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[null,"1.","Record Nr.",null,"UNINA9910555108803321"]
[null,null,"Titolo",null,"Anion-binding catalysis / / edited by Olga García Mancheño"]
[null,null,"Pubbl/distr/stampa",null,"Weinheim, Germany : , : Wiley-VCH, , [2022]"]
[{"$nulls":4},"©2022"]
[null,null,"ISBN",null,"3-527-83065-0"]
[{"$nulls":4},"3-527-83064-2"]
[{"$nulls":4},"3-527-83066-9"]
[null,null,"Descrizione fisica",null,"1 online resource (416 pages)"]
[null,null,"Disciplina",null,"572"]
[null,null,"Soggetti",null,"Bioorganic chemistry"]
[{"$nulls":4},"Electronic books."]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,"Nota di contenuto",null,"Cover -- Title Page -- Copyright -- Contents -- Preface -- List of Abbreviations -- Chapter 1 From Anion Recognition to Organocatalytic Chemical Reactions -- 1.1 Introduction and Background -- 1.1.1 Evolution of Thiourea‐Based Catalysts -- 1.1.2 Evolution of Triazole‐Based Catalysts -- 1.1.3 Progress on Halogen‐Binding‐Based Catalysts -- 1.1.4 Miscellaneous Anion‐Binding Catalysts -- 1.2 Concepts in Anion‐Binding Catalysis -- 1.2.1 Introduction -- 1.2.2 Anion‐Binding Catalysis in Addition Reactions -- 1.2.3 Anion‐Binding Catalysis in Substitution Reactions -- 1.2.4 Anion Binding in Cooperative Catalysis -- 1.2.5 Anion‐Binding in Lewis Acid Enhancement Catalysis -- 1.2.6 Anion‐Binding in Phase Transfer Catalysis -- 1.3 Summary and Outlook -- Acknowledgment -- References -- Chapter 2 Anion Recognition and Binding Constant Determination -- 2.1 Introduction to Supramolecular Chemistry and Binding Constant Determination -- 2.1.1 Chapter Overview -- 2.1.2 Supramolecular Chemistry and Its Connection to Anion‐Assisted Catalysis -- 2.1.3 Brief History of Advances in Supramolecular Anion Binding -- 2.1.4 Predicting the Model of Association and Simulating the Expected Species Distribution Profiles and Binding Curves -- 2.2 Equilibrium Constants, Binding Curves, Titration Conditions, and Errors -- 2.2.1 Physical Origins of Equilibrium Binding Constants -- 2.2.2 Explanation of the Basis for Titration Techniques and Binding Curves -- 2.2.3 Hirose's Rule and Picking the Right Concentration, Solvent, and Technique -- 2.2.4 Error "]
[{"$nulls":4},"Determination -- 2.3 Experimental Techniques: NMR Spectroscopy -- 2.3.1 When to Use -- 2.3.2 Slow Exchange vs. Fast Exchange -- 2.3.3 Determination of the Underlying Equilibria -- 2.3.4 Software for Non‐linear Regression Fitting -- 2.3.5 Common Issues -- 2.4 Experimental Techniques: UV-Vis Spectroscopy -- 2.4.1 When to Use."]
[{"$nulls":4},"2.4.2 Physical Origins of Optical Phenomena -- 2.4.3 Software for Non‐linear Regression Analysis of UV-Vis Titrations -- 2.4.4 Common Issues -- 2.5 Underappreciated Concerns in Binding Constant Determination: Multiple Binding Equilibria -- 2.5.1 When to Expect Additional Equilibria -- 2.5.2 How to Diagnose Additional Equilibria -- 2.5.3 How to Account for Additional Equilibria -- 2.6 Underappreciated Concerns in Binding Constant Determination: Ion Pairing -- 2.6.1 When to Expect Ion Pairing -- 2.6.2 Role of Solvent and Concentration in Ion Pairing -- 2.6.3 How to Diagnose Ion Pairing -- 2.7 Underappreciated Concerns in Binding Constant Determination: Kinetic Processes -- 2.8 Connecting Equilibrium Constants to Structures and Catalysis -- 2.9 Conclusion -- Acknowledgment -- References -- Chapter 3 (Thio)urea and Squaramide‐Catalyzed Anion‐Binding Catalysis with Halogen Anions -- 3.1 Introduction -- 3.2 History and Background -- 3.3 Asymmetric Catalysis by Catalyst Association with the Electrophile -- 3.3.1 Examples Utilizing the N‐Acyliminium Chloride Ion Pair -- 3.3.1.1 Pictet-Spengler Reaction and Variants -- 3.3.1.2 Intramolecular Cyclizations with Other (Hetero)aromatic Nucleophiles -- 3.3.1.3 Intramolecular and Intermolecular aza‐Sakurai Reaction -- 3.3.1.4 Mannich Reaction and Variants -- 3.3.1.5 Petasis‐Type Reactions -- 3.3.2 Examples Utilizing Electrophiles Other than N‐Acyliminium Ion Precursors -- 3.3.2.1 Utilization of Oxocarbenium and Pyrone Intermediates -- 3.3.2.2 Glycosylation Reactions Utilizing HBD-Halide Binding -- 3.3.2.3 Utilization of Non‐heteroatom‐Stabilized Carbocations as Electrophiles -- 3.4 Asymmetric Catalysis by Catalyst Association with the Nucleophile -- 3.4.1 Catalyst‐Nucleophile Association in Phase‐Transfer Catalysis -- 3.4.1.1 Investigation of Hydrogen‐Bonded Fluoride: Structure and Reactivity."]
[{"$nulls":4},"3.4.1.2 Development of Hydrogen‐Bonding Phase‐Transfer Catalysis (HBPTC) -- 3.4.1.3 Development of Acyl‐Transfer Catalysis with Hydrogen‐Bonded Fluoride -- 3.4.2 Catalyst-Nucleophile Association in Homogeneous Catalysis -- 3.5 Conclusions and Outlook -- Acknowledgments -- References -- Chapter 4 Chiral Ureas, Thioureas, and Squaramides in Anion‐Binding Catalysis with Co‐catalytic Brønsted/Lewis Acids -- 4.1 Introduction -- 4.2 Carboxylic Acid Co‐catalysts -- 4.3 Sulfonic Acid Co‐catalysts -- 4.4 Mineral Acid Co‐catalysts -- 4.5 Lewis Acid Co‐catalysts -- 4.6 Conclusions and Outlook -- References -- Chapter 5 Anion‐Binding Catalysis with Other Anions -- 5.1 Introduction -- 5.2 Cyanide Anion -- 5.2.1 Strecker Reaction -- 5.2.2 Acylcyanation of Imines -- 5.3 Oxygen‐Based Anions -- 5.3.1 Alkoxides and Enolates -- 5.3.2 Enolates of Lactones, Cyclic Anhydrides, and Imides -- 5.3.3 Carboxylates -- 5.4 Conclusions and Outlook -- References -- Chapter 6 Silanediols, Phosphoramides, and Other OH‐ and NH‐Based H‐Donor Catalysts -- 6.1 Introduction -- 6.2 Silanediols -- 6.2.1 Introduction -- 6.2.2 Overview of Silanols in Anion Binding and Catalysis -- 6.2.3 Silanediol Anion‐Binding Catalysis -- 6.2.4 Alkoxysilanediol Anion Binding Catalysis -- 6.3 Siloxanes -- 6.4 Thiophosphoramides -- 6.5 Cyclodiphosphazanes -- 6.6 Other Examples -- 6.6.1 Xanthene-Diamine Scaffold -- 6.6.2 Croconamides -- 6.6.3 Pyrrole‐Based Anion‐Binding Catalyst -- 6.6.4 Bisamidine Catalysts -- 6.7 Conclusions -- References -- Chapter 7 1,2,3‐Triazoles and 1,2,3‐Triazolium Ions as Catalysts -- 7.1 Introduction -- 7.2 Triazole‐Based Anion‐Binding Molecular Catalysts -- 7.3 Triazolium "]
[{"$nulls":4},"Ions as Organic Molecular Catalysts with Anion‐Binding Ability -- 7.4 Triazolium Ions in Dual Functional Catalysts -- 7.5 Conclusion -- References."]
[{"$nulls":4},"Chapter 8 Quaternary Ammonium, Phosphonium, and Tertiary Sulfonium Salts as Hydrogen‐Bonding Catalysts -- 8.1 Introduction -- 8.2 Hydrogen‐Bonding Ability of Quaternary Ammonium Salts -- 8.3 Hydrogen‐Bonding Catalysis of Quaternary Ammonium Salts -- 8.4 Hydrogen‐Bonding Catalysis of Quaternary Phosphonium Salts -- 8.5 Hydrogen‐Bonding Catalysis of Tertiary Sulfonium Salts -- 8.6 Conclusion -- References -- Chapter 9 Assisted and Dual Anion Binding in Amino and Nucleophilic Catalysis -- 9.1 Dual Amino/H‐Bond Donor Catalysis -- 9.1.1 Enamine Activation -- 9.1.2 Dienamine Activation -- 9.1.3 Iminium Ion Activation -- 9.1.4 Vinylogous Iminium Ion Activation -- 9.2 Thiourea - Pyridine‐Based Nucleophilic Dual Catalysis -- 9.2.1 Kinetic Resolution and Desymmetrization of Amines -- 9.2.2 Asymmetric Steglich Rearrangement -- 9.2.3 Other Acylation Reactions -- 9.2.4 Anion‐Binding‐Assisted Polymerization Reactions -- 9.3 Conclusions -- References -- Chapter 10 Anion‐Binding Catalysis by Halogen, Chalcogen, Pnictogen, and Tetrel Bonding -- 10.1 History of Halogen Bonding -- 10.2 History of Chalcogen Bonding -- 10.3 History of Pnictogen and Tetrel Bonding -- 10.4 Differences Between Hydrogen Bonding and Other Secondary Interactions -- 10.5 Secondary Bonding in Anion Recognition -- 10.6 Halogen Bonding in Anion‐Binding Catalysis -- 10.7 Chalcogen Bonding in Anion‐Binding Catalysis -- 10.8 Pnictogen and Tetrel Bonding in Anion‐Binding Catalysis -- 10.9 Conclusion -- References -- Chapter 11 New Trends and Supramolecular Approaches in Anion‐Binding Catalysis -- 11.1 General Introduction -- 11.2 Dual Photoredox and Anion‐Binding Catalysis -- 11.3 Combination of Metal and Anion‐Binding Catalysis -- 11.3.1 Anion‐Binding Assisted Hydrogenation Reactions -- 11.3.2 Hydroformylation Reactions -- 11.3.3 Anion‐Binding - Metal‐Catalyzed C-C Forming Reactions."]
[{"$nulls":4},"11.4 Supramolecular Approaches Involving Anion‐Binding Catalysis -- 11.4.1 Mechanically Interlocked Molecules in Anion‐Binding Catalysis -- 11.4.1.1 Molecular Knots as Anion‐Binding Catalysts -- 11.4.1.2 Rotaxanes as Anion‐Binding Catalysts -- 11.4.2 Molecular Motors in Anion‐Binding Catalysis -- 11.4.3 Macrocycles in Anion‐Binding Catalysis -- 11.5 Anion-π Catalysis -- 11.5.1 Anion-π‐Catalyzed Kemp Elimination Reaction -- 11.5.2 Anion-π Interactions in Enolate Chemistry -- 11.5.3 Epoxide‐Opening - Ether Cyclization Reactions -- 11.5.4 Enantioselective Anion-π Catalysis -- 11.5.5 Miscellaneous -- 11.6 Conclusion and Outlook -- References -- Index -- EULA."]
[null,"2.","Record Nr.",null,"UNINA9911002189903321"]
[null,null,"Autore",null,"Onida, Valerio"]
[null,null,"Titolo",null,"Il giudizio di costituzionalità delle leggi in via incidentale : materiali / Valerio Onida, Marilisa D'Amico"]
[null,null,"Pubbl/distr/stampa",null,"Torino, : Giappichelli, ©2025"]
[null,null,"ISBN",null,"9791221106527"]
[null,null,"Edizione",null,"[2. ed]"]
[null,null,"Descrizione fisica",null,"XVIII, 477 p. ; 24 cm"]
[null,null,"Disciplina",null,"342.45020269"]
[null,null,"Locazione",null,"FGBC"]
[null,null,"Collocazione",null,"I H 133"]
[null,null,"Lingua di pubblicazione",null,"Italiano"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]