High-performance materials from bio-based feedstocks / / edited by Andrew J. Hunt, [and five others]

• Pubblicazione: Hoboken, New Jersey : , : Wiley, , [2022]; ©2022
• Descrizione fisica: 1 online resource (429 pages)
• Disciplina: 662.88
• Soggetto topico: Biomass chemicals
• Persona (resp. second.): HuntAndrew J.
• Note generali: Includes index.
• Nota di contenuto: Cover -- Title Page -- Copyright Page -- Contents -- List of Contributors -- Series Preface -- Chapter 1 High-performance Materials from Bio-based Feedstocks: Introduction and Structure of the Book -- 1.1 Introduction -- 1.2 High-performance Bio-based Materials and Their Applications -- 1.2.1 Biomass Constituents -- 1.2.2 Bioderived Materials -- 1.3 Structure of the Book -- References -- Chapter 2 Bio-based Carbon Materials for Catalysis -- 2.1 Introduction -- 2.2 Biomass Resources for Carbon Materials -- 2.2.1 Wood from Natural Forests -- 2.2.2 Agricultural Residues -- 2.3 Thermochemical Conversion Processes -- 2.3.1 Carbonization and Pyrolysis -- 2.3.2 Activation -- 2.3.3 Hydrothermal Carbonization -- 2.3.4 Graphene Preparation from Biomass -- 2.4 Fundamentals of Heterogeneous Catalysis -- 2.5 Catalysis Applications of Selected Bio-based Carbon Materials -- 2.5.1 Biochar -- 2.5.2 Modified Biochar -- 2.5.3 Biomass-Derived Activated Carbon -- 2.5.4 Hydrothermal Bio-based Carbons -- 2.5.5 Sugar-Derived Carbon Catalysts -- 2.5.6 Carbon Nanotubes from Biomass -- 2.5.7 Graphene and Its Derivatives -- 2.6 Summary and Future Aspects -- Chapter 3 Starbon®: Novel Template-Free Mesoporous Carbonaceous Materials from Biomass - Synthesis, Functionalisation and Applications in Adsorption, and Catalysis -- 3.1 Introduction -- 3.2 Choice of Polysaccharide -- 3.2.1 Synthetic Procedure -- 3.2.2 Derivatisation -- 3.2.3 Applications -- 3.2.4 Adsorption Processes -- 3.2.5 Conclusion -- References -- Chapter 4 Conversion of Biowastes into Carbon-based Electrodes -- 4.1 Introduction -- 4.2 Conversion Techniques of Biowastes -- 4.2.1 Carbonization -- 4.2.2 Activation -- 4.3 Structure and Doping -- 4.3.1 Biowaste Selection -- 4.3.2 Structure Control -- 4.3.3 Heteroatom Doping -- 4.4 Electrochemical Applications -- 4.4.1 Supercapacitors. ; 4.4.2 Capacitive Deionization Cells -- 4.4.3 Hydrogen and Oxygen Evolution -- 4.4.4 Fuel Cells -- 4.4.5 Lithium-Ion Batteries and Others -- 4.5 Conclusion and Outlook -- Chapter 5 Bio-based Materials in Electrochemical Applications -- 5.1 Introduction -- 5.2 Fundamentals of Bio-based Materials -- 5.2.1 Bio-based Polymers -- 5.2.2 Carbonaceous Materials from Biological Feedstocks -- 5.3 Application of Bio-based Materials in Batteries -- 5.3.1 General Concept of Metal-Ion Batteries -- 5.4 Application of Bio-based Polymers in Capacitors -- 5.4.1 General Concept of Electrochemical Capacitors -- 5.4.2 Electrode Materials -- 5.5 Alternative Binders for Sustainable Electrochemical Energy Storage -- 5.5.1 Polysaccharides and Cellulose-based Binders -- 5.5.2 Lignin -- 5.6 Application of Bio-based Polymers in Fuel Cells -- 5.6.1 Chitosan -- 5.6.2 Other Biopolymers -- 5.7 Conclusion and Outlook -- Chapter 6 Bio-based Materials Using Deep Eutectic Solvent Modifiers -- 6.1 Introduction -- 6.2 Bio-based Materials -- 6.2.1 Ionic Liquids -- 6.2.2 Deep Eutectic Solvents -- 6.2.3 Morphological/Mechanical Modification -- 6.2.4 Chemical Modification -- 6.2.5 Composite Formation -- 6.2.6 Gelation -- 6.3 Conclusion -- References -- Chapter 7 Biopolymer Composites for Recovery of Precious and Rare Earth Metals -- 7.1 Introduction -- 7.2 Mechanisms of Metal Adsorption -- 7.2.1 Silver -- 7.2.2 Gold and Platinum Group Metals -- 7.2.3 Rare Earth Metals -- 7.3 Composite Materials and Their Adsorption -- 7.3.1 Cellulose-based Composite Adsorbents -- 7.3.2 Chitosan-based Composite Adsorbents -- 7.3.3 Alginate-based Adsorbents -- 7.3.4 Lignin-based Composite Adsorbents -- 7.4 Conclusion and Outlook -- Chapter 8 Bio-Based Materials in Anti-HIV Drug Delivery -- 8.1 Introduction -- 8.2 Biomedical Strategies for HIV Prophylaxis -- 8.3 Properties of Anti-HIV Drug Delivery Systems. ; 8.4 Bio-based Materials for Anti-HIV Drug Delivery Systems -- 8.4.1 Cellulose -- 8.4.2 Chitosan -- 8.4.3 Polylactic Acid -- 8.4.4 Carrageenan -- 8.4.5 Alginate -- 8.4.6 Hyaluronic Acid -- 8.4.7 Pectin -- 8.5 Conclusion -- References -- Chapter 9 Chitin - A Natural Bio-feedstock and Its Derivatives: Chemistry and Properties for Biomedical Applications -- 9.1 Bio-feedstocks -- 9.1.1 Chitin -- 9.1.2 Chitosan -- 9.1.3 Glucan -- 9.1.4 Chitin-Glucan Complex -- 9.1.5 Polyphenols -- 9.2 Synthetic Route -- 9.2.1 Isolation of ChGC -- 9.2.2 Derivatives of ChGC and Its Modified Polymers -- 9.2.3 Preparation of d-Glucosamine from Chitin/Chitosan-Glucan -- 9.3 Properties of Chitin, ChGC, and Its Derivatives for Therapeutic Applications -- 9.3.1 Antibacterial Activity -- 9.3.2 Anticancer Activity -- 9.3.3 Antioxidant Activity -- 9.3.4 Therapeutic Applications -- 9.4 Gene Therapy - A Biomedical Approach -- 9.5 Cs: Properties and Factors Affecting Gene Delivery -- 9.6 Organic Modifications of Cs Backbone for Enhancing the Properties of Cs Associated with Gene Delivery -- 9.6.1 Modification of Cs with Hydrophilic Groups -- 9.6.2 Modification in Cs by Hydrophobic Groups -- 9.6.3 Modification by Cationic Substituents -- 9.6.4 Modification by Target Ligands -- 9.7 Multifunctional Modifications of Cs -- 9.8 Miscellaneous -- 9.9 Conclusion -- Acknowledgments -- References -- Chapter 10 Carbohydrate-Based Materials for Biomedical Applications -- 10.1 Introduction -- 10.2 Bio-based Glycopolymers -- 10.2.1 Chitin and Chitosan -- 10.2.2 Cellulose -- 10.2.3 Starch -- 10.2.4 Dextran -- 10.3 Synthetic Carbohydrate-based Functionalized Materials -- 10.3.1 Glycomimetics -- 10.3.2 Presentation of Glycomimetics in Multivalent Scaffolds -- 10.4 Conclusion -- References -- Chapter 11 Organic Feedstock as Biomaterial for Tissue Engineering -- 11.1 Introduction. ; 11.2 Protein-based Natural Biomaterials -- 11.2.1 Silk -- 11.2.2 Collagen -- 11.2.3 Decellularized Skins -- 11.2.4 Fibrin/Fibrinogen -- 11.3 Polysaccharide-based Natural Biomaterials -- 11.3.1 Chitosan -- 11.3.2 Alginate -- 11.3.3 Agarose -- 11.4 Summary -- References -- Chapter 12 Green Synthesis of Bio-based Metal-Organic Frameworks -- 12.1 Introduction -- 12.2 Green Synthesis of MOFs -- 12.2.1 Solvent-Free and Low Solvent Synthesis -- 12.2.2 Green Solvents -- 12.2.3 Sonochemical Synthesis -- 12.2.4 Electrochemical Synthesis -- 12.3 Bio-based Ligands -- 12.3.1 Amino Acids -- 12.3.2 Aliphatic Diacids -- 12.3.3 Cyclodextrins -- 12.3.4 Other -- 12.3.5 Exemplars: Bio-based MOFs Obtainable via Green Synthesis -- 12.4 Metal Ion Considerations -- 12.4.1 Calcium -- 12.4.2 Magnesium -- 12.4.3 Manganese -- 12.4.4 Iron -- 12.4.5 Titanium -- 12.4.6 Zirconium -- 12.4.7 Aluminium -- 12.4.8 Zinc -- 12.5 Challenges for Further Development Towards Applications -- 12.5.1 Stability Issues -- 12.5.2 Scalability and Cost -- 12.5.3 Competing Alternative Materials -- 12.6 Conclusion -- Chapter 13 Geopolymers Based on Biomass Ash and Bio-based Additives for Construction Industry -- 13.1 Introduction -- 13.2 Pozzolan and Agricultural Waste Ash -- 13.3 Geopolymer -- 13.4 Combustion of Biomass -- 13.4.1 Open Field Burning -- 13.4.2 Controlled Burning -- 13.4.3 Boiler Burning -- 13.4.4 Fluidized Bed Burning -- 13.5 Properties and Utilization of Biomass Ashes -- 13.6 Biomass Ash-based Geopolymer -- 13.6.1 Rice Husk Ash-based Geopolymer -- 13.6.2 Bagasse Ash-based Geopolymer -- 13.6.3 Palm Oil Fuel Ash-based Geopolymer -- 13.6.4 Other Biomass-based Geopolymers -- 13.6.5 Use of Biomass in Making Sodium Silicate Solution and Other Products -- 13.6.6 Fire Resistance of Bio-based Geopolymer -- 13.7 Conclusion -- References. ; Chapter 14 The Role of Bio-based Excipients in the Formulation of Lipophilic Nutraceuticals -- 14.1 Introduction -- 14.2 Emulsions and the Importance of Bio-based Materials as Emulsifiers -- 14.2.1 Conventional Micro- and Nanoemulsions -- 14.2.2 Pickering-Stabilised Emulsions -- 14.3 Novel Formulation Technologies: Colloidal Delivery Vesicles -- 14.3.1 Microgels -- 14.3.2 Nanoprecipitation -- 14.3.3 Liposomes -- 14.3.4 Complex Coacervation -- 14.3.5 Complexation -- 14.4 Key Drying Technologies Employed During Formulation -- 14.4.1 Spray Drying -- 14.4.2 Spray-Freeze Drying -- 14.4.3 Electrohydrodynamic Processing -- 14.4.4 Fluid Bed Drying -- 14.4.5 Extrusion -- 14.5 Conclusions and Future Perspectives -- References -- Chapter 15 Bio-derived Polymers for Packaging -- 15.1 Introduction -- 15.2 Starch -- 15.3 Chitin/Chitosan -- 15.4 Cellulose and Its Derivatives -- 15.4.1 Cellulose Nanocrystals -- 15.4.2 Cellulose Nanofibers -- 15.4.3 Bacterial Nanocellulose -- 15.4.4 Carboxymethyl Cellulose -- 15.5 Poly(Lactic Acid) -- 15.5.1 Bio-based Toughening Agents Used in PLA Toughness Improvement -- 15.5.2 Toughening of PLA and Its Properties Related to Packaging Applications -- 15.6 Bio-based Active and Intelligent Agents for Packaging -- 15.6.1 Active Agents -- 15.6.2 Intelligent Packaging -- 15.7 Conclusion -- References -- Chapter 16 Recent Developments in Bio-Based Materials for Controlled-Release Fertilizers -- 16.1 Introduction and Historical Review -- 16.1.1 Early Fertilizer Development and Its Impact on Environment -- 16.1.2 Controlled-Release Fertilizer -- 16.2 Mechanistic View of Controlled-Release Fertilizer from Bio-based Materials -- 16.2.1 Coating Type -- 16.2.2 Matrix Type -- 16.2.3 Other Release Mechanisms -- 16.3 Controlled Release Technologies from Bio-based Materials -- 16.3.1 Natural Polymers and Their Fertilizer Applications. ; 16.3.2 Bio-based Modified Polymer Coatings for Controlled-Release Fertilizer.
• Titolo autorizzato: High-Performance Materials from Bio-Based Feedstocks
• ISBN: 1-119-65574-9; 1-119-65573-0
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910566694803321
• Lo trovi qui: Univ. Federico II
• Serie: Wiley Series in Renewable Resource Ser.