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Orbital interaction theory of organic chemistry [[electronic resource] /] / by Arvi Rauk



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Autore: Rauk Arvi <1942-> Visualizza persona
Titolo: Orbital interaction theory of organic chemistry [[electronic resource] /] / by Arvi Rauk Visualizza cluster
Pubblicazione: New York, : Wiley-Interscience, 2001
Edizione: 2nd ed.
Descrizione fisica: 1 online resource (360 p.)
Disciplina: 547.128
547/.128
Soggetto topico: Molecular orbitals
Physical organic chemistry
Soggetto genere / forma: Electronic books.
Note generali: "A Wiley-Interscience publication."
Nota di bibliografia: Includes bibliographical references (p. 313-324) and index.
Nota di contenuto: CONTENTS; PREFACE; 1 SYMMETRY AND STEREOCHEMISTRY; Purpose; Definition of a Group; Molecular Point Groups; Schoenflies Notation; Interrelations of Symmetry Elements; Type Classification; Isomerism and Measurements; Stereoisomerism of Molecules; Stereotopic Relationships of Groups in Molecules; Asymmetric Synthesis and Stereochemistry; NMR and Stereochemistry; Symmetry and Structural Parameters; Note on Hybridization; Symmetry and Orbitals; Atomic Orbitals; Molecular and Group Orbitals; In What Combination?; 2 MOLECULAR ORBITAL THEORY; Introduction; Electronic Schrödinger Equation (A.1)
Fock Equations (A.42)The Basis Set (STO-3G, 6-31G*, and All That); Orbital Energies and Orbitals; Representation of MOs; Total Energies and the Hartree-Fock Limit; Successes and Failures of Hartree-Fock Theory; Beyond Hartree-Fock; Density Functional Theory; Geometry Optimization; Normal Coordinates and Harmonic Frequency Analysis; Zero Point Vibrational Energies; 3 ORBITAL INTERACTION THEORY; Relationship to Hartree-Fock Equations; Hückel Approximation; Orbital Energies and Total Electronic Energy; Case Study of a Two-Orbital Interaction; Case 1: ε[sub(A)] = ε[sub(B)], S[sub(AB)] = 0
Case 2: ε[sub(A)] = ε[sub(B)], [sub(AB)] > 0, [sub(AB)] « 1Case 3: ε[sub(A)] > ε[sub(B)], S[sub(AB)] = 0; Case 4: ε[sub(A)] > ε[sub(B)], S[sup(AB)] > 0; Effect of Overlap; Energetic Effect of Overlap; Orbital Effect of Overlap; First Look at Bonding; Relationship to Perturbation Theory; Generalizations for Intermolecular Interactions; Energy and Charge Distribution Changes from Orbital Interaction; Four-Electron, Two-Orbital Interaction; Three-Electron, Two-Orbital Interaction; Two-Electron, Two-Orbital Interaction; One-Electron, Two-Orbital Interaction; Zero-Electron, Two-Orbital Interaction
Interactions between Molecules: Many Electrons, Many OrbitalsGeneral Principles Governing the Magnitude of h[sub(AB)] and S[sub(AB)]; Interactions of MOs; Electrostatic Effects; Group Orbitals; Zero-Coordinated Atoms; Monocoordinated Atoms; Dicoordinated Atoms; Tricoordinated Atoms; Tetracoordinated Atoms; Assumptions for Application of Qualitative MO Theory; Example: Carbonyl Group; Construction of Interaction Diagram; Interpretation of Interaction Diagram; Chemical Reactivity; Why Does It Work and When Might it Not?; 4 SIGMA BONDS AND ORBITAL INTERACTION THEORY
C-X σ Bonds: X = C, N, O, F and X = F, Cl, Br, Iσ Bonds: Homolytic versus Heterolytic Cleavage; Heterolytic Cleavage of σ Bonds Involving C or H; Homolytic Cleavage of σ Bonds Involving C or H; Homonuclear σ Bonds C-C, N-N, O-O, F-F, Cl-Cl, Br-Br, and I-I; Interactions of σ Bonds; σ Bonds as Electron Donors or Acceptors; σ Bonds as Electron Acceptors; As a σ Acceptor; As a π Acceptor; σ Bonds as Electron Donors; As a σ Donor; As a π Donor; Bonding in Cyclopropane; 5 SIMPLE HÜCKEL MOLECULAR ORBITAL THEORY; Simple Hückel Assumptions
Charge and Bond Order in SHMO Theory: (S[sub(AB)] = 0, One Orbital per Atom)
Sommario/riassunto: A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction
Titolo autorizzato: Orbital interaction theory of organic chemistry  Visualizza cluster
ISBN: 1-280-26470-5
9786610264704
0-470-35106-3
0-471-46184-9
0-471-22041-8
Formato: Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione: Inglese
Record Nr.: 9910143189503321
Lo trovi qui: Univ. Federico II
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