Conjugated Polymer Synthesis and Materials Applications

• Autore: Chujo Y (Yoshiki)
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2026; ©2026
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (401 pages)
• Disciplina: 547.84
• Soggetto topico: Conjugated polymers; Materials science
• Nota di contenuto: Cover -- Half Title Page -- Title Page -- Copyright -- Contents -- About the Editor -- Preface -- 1. Transition Metal-catalyzed Polycondensation -- 1.1 Introduction -- 1.2 Ni-catalyzed Polycondensation -- 1.3 Pd-catalyzed Polycondensation -- 1.4 Pd-catalyzed Polycondensation via C-H Bond Functionalization -- 1.5 Cu- and Fe-catalyzed Polycondensation -- 1.6 Other Transition Metal-catalyzed Polymerization -- 1.7 Summary -- References -- 2. Living Conjugated Polymers -- 2.1 Introduction -- 2.2 Metal p -Binding in CTP -- 2.3 Catalysts for CTP -- 2.4 Kumada-Corriu Catalyst-transfer Polymerization -- 2.5 Catalyst-transfer Polymerization with Organolithium Reagents -- 2.6 Negishi Catalyst-transfer Polymerization -- 2.7 Suzuki-Miyaura Catalyst-transfer Polymerization -- 2.8 Stille Catalyst-transfer Polymerization (Stille CTP -- 2.9 Buchwald-Hartwig Amination and Direct Arylation Polymerization ( C-H Activation) -- 2.10 Chain-growth Polymerization of Aromatics Without Metal Catalysts -- 2.11 Conclusion -- Acknowledgment -- Abbreviations -- Polymers -- Metal Catalysts -- Ligands -- Miscellaneous Reagents and Terms -- References -- 3. Optically Active Through-space Conjugated Polymers Based on Planar Chiral [2.2]Paracyclophane -- 3.1 Introduction -- 3.2 Through-space Conjugation of [2.2]Paracyclophane-based Conjugated Polymers -- 3.3 Optically Active Through-space Conjugated Polymers Based on Planar Chiral [2.2]Paracyclophane -- 3.4 Optically Active Through-space Conjugated Cyclic Oligomers Based on Planar Chiral [2.2]Paracyclophane -- 3.5 Conclusion -- References -- 4. Development of Solid-state Luminescent Conjugated Polymers Containing Boron Element-blocks and Their Applications -- 4.1 Introduction -- 4.2 Boron Ketoiminates -- 4.2.1 Transformation of the Conventional Luminescent Complex to AIE-active One. ; 4.2.2 Modulation of the Direction of Color Changes in Mechanochromic Luminescence Behaviors by the Substituent Effect -- 4.2.3 Requirement of Heat-insensitive Mechanochromic Luminescent Materials -- 4.2.4 Development of Heat-insensitive Mechanochromic Luminescent Materials -- 4.2.5 Development of AIE-active Conjugated Polymers -- 4.2.6 Enhancement of Solid-state Luminescent Properties -- 4.2.7 Development of the Thermochromic and Mechanochromic Luminescent Polymers -- 4.2.8 Enhancement of Environmental Sensitivity -- 4.2.9 Mechanochromic Luminescent Sensor for Marking a Tiny Spot -- 4.3 Rational Design for AIE-active Molecules Based on Excitation-driven Complexes -- 4.3.1 Idea of Excitation-driven Complexes and Logical Design from Scratch -- 4.3.2 Design for Planar AIE-active Molecules -- 4.3.3 Development of Solid-state Luminescent Polymers -- 4.3.4 Stimuli-responsive Materials Based on Regioregular Conjugated Polymer -- 4.3.5 Injection of Stimuli-responsiveness into Conjugated Polymer by Element Replacement -- 4.4 AIE-active Materials Possessing NIR Luminescent Properties -- 4.4.1 Transformation to NIR-luminescent Materials by Aza-substitution at "the Isolated LUMO -- 4.4.2 NIR-AIE Molecules and Polymers and Their Applications -- 4.5 Conclusion -- References -- 5. Arsenic-containing Conjugated Polymers -- 5.1 Introduction -- 5.2 Arsenic in Organic Compounds -- 5.3 As-C Bond Formation -- 5.3.1 Conventional Methodologies -- 5.3.2 In Situ Generation of Organoarsenic Electrophile from Arsenic Homocycles -- 5.3.3 In Situ Generation of Organoarsenic Nucleophile from Arsenic Homocycles -- 5.3.4 Preparation and Utilization of Tribromoarsine -- 5.4 Arsenic-containing p -conjugated Systems -- 5.4.1 Arsole Derivatives -- 5.4.2 Other Arsenic-containing p -conjugated Systems -- 5.5 Poly(vinylene-arsine)s -- 5.5.1 Synthesis of Poly(vinylene-arsine)s. ; 5.5.2 Properties of Poly(vinylene-arsine)s -- 5.5.3 Poly(vinylene-phosphine)s and Poly(vinylene-stibine)s -- 5.5.4 Cross-linked Poly(vinylene-arsine)s -- 5.6 Arsole Polymers -- 5.7 p -Conjugated Polymers with Other Arsenic Units -- 5.8 Conclusion -- References -- 6. Carborane-containing Conjugated Polymers and Their Applications for Optoelectronic Materials -- 6.1 Introduction -- 6.2 Advanced Functional Materials -- 6.2.1 Hydrogen Storage -- 6.2.2 Enhancement of Thermal Stability of Composites -- 6.3 Electronic Properties of Carborane-containing Conjugated Polymers -- 6.3.1 Electrochemical Polymerization -- 6.3.2 Electric Devices -- 6.3.3 Applications for OPV -- 6.4 Luminescent Materials -- 6.4.1 Luminescent Materials and Devices -- 6.4.2 Aggregation-induced Emission -- 6.5 Photochemistry of o-carboranes -- 6.5.1 Demands for Solid-state Luminescent Materials -- 6.5.2 Experimental Proofs for Emission Annihilation Through the Bond Elongation at the Carbon-Carbon Bond in o-carborane -- 6.5.3 CT Emission of Aryl-modified o-carboranes -- 6.5.4 Angular Dependency of Electron Acceptor Properties of the o-carborane Unit -- 6.5.5 Twisted intramolecular Charge Transfer in the Crystalline State -- 6.6 Applications for Solid-state Luminescent Materials -- 6.6.1 Development of Highly Efficient Solid-state Luminescent Materials -- 6.6.2 High Emission Efficiency of Bis-o-carborane-modified Aromatic Systems -- 6.6.3 Solid-state Luminescence of Nido-carborane -- 6.6.4 Enhancement to Luminescent Efficiencies by Thermal Rearrangement from Ortho- to Meta-carborane -- 6.7 Stimuli-responsive Luminochromic Materials -- 6.7.1 Multi-stimuli-responsiveness of Bis-o-carborane-modified Anthracene -- 6.7.2 Real-time Thermochromic Luminescent Properties of Bis-o-carboranemodified Benzodithiophenes. ; 6.7.3 Constant Luminescent Properties During Phase Changes and Luminochromic Behaviors -- 6.7.4 Aggregation-caused Luminochromic Properties in the Polymer Film for Constructing Film-type Sensors -- 6.7.5 Thermochromic Luminescence by the Regulation of Rotation of o-carborane -- 6.8 Conclusion -- References -- 7. Low-bandgap Conjugated Polymers -- 7.1 Introduction -- 7.2 Design Principles of LBG-CPs -- 7.2.1 D-A Interaction for Bandgap Reduction -- 7.2.2 Stabilized Quinoidal Resonance for Bandgap Reduction -- 7.3 Synthesis of LBG-CPs -- 7.3.1 Stille Coupling for Constructing LBG-CPs -- 7.3.1.1 Synthesis of LBG-CPs Based on Thieno[3,4-b]Thiadiazole (TT) and Its Derivatives -- 7.3.1.2 Synthesis of LBG-CPs Based on Benzothiadiazole (BT) and Its Derivatives -- 7.3.1.3 Synthesis of LBG-CPs Based on Benzobisthiadiazole (BTT) and Its Derivatives -- 7.3.1.4 Synthesis of LBG-CPs Based on Diketopyrrolopyrrole (DPP) and Its Derivatives -- 7.3.1.5 Synthesis of LBG-CPs Based on Isoindigo (IID) and Its Derivatives -- 7.3.1.6 Synthesis of LBG-CPs Based on Benzofurandione (BFDO) and Its Derivatives -- 7.3.1.7 Synthesis of LBG-CPs Based on 4,4'-difluoro-4-bora-3a,4a-diazas- indacene (BODIPY) and Its Derivatives -- 7.3.2 Other Polymerization Methods for Constructing LBG-CPs -- 7.3.2.1 Suzuki Coupling -- 7.3.2.2 Aldol Condensation -- 7.4 Application of LBG-CPs -- 7.4.1 Application in OPDs -- 7.4.2 Application in OTEs -- 7.4.3 Application in Bioimaging and PTT -- 7.5 Conclusions and Perspective -- Acknowledgments -- References -- 8. Polymers with Three-dimensional Conjugated Molecules -- 8.1 Introduction -- 8.2 Corannulene-containing Polymer -- 8.3 Supramolecular Polymers Based on Bowl-shaped p -conjugated Molecules -- 8.4 Helicene-based Polymers -- 8.5 Conclusion and Outlook -- Acknowledgment -- References -- 9. Conjugated Polymers for Energy Storage Devices. ; 9.1 Introduction -- 9.2 Conjugated Polymers as Binder Materials in LIBs -- 9.2.1 Graphite Anodes -- 9.2.2 Si Anodes -- 9.3 Conjugated Polymers as Anodic Active Materials -- 9.3.1 Organic Anodes -- 9.3.2 Hard Carbons -- 9.4 Polymerizable Conjugated Molecules as Electrolyte Additives -- 9.5 p -Conjugated Polymers as Electrocatalysts -- 9.6 Conclusion -- 9.6.1 Binders -- 9.6.2 Active Materials -- 9.6.3 Electrolyte Additives -- 9.6.4 Catalysts in Li-O2 Batteries -- References -- 10. Conjugated Polymers and Their Applications in Organic Field Transistors, Organic Electrochemical Transistors, and Organic Thermoelectrics -- 10.1 Introduction -- 10.1.1 What Makes the CP Semiconducting -- 10.1.2 What Are the Charge Carriers -- 10.1.3 Formation of Charge Carriers -- 10.1.4 Band Structure -- 10.1.5 Ion Transport -- 10.1.6 Morphology and Multilevel Microstructures -- 10.2 Polymers for Organic Field Effect Transistors -- 10.2.1 Introduction -- 10.2.2 Example p-type Polymers -- 10.2.2.1 Thiophene-based Polymers -- 10.2.2.2 Indacenodithiophene-based Polymers -- 10.2.2.3 Isoindigo-based Polymers -- 10.2.2.4 Cyclopentadithiophene-based Polymers -- 10.2.3 Example n-type Polymers -- 10.2.4 Example Ambipolar Polymers -- 10.2.4.1 Isoindigo-based Polymers -- 10.2.5 Key Approaches to Improve OFET Performance -- 10.2.5.1 Backbone Modifications -- 10.2.5.2 Side Chain Modifications -- 10.2.5.3 Device Architecture -- 10.2.6 Application and Future Outlook -- 10.3 Organic Electrochemical Transistors -- 10.3.1 Design Principle -- 10.3.2 Example Polymers -- 10.3.2.1 P-type -- 10.3.3 N-type -- 10.3.3.1 Imide-based -- 10.3.3.2 Isoindigo -- 10.3.3.3 Diketopyrrolopyrrole -- 10.3.3.4 Ladder Type -- 10.3.3.5 Acceptor-Acceptor -- 10.3.4 Summary Tables of Reviewed p- and n-type Materials -- 10.3.4.1 P-type Materials -- 10.3.4.2 N-type Materials -- 10.4 Organic Thermoelectrics. ; 10.4.1 Introduction.
• Sommario/riassunto: Comprehensive reference exploring the synthesis, preparation, and applications of new and novel conjugated polymers Conjugated Polymer Synthesis and Materials Applications summarizes the fundamentals and major developments in the synthesis of new conjugated polymers.
• Titolo autorizzato: Conjugated Polymer Synthesis and Materials Applications
• ISBN: 3-527-84945-9; 3-527-84944-0
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911048000103321
• Lo trovi qui: Univ. Federico II