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[null,"1.","Record Nr.",null,"UNINA9911019824903321"]
[null,null,"Titolo",null,"Iridium complexes in organic synthesis / / edited by Luis A. Oro and Carmen Claver"]
[null,null,"Pubbl/distr/stampa",null,"Weinheim, : Wiley-VCH, c2009"]
[null,null,"ISBN",null,"9786612025334"]
[{"$nulls":4},"9781282025332"]
[{"$nulls":4},"1282025333"]
[{"$nulls":4},"9783527623075"]
[{"$nulls":4},"3527623078"]
[{"$nulls":4},"9783527623082"]
[{"$nulls":4},"3527623086"]
[null,null,"Descrizione fisica",null,"1 online resource (xvii, 396 pages) : illustrations (some color)"]
[null,null,"Disciplina",null,"547.215"]
[null,null,"Soggetti",null,"Organic compounds - Synthesis"]
[{"$nulls":4},"Iridium catalysts"]
[{"$nulls":4},"Asymmetric synthesis"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Iridium Complexes in Organic Synthesis; Contents; Preface; List of Contributors; 1: Application of Iridium Catalysts in the Fine Chemicals Industry; 1.1 Introduction; 1.2 Industrial Requirements for Applying Catalysts; 1.2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of Catalysts; 1.2.3 Requirements for Practically Useful Catalysts; 1.2.3.1 Preparation Methods; 1.2.3.2 Catalysts Cost; 1.2.3.3 Availability of the Catalysts; 1.2.3.4 Catalytic Performance; 1.2.3.5 Separation"]
[{"$nulls":4},"1.3 Enantioselective Hydrogenation of C=N Bonds1.3.1 Catalysts and Scope; 1.3.2 Industrial Applications; 1.4 Enantioselective Hydrogenation of C=C Bonds; 1.4.1 Catalysts and Scope; 1.4.2 Industrial Applications; 1.5 Miscellaneous Catalytic Applications with Industrial Potential; 1.6 Conclusions and Outlook; References; 2: Dihydrido Iridium Triisopropylphosphine Complexes: From Organometallic Chemistry to Catalysis; 2.1 Introduction; 2.2 [Ir(COD)(NCMe)(PR3)]BF4 (PR3 = PiPr3, PMe3) and Related Complexes as "]
[{"$nulls":4},"Catalyst Precursors: Is 1,5-Cyclo-Octadiene an Innocent and Removable Ligand?"]
[{"$nulls":4},"2.3 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkene Hydrogenation Catalysts2.4 The Dihydrido Iridium Triisopropylphosphine Complex [IrH2(NCMe)3(PiPr3)]BF4 as Alkyne Hydrogenation Catalysts; 2.5 Dihydrido Arene Iridium Triisopropylphosphine Complexes; 2.6 Dihydrido Iridium Triisopropylphosphine Complexes as Imine Hydrogenation Catalysts; 2.7 Conclusions; Acknowledgments; References; 3: Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts; 3.1 Introduction; 3.2 Types of Ir-NHC and Reactivity"]
[{"$nulls":4},"3.2.1 Mono-NHC s and Intramolecular C-H Activation3.2.2 Chelating bis-NHC s; 3.2.3 Abnormal NHCs; 3.3 Catalysis with Ir-NHC s; 3.4 Conclusions; References; 4: Iridium-Catalyzed C=O Hydrogenation; 4.1 Introduction; 4.2 Homogeneous C=O Hydrogenations; 4.2.1 Chemoselective Hydrogenations; 4.2.2 Enantioselective Hydrogenations; 4.2.3 Transfer Hydrogenation (TH); 4.2.4 Asymmetric Transfer Hydrogenation (ATH); 4.3 Heterogeneous, Supported and Biocatalytic Hydrogenations; References; 5: Catalytic Activity of Cp* Iridium Complexes in Hydrogen Transfer Reactions; 5.1 Introduction"]
[{"$nulls":4},"5.2 Hydrogen Transfer Oxidation of Alcohols (Oppenauer-Type Oxidation)5.3 Transfer Hydrogenation of Unsaturated Compounds; 5.3.1 Transfer Hydrogenation of Quinolines; 5.3.2 Transfer Hydrogenation of Ketones and Imines; 5.4 Asymmetric Synthesis Based on Hydrogen Transfer; 5.4.1 Asymmetric Transfer Hydrogenation of Ketones; 5.4.2 Dynamic Kinetic Resolution; 5.5 Hydrogen Transfer Reactions in Aqueous Media; 5.6 Carbon-Nitrogen Bond Formation Based on Hydrogen Transfer; 5.6.1 N-Alkylation of Amines with Alcohols; 5.6.2 Cyclization of Amino Alcohols; 5.6.3 Cyclization of Primary Amines with Diols"]
[{"$nulls":4},"5.6.4 Amidation of Alcohols with Hydroxylamine"]
[null,null,null,"Sommario/riassunto","Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis.A must for organic, complex and catalytic chemists, as well as those working with/on organometallics."]