Thermodynamics of surface phenomena / / R.Kh. Dadashev

• Autore: Dadashev R. Kh (Raikom Khasimkhanovich)
• Pubblicazione: Cambridge, : Cambridge International Science Publishing, 2008
• Descrizione fisica: 1 online resource (297 p.)
• Disciplina: 530.427
• Soggetto topico: Thermodynamics; Surfaces (Physics)
• Note generali: Bibliographic Level Mode of Issuance: Monograph
• Nota di bibliografia: Includes bibliographical references and index.
• Nota di contenuto: Intro -- CONTENTS -- PREFACE -- INTRODUCTION -- 1. The Gibbs method in thethermodynamics of surfacephenomena -- 1.1. Dividing surface and excess quantity in Gibbs capillarity theory -- 1.2. Excess thermodynamic potential. Gibbs adsorption equation -- 1.3. Dependence of excess thermodynamic quantities on the position of the dividing surface -- 1.4. Adsorption equilibrium in two-phase multicomponent systems -- 1.5. Calculation of adsorption in two-component systems -- 1.6. Adsorption in two-phase systems with a low content of components in one of the phases -- 1.7. Calculation of adsorption at the liquid-vacuum interface on the basis of the concentration dependence of surface tension -- 1.8. Calculation of adsorption in multicomponent systems -- 1.9. Calculation of the adsorption of components with thevariation of the composition along lines with a constant content of components, with the exception of two components -- 1.10. Calculation of adsorption of components for the variation of the composition by adding one of the components -- 1.11. Relationship between the values of adsorption in relation to different positions of the dividing surface -- 1.12. Adsorption method of determination of the molecular mass of surface-active substances -- 1.13. Criteria of the surface activity of a component in multicomponent solutions -- 2. Thermodynamic description of the surface properties by the method of the finite thickness layer -- 2.1. Effective thickness of the surface layer of solutions -- 2.2. Temperature dependence of the thickness of the surface layer of liquid metals -- 2.3. Calculation of the composition of the surface layer of multicomponent solutions on the basis of the concentration dependence of surface tension -- 2.4. The molar surface, the thickness of the surface layer and their dependence on the composition of the multicomponent solution. ; 2.5. Partial-molar quantities in multicomponent solutions. Partial-molar surfaces -- 2.6. Partial-molar surfaces of components -- 3. The method of measurement of the surface tension and density of metals and alloys -- 3.1. Selection of the method of measuring surface tension anddensity -- 3.2. Special features of measurement of the density of liquid metals and alloys with areometer -- 3.3. Determination of the concentration dependence of the density of metallic melts -- 3.3.1. Pycnometers for the measurement of the concentration dependence on the density of melts [150] -- 3.2.2. Areometric method of determination of the concentration dependence of density -- 3.4. Combined measurement of the physical and chemical properties of liquid metals and their alloys -- 3.4.1. A device for the combined determination of surface tension and density -- 3.4.2. A combined device for detailed examination of the physical-chemical properties of multicomponent melts -- 3.5. Combined device for the determination of the concentration dependence of the surface tension and density of multicomponent melts [154] -- 3.6. Experimental equipment for the methods of measurement of the physical-chemical properties of multicomponent metallic melts -- 3.7. Method of processing measurement results -- 3.7.1. The law of distribution of the error of measurement of surface tension -- 3.7.2. Error of determination of the composition of the melt prepared using a dosing apparatus -- 3.7.3. Error of the measurement of the density of liquid metals -- 3.7.4. Error of measuring surface tension -- 4. Surface properties and molar volumes of pure metals and binary systems -- 4.1. Temperature dependence of the parameters of the surface layer of low-melting alloys -- 4.2. Surface tension and density of indium-tin and gallium-lead binary systems. ; 4.3. Special features of the concentration dependence of the thermodynamic parameters of the surface layer of indium-tin and thallium-lead melts -- 4.4. Surface properties of binary systems: bismuth-thallium, tin-thallium and indium-thallium -- 4.5. Surface tension and molar volumes in gallium-bismuth melts -- 5. Surface tension and density of multicomponent melts -- 5.1. Surface tension and molar volumes of ternary systems -- 5.1.1. The indium-tin-lead system -- 5.1.2. The thallium-lead-bismuth system -- 5.1.3. The indium-tin-gallium system -- 5.2. Application of the methods of mathematical experimentaldesign in examination of the surface properties of multicomponent systems -- 5.3. Investigation of the surface tension and density of ternary systems using experiment design methods -- 5.3.1. Concentration dependence of the surface tension of ternary systems -- 5.4. Surface tension of four-component systems -- 5.4.1. The indium-tin-lead-bismuth system -- 5.5. Special features of the variation of the physical and chemical properties with the composition of the multicomponent melt. Concentration buffering of surface tension -- 6. Thermodynamic parameters of the surface layer of multicomponent melts and methods of predicting the parameters -- 6.1. Adsorption phenomena in multicomponent metallic melts -- 6.1.1. Effect of the surface-active component on the adsorption processes in binary melts -- 6.1.2. Adsorption behaviour of the inactive component in In-Sn-Ga, Tl-Pb-In, Tl-Pb-Sn and Tl-Bi-In ternary melts -- 6.1.3. Adsorption phenomena in indium-tin-lead-bismuth and indium-lead-gallium-bismuth four-component solutions -- 6.2. Composition and thickness of the surface layer of multicomponent melts -- 6.3. The current state of experimental examination of the surface properties and molar volumes of multicomponent metallic systems. ; 6.4. Methods of predicting the surface properties of multicomponent melts -- 6.5. Prediction of surface tension and excess molar volume on the basis of the properties of melts of lateral binary systems -- 6.6. Theoretical description of the concentration dependence of the surface tension of multicomponent solutions -- 6.7. Equation of surface tension isotherms of binary and ternary systems -- Conclusions -- Appendix -- References -- Index.
• Titolo autorizzato: Thermodynamics of surface phenomena
• ISBN: 1-907343-02-4
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9910809570303321
• Lo trovi qui: Univ. Federico II