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[null,"1.","Record Nr.",null,"UNINA9910830228103321"]
[null,null,"Autore",null,"Soustelle Michel"]
[null,null,"Titolo",null,"Thermodynamic modeling of solid phases / / Michel Soustelle"]
[null,null,"Pubbl/distr/stampa",null,"London, England ; ; Hoboken, New Jersey : , : iSTE : , : Wiley, , 2015"]
[{"$nulls":4},"©2015"]
[null,null,"ISBN",null,"1-119-17853-3"]
[{"$nulls":4},"1-119-17851-7"]
[{"$nulls":4},"1-119-17852-5"]
[null,null,"Descrizione fisica",null,"1 online resource (266 p.)"]
[null,null,"Collana",null,"Chemical Engineering Series. Chemical Thermodynamics set ; ; Volume 3"]
[null,null,"Disciplina",null,"536.7"]
[null,null,"Soggetti",null,"Phase rule and equilibrium - Mathematical models"]
[{"$nulls":4},"Solids - Thermal properties"]
[{"$nulls":4},"Thermodynamics - Mathematical models"]
[{"$nulls":4},"Chemical reactions"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Cover; Title Page; Copyright; Contents; Preface; Notations and Symbols; 1: Pure Crystalline Solids; 1.1. Characteristic values of a solid; 1.2. Effect of stress and Young's modulus; 1.3. Microscopic description of crystalline solids; 1.4. Partition function of vibration of a solid; 1.4.1. Einstein's single-frequency model; 1.4.2. Debye's frequency distribution model; 1.4.3. Models with more complex frequency distributions; 1.5. Description of atomic solids; 1.5.1. Canonical partition function of an atomic solid; 1.5.2. Helmholtz energy and internal energy of an atomic solid"]
[{"$nulls":4},"1.6. Description of molecular solids1.6.1. Partition function of molecular crystals; 1.6.2. Thermodynamic functions of molecular solids; 1.7. Description of an ionic solid; 1.7.1. Crosslink energy of an ionic solid; 1.7.1.1. Attraction energy; 1.7.1.2. Repulsion energy; 1.7.1.3. Crosslink energy; 1.7.2. Born/Haber cycle; 1.7.3. Vibrational partition function and internal energy of an ionic solid; 1.8. Description of a metallic solid; 1.8.1. Sommerfeld's electron perfect gas model; 1.8.1.1. Determination of the coefficient α; 1.8.1.2. Kinetic energy of electrons in the metal"]
[{"$nulls":4},"1.8.1.3. Electrochemical potential of the electrons in the metal and the Fermi energy1.8.1.4. Energy distribution of the free electrons; 1.8.1.5. "]
[{"$nulls":4},"Contribution of the free electrons to the internal energy of a metal; 1.8.2. The metallic bond and band theory; 1.8.2.1. Origin of energy bands; 1.8.2.2. Conductors, insulators and semiconductors; 1.8.2.3. Determination of the number N of free electrons; 1.8.2.4. Distribution of energy states and of free electrons at absolute zero; 1.9. Molar specific heat capacities of crystalline solids"]
[{"$nulls":4},"1.9.1. Contribution of the vibrational energy to the specific heat capacity at constant volume1.9.1.1. Case of a unique vibration in Einstein's model; 1.9.1.2. Case of Debye's acoustic vibration distribution; 1.9.2. Specific heat capacity of an atomic solid at constant volume; 1.9.2.1. Case of conductors; 1.9.2.2. Case of insulating materials; 1.9.3. Specific heat capacity of a molecular or ionic solid at constant volume; 1.9.4. Conclusion as to the specific heat capacity of a crystalline solid; 1.10. Thermal expansion of solids; 1.10.1. Expansion coefficients"]
[{"$nulls":4},"1.10.1.1. Linear expansion coefficient1.10.1.2. Thermal expansion tensor; 1.10.1.3. Cubic expansion coefficient (or coefficient of relative volume increase); 1.10.1.4. Relation between the thermomechanical coefficients; 1.10.2. Origin of thermal expansion in solids; 1.10.3. Quantum treatment of thermal expansion. Grüneisen parameter; 1.10.4. Expansion coefficient of metals; 2: Solid Solutions; 2.1. Families of solid solutions; 2.1.1. Substitutional solid solutions; 2.1.2. Insertion solid solution; 2.1.2.1. Octahedral sites of the cubic centered faces lattice"]
[{"$nulls":4},"2.1.2.2. Tetrahedral sites of the cubic centered faces lattice"]
[null,null,null,"Sommario/riassunto","The book offers advanced students, in 7 volumes, successively characterization tools phases, the study of all types of phase, liquid, gas and solid, pure or multi-component, process engineering, chemical and electrochemical equilibria, the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention was given to the rigor of mathematical developments.   Besides some very specialized books, the vast majority of existing works are intended for beginners and therefore limited in s"]