Fundamentals and applications of biosorption isotherms, kinetics and thermodynamics [[electronic resource] /] / Yu Liu and Jianlong Wang, editors

• Pubblicazione: Hauppauge, N.Y., : Nova Science Publishers, c2009
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (304 p.)
• Disciplina: 660.6/2
• Soggetto topico: Microbial biotechnology; Adsorption (Biology)
• Altri autori: LiuYu <1964-> WangJianlong
• Note generali: Includes index.
• Nota di contenuto: Intro -- FUNDAMENTALS AND APPLICATIONSOF BIOSORPTION ISOTHERMS,KINETICS AND THERMODYNAMICS -- FUNDAMENTALS AND APPLICATIONSOF BIOSORPTION ISOTHERMS,KINETICS AND THERMODYNAMICS -- LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA -- CONTENTS -- PREFACE -- Chapter 1: BASIC MICROBIOLOGY: MICROBIAL STRUCTURE AND FUNCTION -- 1.1. OVERVIEW OF CELL STRUCTURE -- 1.1.1. Prokaryotes and Eukaryotes -- 1.1.2. Cellular Structure -- (i) Cellular Wall -- ii) Cellular Membrane -- (iii) Cytoplasm -- iv) Nuclear Area -- 1.2. BACTERIA -- 1.2.1. Size and Shape -- 1.2.2. Cell Structure -- 1.2.3. Cell Wall -- (I) Gram-Positive Cell Walls -- (II) Gram-Negative Cell Walls -- 1.2.4. Capsules -- 1.2.5. S-Layers -- 1.3. FUNGI -- 1.4. ALGAE -- 1.5. CHEMICAL FUNCTIONAL GROUPSRELATED TO THE BIOSORPTION -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 2: BIOSORBENTS -- 2.1. TYPES OF BIOSORBENTS -- 2.2. BACTERIA -- 2.3. FUNGI -- 2.3.1. Yeast - Saccharomyces Cerevisiae -- 2.3.1.1. Advantages of S. Cerevisiae as Biosorbents in Metal Biosorption -- 2.3.1.2. Forms of S. Cerevisiae Used for Biosorption -- 2.3.1.3. Biosorptive Capacity of S. Cerevisiae -- 2.3.1.4. Selectivity and Competitive Biosorption by S. Cerevisiae -- 2.3.2. Filamentous Fungi -- 2.3.2.1. Penicillium -- 2.3.2.2. Aspergillus -- 2.3.2.3. White Rot Fungi -- 2.3.3. Selectivity and Competitive Biosorption by Fungi -- 2.3.4. Comparison among Fungi and Yeast and Other Biomaterials -- 2.4.MARINE ALGAE -- 2.4.1. Introduction to Microbiology of Algae -- 2.4.2. Algae Used for Biosorption -- 2.5. EFFECT OF PRE-TREATMENT ON BIOSORPTION -- 2.6. IMMOBILIZED BIOMASS FOR BIOREACTORSAND REGENERATION/REUSE -- 2.7. BIOSORBENT SELECTION AND ASSESSMENT -- 2.8. DEVELOPMENT OF NOVEL BIOSORBENTS -- 2.9. COMMERCIAL APPLICATIONS -- 2.9.1. Several Attempts of the Biosorption Commercialization -- 2.9.2. Application Feasibility and Considerations. ; 2.10. OPPORTUNITY OF BIOSORPTION RESEARCH -- 2.11. CHALLENGES OF BIOSORPTION RESEARCH -- 2.12. SELECTION OF BIOMATERIALS -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 3: BIOSORPTION ISOTHERMSAND THERMODYNAMICS -- 3.1. INTRODUCTION -- 3.2. LANGMUIR ISOTHERM EQUATION -- 3.2.1. Equilibrium Approach for Derivation of Langmuir Isotherm -- 3.2.2. Kinetic Approach for Derivation of Langmuir Isotherm -- 3.2.3. Some Consideration on Use of Langmuir Kinetics -- 3.3. FREUNDLICH ISOTHERM EQUATION -- 3.4. SIPS ISOTHERM EQUATION -- 3.4.1. Derivation from an Equilibrium Approach -- 3.4.2. Derivation of Sips Isotherm from a Thermodynamic Approach -- 3.5. REDLICH-PETERSON ISOTHERM EQUATION -- 3.6. KHAN ISOTHERM EQUATION -- 3.7. TOTH ISOTHERM EQUATION -- 3.8. RADKE-PRAUSNITZ ISOTHERM EQUATION -- 3.9. DUBININ-RADUSHKEVICH ISOTHERM EQUATION -- 3.10. FRUMKIN ISOTHERM EQUATION -- 3.11. FLORY-HUGGINS ISOTHERM EQUATION -- 3.12. BET ISOTHERM EQUATION -- 3.13. TEMKIN ISOTHERM EQUATION -- 3.14. ADSOPRTION/BIOSORPTION THERMODYNAMICS -- 3.15. EFFECTS OF INITIAL CONDITIONS ON BIOSORPTION -- 3.15.1. Experimentally Observed Effects of Initial Conditions on Biosorption -- (I) Effect of Initial Adsorbate Concentration on Biosorption Kinetics and Equilibrium -- (II) Effect of Initial Biosorbent Concentration on Biosorption -- 3.15.2. Theoretical Interpretation on the Effect of Initial Conditions on BiosorptionRate Constant -- 3.15.3. Theoretical Interpretation on the Effect of Initial Conditions on Biosorption Equilibrium -- 3.16. SOME OTHER APPROACHES FOR EQUILIBRIUM MODEL -- REFERENCES -- Chapter 4: BIOSORPTION KINETICS -- 4.1. INTRODUCTION -- 4.2. PSEUDO FIRST-ORDER RATE EQUATIONFOR ADSORPTION/BIOSORPTION -- 4.2.1. Approach by Boyd et al. (1947) for Derivation of Pseudo First-order Equation -- 4.2.2. Approach by Liu et al. (2003) for Derivation of Pseudo First-order Equation. ; 4.2.3. Approach by Azizian (2004) for Derivation of Pseudo First-order Equation -- 4.2.4. Approach by Rudzinski and Plazinski (2006) for Derivation of Pseudo First-Order Equation -- 4.2.5. Estimate of Kinetic Constants in First-order Rate Equation -- 4.3. PSEUDO SECOND-ORDER RATE EQUATION FOR ADSORPTION/BIOSORPTION -- 4.3.1. Approach by Blanchard et al. (1984)for Derivation of Pseudo Second-order Equation -- 4.3.2. Approach by Azizian (2004)for Derivation of Pseudo Second-order Equation -- 4.3.4. Approach by Rudzinski and Plazinski (2006) for Derivation of Pseudo Second-order Equation -- 4.3.5. Estimate of Kinetic Constants in Second-order Rate Equation -- 4.4. LANGMUIR KINETICS FOR ADSORPTION/BIOSORPTION -- 4.5. A GENERAL RATE LAW EQUATIONFOR ADSORPTION/BIOSORPTION -- 4.5.1. Uncertainty of Preset-order Rate Equations in Description of Biosorption Data -- (1) Description of Biosorption Data by Various Preset-Order Kinetic Equations -- (2) Uncertainty Incurred in Kinetic Description of Biosorption Data -- 4.5.2. A General Kinetic Equation for Biosorption -- (i) Approach by Liu and Shen (2008a) -- (ii) Approach by Brouers and Sotolongo-Costa (2006) -- 4.6. OTHER USEFUL KINETIC EQUATIONSFOR ADSORPTION/BIOSORPTION -- 4.6.1. Elovich Equation -- 4.6.2. Weber-Morris Equation or Intraparticle Diffusion Equation -- 4.7. SOME STATISTICAL METHODS FOR EVALUATION OFADSORPTION/BIOSORPTIONMODELS FITNESS -- 4.7.1. Correlation Coefficient -- 4.7.2. Prediction Error Square -- 4.7.3. Relative Goodness of Curve Fitting -- 4.7.4. F-test -- 4.7.5. P-value -- 4.7.6. Remarks -- REFERENCES -- Chapter 5: GENERAL MECHANISMS OF BIOSORPTION -- 5.1. INTRODUCTION -- 5.2. PROCESS OF METAL ION SORPTION -- 5.3. EXTRA CELLULAR ACCUMULATION/PRECIPITATION -- 5.4. CELL SURFACE SORPTION/PRECIPITATION -- 5.4.1. Ion Exchange -- 5.4.2. Complexation -- 5.4.3. Precipitation and Redox Reaction. ; 5.5. INTRACELLULAR ACCUMULATION -- 5.6. INSTRUMENTAL TOOLS AND TECHNIQUES -- 5.6.1. Introduction -- 5.6.2. FTIR -- 5.6.3. Titration -- 5.6.4. SEM-EDX -- 5.6.5. TEM-EDX -- 5.6.6. AFM -- 5.6.7. XAS -- 5.6.8. XPS -- 5.6.9. NMR -- 5.6.10. CLSM -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 6: FACTORS INFLUENCING BIOSORPTION PROCESS -- 6.1. INTRODUCTION -- 6.2. PROPERTIES OF METAL IONS -- 6.3. INFLUENCE OF PH -- 6.4. TEMPERATURE EFFECT -- 6.5. IONIC STRENGTH EFFECT -- 6.6. PRESENCE OF ANIONS AND CATIONS -- 6.7. OTHER FACTORS -- 6.7.1. Contact Time -- 6.7.2. Cell Culture Conditions -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 7: CORRELATING METAL IONIC CHARACTERISTICSWITH BIOSORPTION CAPACITY -- 7.1. EFFECTS OF ION CHARACTERISTICSON METAL BIOSORPTION -- 7.2. THEORETIC BASIS FOR APPLICATIONOF QICARS IN METAL BIOSORPTION -- 7.3. APPLICATION OF QSARS METHODIN BIOSORPTION OF METAL IONS -- 7.4.METAL ION CHARACTERISTICS PARAMETERSAND CORRELATION APPROACH -- 7.4.1. Biomass and Metal Ions -- 7.4.2. Selection of Characteristic Parameters -- 7.4.3. Maximum Biosorption Capacity qmax -- 7.4.4. Characteristic and Qmax: Correlation of Relationships -- 7.5. CLASSIFICATION OF METAL IONSAND THEIR SORPTION CAPACITY -- 7.6. EFFECT OF ION CHARACTERISTICSON METAL-BIOMASS INTERACTION -- 7.7. REMARKS -- ACKNOWLEDGMENTS -- REFERENCES -- Chapter 8: BIOSORPTION OF HEAVY METALS BY AEROBICGRANULES:AN INNOVATIVE APPROACH -- 8.1. INTRODUCTION -- 8.2.WHAT ARE AEROBIC GRANULES? -- 8.3. PROBLEM ASSOCIATED WITH APPLICATIONOF BIOSORPTION TECHNOLOGY -- 8.4. ELEMENTAL COMPOSITIONOF FRESH AEROBIC GRANULES -- 8.5. ELEMENTAL COMPOSITION OF AEROBICGRANULES AFTER BIOSORPTION -- 8.6. CHEMICAL PRECIPITATION OF HEAVYMETALS DURING BIOSORPTION -- 8.7. CONTRIBUTION OF ECP TO BIOSORPTION -- 8.8. CONTRIBUTION OF ION EXCHANGE TO BIOSORPTION -- 8.9. ROLE OF GRANULE FUNCTIONALGROUPS TO METAL BIOSORPTION. ; 8.10. SPATIAL DISTRIBUTION OF ADSORBEDHEAVY METAL IN AEROBIC GRANULE -- 8.11. EFFECT OF PH ON BIOSORPTIONOF HEAVY METAL BY AEROBIC GRANULES -- REFERENCES -- INDEX.
• Titolo autorizzato: Fundamentals and applications of biosorption isotherms, kinetics and thermodynamics
• ISBN: 1-61728-660-5
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910807215103321
• Lo trovi qui: Univ. Federico II
• Serie: Environmental science, engineering and technology series.