Metal-Carbon Bonds in Enzymes and Cofactors / / Helmut Sigel, Astrid Sigel, Roland K.O. Sigel

• Pubblicazione: Berlin ; ; Boston : , : De Gruyter, , [2015]; ©2009
• Descrizione fisica: 1 online resource
• Soggetto topico: Anorganische Chemie; Bioanorganische Chemie; Biochemie; Koordinationschemie; SCIENCE / Chemistry / Inorganic
• Persona (resp. second.): SigelAstrid; SigelHelmut; SigelRoland K.O.
• Nota di contenuto: Frontmatter -- Historical Development and Perspectives of the Series / Sigel, Astrid / Sigel, Helmut / Sigel, Roland K. O. -- Preface to Volume 6: Metal-Carbon Bonds in Enzymes and Cofactors -- Contents -- Contributors to Volume 6 -- Titles of Volumes 1-44 in the Metal Ions in Biological Systems Series -- 1 Organometallic Chemistry of B12 Coenzymes / Kräutler, Bernhard -- 2 Cobalamin- and Corrinoid-Dependent Enzymes / Matthews, Rowena G. -- 3 Nickel-Alkyl Bond Formation in the Active Site of Methyl-Coenzyme M Reductase / Jaun, Bernhard / Thauer, Rudolf K. -- 4 Nickel-Carbon Bonds in Acetyl-Coenzyme A Synthases/Carbon Monoxide Dehydrogenases / Lindahl, Paul A. -- 5 Structure and Function of [NiFe]-Hydrogenases / Fontecilla-Camps, Juan C. -- 6 Carbon Monoxide and Cyanide Ligands in the Active Site of [FeFe]-Hydrogenases / Peters, John W. -- 7 Carbon Monoxide as Intrinsic Ligand to Iron in the Active Site of [Fe]-Hydrogenase / Shima, Seigo / Thauer, Rudolf K. / Ermler, Ulrich -- 8 The Dual Role of Heme as Cofactor and Substrate in the Biosynthesis of Carbon Monoxide / Rivera, Mario / Rodríguez, Juan C. -- 9 Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site / Lucas, Heather R. / Karlin, Kenneth D. -- 10 Interaction of Cyanide with Enzymes Containing Vanadium, Manganese, Non-Heme Iron, and Zinc / Sosa-Torres, Martha E. / Kroneck, Peter M. H. -- 11 The Reaction Mechanism of the Molybdenum Hydroxylase Xanthine Oxidoreductase: Evidence Against the Formation of Intermediates Having Metal-Carbon Bonds / Hille, Russ -- 12 Computational Studies of Bioorganometallic Enzymes and Cofactors / Liptak, Matthew D. / Van Heuvelen, Katherine M. / Brunold, Thomas C. -- Subject Index -- Author Index of Contributors to MIBS and MILS
• Sommario/riassunto: The occurrence of a wide variety of metal-carbon bonds in living organisms, ranging from bacteria to humans, is only recently recognized. Of course, the historical examples are the B12 coenzymes containing cobalt-carbon bonds, but now such bonds are also known for nickel, iron, copper, and other transition metal ions. There is no other comparable book; MILS-6, written by 17 experts, summarizes the most recent insights into this fascinating topic.
• Titolo autorizzato: Metal-Carbon Bonds in Enzymes and Cofactors
• ISBN: 3-11-043658-2
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910460806103321
• Lo trovi qui: Univ. Federico II