situ Mixing -- 8.4.2 In Situ Mixing -- 8.4.3 Fabrication Techniques -- 8.4.3.1 Drop Casting -- 8.4.3.2 Vacuum-Assisted Filtration (VAF) -- 8.4.3.3 Hot Press (HP) -- 8.5 Properties of MXene/Polymer Composite -- 8.5.1 Electronic and Dielectric Property -- 8.5.2 Dielectric Constant -- 8.5.3 Dielectric Loss -- 8.5.4 Breakdown Strength -- 8.5.5 AC Electrical Conductivity -- 8.6 Dielectric Applications of MXene/Polymer Composite Materials -- 8.7 Conclusion -- References -- Chapter 9 MXenes-Reinforced Polymer Composites for Microwave Absorption and Electromagnetic Interference Shielding Applications -- 9.1 Introduction to MXenes -- 9.1.1 Structure and Properties -- 9.1.2 Applications -- 9.2 Materials for EMI Shielding and Microwave Absorption -- 9.3 MXenes-Based Materials for EMI Shielding and Microwave Absorption -- 9.3.1 MXenes -- 9.3.2 MXenes/Carbon Composites -- 9.3.3 MXenes/Magnetic Materials -- 9.3.4 MXenes/Polymer Composites -- 9.3.5 Hybrid Combinations -- 9.4 EMI Shielding Mechanisms for MXene-Based Materials -- 9.5 MXenes/Polymer Composites for EMI Shielding and Microwave Absorption -- 9.6 Electrospun Fibers with MXenes as Additives -- 9.7 Conclusions and Future Outlook -- References -- Chapter 10 Polymer/MXene Composites for Supercapacitor and Electrochemical Double Layer Capacitor Applications -- 10.1 Introduction -- 10.2 MXene-Polymer Composites -- 10.2.1 Classification -- 10.2.2 Preparation Methods -- 10.2.2.1 Ex Situ Blending (Solvent Processing) -- 10.2.2.2 In Situ Polymerization -- 10.2.2.3 Other Preparation Methods. ; 10.2.3 Properties -- 10.2.3.1 Electrical Properties -- 10.2.3.2 Thermal Properties -- 10.2.3.3 Mechanical Properties -- 10.3 Applications of MXene Polymer Composites for Supercapacitor Applications -- 10.3.1 Introduction to Supercapacitor and Its Classification -- 10.3.2 Classification of Supercapacitor -- 10.3.3 Recent Advancements and Achievements in Various MXene-Polymer Composites for Supercapacitor Applications -- 10.4 Challenges and Future Perspectives -- 10.5 Conclusion -- References -- Chapter 11 MXene-Based Polymer Composites for Hazardous Gas and Volatile Organic Compound Detection -- 11.1 Introduction -- 11.2 Synthesis of MXenes and MXene-Polymer Composites -- 11.2.1 Synthesis of MXenes -- 11.2.2 Synthesis of MXene-Based Composites -- 11.2.3 MXene-Polymer Composites -- 11.3 Properties of MXenes and MXene-Polymer Composites -- 11.3.1 Mechanical Properties -- 11.3.2 Electronic Properties -- 11.3.3 Magnetic Properties -- 11.4 Mxene-Polymer Composites Applications -- 11.4.1 Detection of VOCs and Hazardous Gases -- 11.4.2 Environment-Related Applications -- 11.4.2.1 Catalysis -- 11.4.2.2 Electrocatalysis -- 11.4.2.3 Photocatalysis -- 11.4.3 Water Remediation -- 11.5 Future Directions -- 11.5.1 Bioimaging -- 11.5.1.1 Magnetic Resonance Imaging (MRI) -- 11.5.1.2 Photoacoustic (PA) Imaging -- 11.5.2 Computed Tomography (CT) -- 11.5.3 Bone Regeneration -- 11.6 Conclusion -- Acknowledgement -- References -- Chapter 12 MXene-Reinforced Polymer Composites as Flexible Wearable Sensors -- 12.1 Introduction -- 12.2 Performance Parameter for Flexible Pressure and Strain Sensor -- 12.2.1 Sensitivity -- 12.2.2 Stretchability -- 12.2.3 Hysteresis -- 12.2.4 Durability and Range -- 12.3 Design of MXenes/Polymer Composites as Flexible Pressure Sensors -- 12.4 Design of MXenes/Polymer Composites as Flexible Strain Sensors. ; 12.5 Design of MXenes/Biopolymer Composites as a Flexible Pressure Sensor.
• Sommario/riassunto: This book explores the integration of MXenes, a class of two-dimensional materials, into polymer composites, focusing on their synthesis, fabrication methods, properties, and applications. Edited by a team of international experts, it provides a comprehensive overview of the fundamental properties of MXenes, including their electronic, magnetic, and thermal characteristics. The book discusses various synthesis methods such as chemical exfoliation and delamination, and delves into surface modification strategies to enhance their properties. It also covers the application of MXene-polymer composites in energy storage, biomedical fields, electronic devices, and electromagnetic interference shielding. The intended audience includes researchers, engineers, and professionals in materials science and polymer engineering fields, aiming to understand the latest advancements in MXene technology and their practical applications.
• Titolo autorizzato: MXene Reinforced Polymer Composites
• ISBN: 9781119901273; 1119901278; 9781119901266; 111990126X; 9781119901280; 1119901286
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911019765403321
• Lo trovi qui: Univ. Federico II