Basics of analytical chemistry and chemical equilibria / / Brian M. Tissue

• Pubblicazione: Hoboken, N.J., : Wiley, c2013; Hoboken, NJ : , : John Wiley & Sons, Inc., , c2013
• Edizione: 1st ed.
• Descrizione fisica: xi, 413 p. : ill
• Disciplina: 543
• Soggetto topico: Chemical equilibrium; Chemistry, Analytic
• Classificazione: 433; 543
• Note generali: Includes index.
• Nota di contenuto: COVER -- TITLE PAGE -- COPYRIGHT -- CONTENTS -- PREFACE -- I QUANTITATIVE ANALYSIS USING REACTIONS THAT GO TO "COMPLETION -- 1 MAKING MEASUREMENTS -- 1.1 Introduction -- 1.2 GLP and a Few Other Important Acronyms -- 1.3 Precision and Random Error -- 1.4 Discarding a Suspected Outlier -- 1.5 Calibration -- 1.6 Maintaining Accurate Results -- Practice Exercises -- 2 SAMPLE PREPARATION, EXTRACTIONS, AND CHROMATOGRAPHY -- 2.1 Sampling and Control Samples -- 2.2 Sample Preparation -- 2.3 Solvents and Solutions -- 2.4 Introduction to Solubility -- 2.5 Extraction -- 2.6 Stationary Phases -- 2.7 Solid-Phase Extraction (SPE) -- 2.8 Introduction to Chromatography -- 2.9 Immunoassays -- Practice Exercises -- 3 CLASSICAL METHODS -- 3.1 Introduction -- 3.2 Review of Chemical Reactions -- 3.3 Reactions in Aqueous Solution -- 3.4 Gravimetry -- 3.5 Titration -- 3.6 Titration Curves -- 3.7 Coulometry -- Practice Exercises -- 4 MOLECULAR SPECTROSCOPY -- 4.1 Introduction -- 4.2 Properties of EM Radiation -- 4.3 Electromagnetic Spectrum -- 4.4 Spectroscopic Transitions -- 4.5 UV/Vis Absorption Spectroscopy -- 4.6 UV/Vis Instrumentation -- 4.7 Beer-Lambert Law -- 4.8 Molecular Fluorescence -- Practice Exercises -- II REACTIONS THAT DO NOT GO TO "COMPLETION." EQUILIBRIA IN AQUEOUS SOLUTIONS -- 5 ACID-BASE EQUILIBRIA AND ACTIVITY -- 5.1 Acids and Bases -- 5.2 Weak Acids and Weak Bases -- 5.3 Water and Kw -- 5.4 Acid Strength -- 5.5 The Concept of Activity -- 5.6 Acid-Base Equilibrium Calculations -- Practice Exercises -- 6 BUFFER SOLUTIONS AND POLYPROTIC ACIDS -- 6.1 Buffer Solutions -- 6.2 Alpha Fraction Plots -- 6.3 Weak Acid Titration Curve -- 6.4 Polyprotic Acids -- Practice Exercises -- 7 COMPLEXATION AND PRECIPITATION EQUILIBRIA -- 7.1 Complex Terminology -- 7.2 Complex Equilibria -- 7.3 Competing Equilibria -- 7.4 Stepwise Complexation. ; 7.5 Precipitate Equilibrium -- 7.6 Molar Solubility -- 7.7 Precipitation and Competing Equilibria -- Practice Exercises -- III INSTRUMENTAL METHODS AND ANALYTICAL SEPARATIONS -- 8 ELECTROANALYTICAL CHEMISTRY -- 8.1 Introduction -- 8.2 Standard Reduction Potentials -- 8.3 Using Half Reactions -- 8.4 Background on Spontaneous Reactions and Equilibrium -- 8.5 Reaction Energies, Voltages, and the Nernst Equation -- 8.6 Electrochemical Cells -- 8.7 Potentiometry -- 8.8 Ion-Selective Electrodes (ISE) -- 8.9 Voltammetry -- Practice Exercises -- 9 ATOMIC SPECTROMETRY -- 9.1 Atomization -- 9.2 Atomic Absorption Spectrometry (AAS) -- 9.3 Atomic Emission Spectrometry (AES) -- 9.4 Introduction to Mass Spectrometry (MS) -- 9.5 ICP-MS Measurements -- 9.6 Summary -- Practice Exercises -- 10 ANALYTICAL SEPARATIONS -- 10.1 Thin-Layer Chromatography -- 10.2 Chromatogram Terminology -- 10.3 Column Selection -- 10.4 High Performance Liquid Chromatography -- 10.5 Gas Chromatography -- 10.6 Molecular Mass Spectrometry -- 10.7 Electrophoresis -- Practice Exercises -- INDEX -- EULA.
• Sommario/riassunto: Enables students to progressively build and apply new skills and knowledge Designed to be completed in one semester, this text enables students to fully grasp and apply the core concepts of analytical chemistry and aqueous chemical equilibria. Moreover, the text enables readers to master common instrumental methods to perform a broad range of quantitative analyses. Author Brian Tissue has written and structured the text so that readers progressively build their knowledge, beginning with the most fundamental concepts and then continually applying these concepts as they advance to more sophisticated theories and applications. Basics of Analytical Chemistry and Chemical Equilibria is clearly written and easy to follow, with plenty of examples to help readers better understand both concepts and applications. In addition, there are several pedagogical features that enhance the learning experience, including: Emphasis on correct IUPAC terminology "You-Try-It" spreadsheets throughout the text, challenging readers to apply their newfound knowledge and skills Online tutorials to build readers' skills and assist them in working with the text's spreadsheets Links to analytical methods and instrument suppliers Figures illustrating principles of analytical chemistry and chemical equilibria End-of-chapter exercises Basics of Analytical Chemistry and Chemical Equilibria is written for undergraduate students who have completed a basic course in general chemistry. In addition to chemistry students, this text provides an essential foundation in analytical chemistry needed by students and practitioners in biochemistry, environmental science, chemical engineering, materials science, nutrition, agriculture, and the life sciences.
• Titolo autorizzato: Basics of analytical chemistry and chemical equilibria
• ISBN: 1-118-64704-1; 1-118-64696-7; 1-118-64701-7
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910808568403321
• Lo trovi qui: Univ. Federico II
• Serie: THEi Wiley ebooks.