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[null,"1.","Record Nr.",null,"UNISA996309058203316"]
[null,null,"Autore",null,"Schoonjans Steven"]
[null,null,"Titolo",null,"Modalpartikeln als multimodale Konstruktionen : eine korpusbasierte Kookkurrenzanalyse von Modalpartikeln und Gestik im Deutschen / / Steven Schoonjans"]
[null,null,"Pubbl/distr/stampa",null,"Berlin, Germany : , : De Gruyter, , 2018"]
[{"$nulls":4},"©2018"]
[null,null,"ISBN",null,"3-11-056378-9"]
[{"$nulls":4},"3-11-056626-5"]
[null,null,"Descrizione fisica",null,"1 online resource (332 pages) : illustrations, tables"]
[null,null,"Collana",null,"Empirische Linguistik / Empirical Linguistics, , 2198-8676 ; ; Band 8"]
[null,null,"Disciplina",null,"401.4"]
[null,null,"Soggetti",null,"Modality (Linguistics)"]
[{"$nulls":4},"Electronic books."]
[null,null,"Lingua di pubblicazione",null,"Tedesco"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Nota di bibliografia","Includes bibliographical references."]
[null,null,"Nota di contenuto",null,"Frontmatter -- Vorwort und Danksagung -- Inhalt -- 1. Einführung -- 2. Modalpartikeln -- 3. Multimodalität -- 4. Konstruktionen -- 5. Angaben zur Korpusstudie -- 6. Anmerkungen zur Gestikanalyse -- 7. Fallstudie 1: Kopfschütteln -- 8. Fallstudie 2: Intersubjektive Zeigegesten -- 9. Weitere abtönende Gesten -- 10. Weitere abtönungsliierte Gesten -- 11. Kombinatorik und Wiederholung -- 12. Distribution der abtönenden Gesten -- 13. Die Grammatikalisierung abtönender Gesten -- 14. Abtönungsformen als multimodale Konstruktionen? -- 15. Fazit -- Literaturverzeichnis -- Anhang"]
[null,null,null,"Sommario/riassunto","Ähnlich wie Modalpartikeln (Abtönungspartikeln) können Gesten unter anderem dazu verwendet werden, bestimmte Nuancen oder Stellungnahmen zur Äußerung zu vermitteln. Ihre Interaktion mit den Modalpartikeln wurde aber bislang nicht näher untersucht. Dieses Buch legt anhand eines Korpus von Fernseh- und Parlamentsmaterialien für sieben Modalpartikeln des Deutschen (denn, doch, eben, eigentlich, einfach, halt, ja) dar, mit welchen Gesten sie kombiniert werden und welche externen Faktoren dieses Kookkurrenzverhalten beeinflussen. Zwei dieser Kombinationsmuster werden im Fallstudienteil ausführlicher besprochen: die Kombination von einfach mit einem Kopfschütteln und die Kombination von ja mit der sogenannten intersubjektiven Zeigegeste. Dabei wird auch auf die Grammatikalisierung dieser Gesten eingegangen, sowie auf die Frage, "]
[{"$nulls":4},"inwiefern diese Kookkurrenzmuster als multimodale Konstruktionen im Sinne der Konstruktionsgrammatik zu betrachten sind. Das Buch deckt also ein breites Themenfeld ab und wirft ein neues Licht auf Fragen aus der Partikelforschung, der Gestenforschung, der Grammatikalisierungsforschung und der Konstruktionsgrammatik."]
[null,"2.","Record Nr.",null,"UNINA9911019196303321"]
[null,null,"Titolo",null,"Computational modeling for homogeneous and enzymatic catalysis : a knowledge-base for designing efficient catalysts / / edited by Keiji Morokuma and Djamaladdin G. Musaev"]
[null,null,"Pubbl/distr/stampa",null,"Weinheim, : Wiley-VCH"]
[{"$nulls":4},"Chichester, : John Wiley [distributor], 2008"]
[null,null,"ISBN",null,"9786612372230"]
[{"$nulls":4},"9781282372238"]
[{"$nulls":4},"1282372238"]
[{"$nulls":4},"9783527621965"]
[{"$nulls":4},"3527621962"]
[{"$nulls":4},"9783527621972"]
[{"$nulls":4},"3527621970"]
[null,null,"Descrizione fisica",null,"1 online resource (400 p.)"]
[null,null,"Disciplina",null,"660.2995"]
[null,null,"Soggetti",null,"Catalysis - Computer simulation"]
[{"$nulls":4},"Catalysts"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Computational Modeling for Homogeneous and Enzymatic Catalysis; Contents; Preface; List of Contributors; 1 Computational Insights into the Structural Properties and Catalytic Functions of Selenoprotein Glutathione Peroxidase (GPx); 1.1 Introduction; 1.2 Catalytic Functions; 1.2.1 Peroxidase Activity; 1.2.2 Reductase Activity; 1.3 Computational Details; 1.3.1 Computational Methods; 1.3.2 Computational Models; 1.4 Results and Discussion; 1.4.1 Refinement of the Active Site; 1.4.2 Catalytic Functions: Peroxidase Activity"]
[{"$nulls":4},"1.4.3 Catalytic Functions: Effect of the Surrounding Protein on the Peroxidase Activity1.4.3.1 Hydrogen Peroxide Coordination; 1.4.3.2 Formation of Selenenic Acid [E-Se-OH]; 1.4.4 Catalytic Functions: Reductase Activity; 1.4.4.1 Peroxynitrite/Peroxynitrous Acid (ONOO ̄/ONOOH) Coordination; 1.4.4.2 Oxidation Pathway; 1.4.4.3 Nitration Pathways; 1.5 Summary; References; 2 A Comparison of Tetrapyrrole Cofactors in Nature and their Tuning by Axial Ligands; 2.1 Introduction; 2.2 Methodology; 2.3 Comparison of the Intrinsic Chemical Properties "]
[{"$nulls":4},"of the Tetrapyrroles; 2.3.1 Introduction"]
[{"$nulls":4},"2.3.2 Spin States2.3.3 Tetrapyrroles Prefer Their Native Ions; 2.3.4 Cavity Size and Flexibility of the Tetrapyrroles; 2.3.5 Cytochrome-like Electron Transfer; 2.3.6 Stability of a Metal-Carbon Bond; 2.3.7 Metallation Reaction; 2.4 Tuning of Tetrapyrrole Structure and Function by Axial Ligands; 2.4.1 Introduction; 2.4.2 Importance of the Lower Axial Ligand for B(12) Chemistry; 2.4.3 Lower Axial Ligand in Cofactor F430; 2.4.4 Importance of Axial Ligands for the Globins; 2.4.5 Role of Axial Ligands for the Cytochromes; 2.4.6 Role of the Axial Ligand in Heme Enzymes"]
[{"$nulls":4},"2.4.7 Tuning the His Ligand by Hydrogen Bonds in Heme Proteins2.4.8 Axial Ligand in Chlorophylls; 2.5 Concluding Remarks; References; 3 Modeling of Mechanisms for Metalloenzymes where Protons and Electrons Enter or Leave; 3.1 Introduction; 3.2 Energy Diagrams; 3.2.1 Photosystem II; 3.2.2 Cytochrome c Oxidase; 3.2.3 Nitric Oxide Reduction; 3.2.4 NiFe-hydrogenase; 3.2.5 Molybdenum CO Dehydrogenase; 3.3 Conclusions; References; 4 Principles of Dinitrogen Hydrogenation: Computational Insights; 4.1 Introduction"]
[{"$nulls":4},"4.2 Reaction Mechanism of the Coordinated Dinitrogen Molecule in Di-zirconocene-N(2) Complexes with a Hydrogen Molecule4.2.1 Mechanism of the Reaction (3); 4.2.2 Mechanisms of the Reactions (4) and (5); 4.3 Factors Controlling the N(2) Coordination Modes in the Di-zirconocene-N(2) Complexes; 4.4 Why the [(η(5)-C(5)Me(n)H(5-n))(2)Ti](2)(μ(2),η(2),η(2)-N(2)) Complex Cannot Add a H(2) Molecule to the Side-on Coordinated N(2), while its Zr- and Hf-analogs Can"]
[{"$nulls":4},"4.4.1 Relative Stability of the Lowest Singlet (S) and Triplet (T) Electronic States of the Complexes [(η(5)-C(5)Me(n)H(5-n))(2)M](2)(μ(2),η(2),η(2)-N(2)), II_M (for M = Ti, Zr, and Hf, and n = 0 and 4)"]
[null,null,null,"Sommario/riassunto","Here, the world's most active and productive computational scientists from academia and industry present established, effective and powerful tools for understanding catalysts. With its broad scope -- nitrogen fixation, polymerization, C-H bond activation, oxidations, biocatalysis and much more -- this book represents an extensive knowledge base for designing efficient catalysts, allowing readers to improve the performance of their own catalysts."]