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[null,"1.","Record Nr.",null,"UNINA9910830037203321"]
[null,null,"Autore",null,"Shi Feng"]
[null,null,"Titolo",null,"Carbonyl compounds : reactants, catalysts and products / / Feng Shi, Hongli Wang, Xingchao Dai"]
[null,null,"Pubbl/distr/stampa",null,"Weinheim, Germany : , : Wiley-VCH, , [2022]"]
[{"$nulls":4},"©2022"]
[null,null,"ISBN",null,"3-527-82561-4"]
[{"$nulls":4},"3-527-82562-2"]
[{"$nulls":4},"3-527-82560-6"]
[null,null,"Descrizione fisica",null,"1 online resource (375 pages)"]
[null,null,"Disciplina",null,"547.036"]
[null,null,"Soggetti",null,"Carbonyl compounds"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,"Nota di contenuto",null,"Cover -- Title Page -- Copyright -- Contents -- Preface -- Part I Carbonyl Molecules as Reactants -- Chapter 1 Carbon Monoxide -- 1.1 Hydroformylation of Alkenes and Alkynes -- 1.1.1 Co Catalysts -- 1.1.2 Rh Catalysts -- 1.1.3 Au Catalysts -- 1.1.4 Ligand‐Modified Heterogeneous Catalysts -- 1.1.5 Single‐Atom Catalysts -- 1.2 Hydroxy-, Alkoxy-, and Aminocarbonylation of Alkenes and Alkynes -- 1.2.1 Hydroxycarbonylation of Alkenes -- 1.2.2 Hydroxycarbonylation of Alkynes -- 1.2.3 Alkoxycarbonylation of Alkenes -- 1.2.4 Alkoxycarbonylation of Alkynes -- 1.2.5 Aminocarbonylation of Alkenes -- 1.2.6 Aminocarbonylation of Alkynes -- 1.3 The Pauson-Khand Reaction -- 1.3.1 The Catalytic Pauson-Khand Reaction -- 1.3.2 Stereoselective Pauson-Khand Reactions -- 1.3.3 Pauson-Khand Transfer Carbonylation Reactions -- 1.4 Synthesis of Acetic Acid -- 1.4.1 Process Considerations -- 1.4.2 Rhodium‐Catalyzed Carbonylation -- 1.4.3 Iridium‐Catalyzed Carbonylation -- 1.5 Carbonylation of C X Bonds -- 1.5.1 Hydroxy‐, Alkoxy‐, and Aminocarbonylations of C X Bonds -- 1.5.2 Reductive Carbonylations -- 1.5.3 Carbonylative Coupling Reactions with Organometallic Reagents -- 1.5.4 Carbonylative Sonogashira Reactions -- 1.5.5 Carbonylative C-H Activation Reactions -- 1.5.6 Carbonylative Heck Reactions -- 1.6 Carbonylation of Epoxides -- 1.6.1 Ring‐expansion Carbonylation of Epoxides -- 1.6.2 Hydroformylation and Silylformylation of Epoxides -- 1.6.3 Alternating Copolymerization of "]
[{"$nulls":4},"Epoxides -- 1.6.4 Alkoxycarbonylation and Aminocarbonylation of Epoxides -- 1.7 Carbonylation of Aldehydes -- 1.7.1 Amidocarbonylations of Aldehydes -- 1.7.2 Hydroformylation and Silylformylation of Aldehydes -- 1.7.3 Hetero Pauson-Khand Reactions of Aldehydes -- 1.7.4 Reactions of Aldehydes with Acylanions -- 1.7.5 Miscellaneous of Aldehydes -- 1.8 Oxidative Carbonylation Reaction."]
[{"$nulls":4},"1.8.1 Oxidative Carbonylation of Alkenes -- 1.8.2 Oxidative Carbonylation of Alkynes -- 1.8.3 Oxidative Carbonylation of Organometallic Reagents -- 1.8.4 Oxidative Carbonylation of Arenes -- 1.8.5 Oxidative Carbonylation of Amines -- 1.9 Other Reactions -- 1.9.1 Reactions of Diazoalkanes with Carbon Monoxide -- 1.9.2 Reaction of C-NO2 with CO -- Chapter 2 Carbon Dioxide -- 2.1 Synthesis of Urea Derivatives -- 2.1.1 Metal‐free Catalyst Systems -- 2.1.2 Ph3SbO as Catalyst -- 2.1.3 Pd Catalyst Systems -- 2.1.4 Ionic Liquids as Catalyst -- 2.1.5 CeO2 as Catalyst -- 2.2 Synthesis of Carbamate Derivatives -- 2.2.1 Ru Catalyst Systems -- 2.2.2 Sn or Ni Catalyst Systems -- 2.2.3 Zeolite as Catalyst -- 2.2.4 Other Catalyst Systems -- 2.3 Synthesis of Carboxyl Acid Derivatives -- 2.4 Cycloaddition of Epoxide with CO2 -- 2.4.1 Oxides Catalysts -- 2.4.2 Zeolite Catalysts -- 2.4.3 Supported Nanoparticle and Lewis Acid Catalysts -- 2.4.4 Carbon Catalysts -- 2.4.5 Salen, Porphyrins, and Phthalocyanines Catalysts -- 2.4.6 Ionic Liquid Catalysts -- 2.4.7 Metal-Organic Framework (MOF) Catalysts -- 2.4.8 Bifunctional Catalysts -- 2.4.9 Other Catalysts -- 2.5 Reaction of Polyalcohols/Olefins with CO2 -- 2.6 Formylation of Amines with CO2 -- 2.7 Reactions of Propargyl Alcohols/Propargyl Amines with CO2 -- 2.8 Other Reactions -- 2.8.1 Reactions of Aromatic Halides with CO2 -- 2.8.2 Reactions of 2‐Aminobenzonitriles with CO2 -- Chapter 3 Other C1 Carbonyl Molecules -- 3.1 Formaldehyde (HCHO) -- 3.1.1 Carbonylation of Halides with HCHO -- 3.1.2 Carbonylation of Olefins with HCHO -- 3.1.3 Carbonylation of Alkynes with HCHO -- 3.2 Formic Acid (HCOOH) -- 3.2.1 Hydroxycarbonylation of Arenes with Formic Acid -- 3.2.2 Carbonylation of Alkenes with Formic Acid -- 3.2.3 Carbonylation of Alkynes with Formic Acid -- 3.2.4 N‐Formylation Reactions with Formic Acid."]
[{"$nulls":4},"3.2.4.1 Metal Oxides Catalysts -- 3.2.4.2 Brønsted Acidic as Catalyst -- 3.2.4.3 Amberlite IR‐120 Resins as Catalysts -- 3.2.4.4 Magnetic Catalysts -- 3.2.4.5 Zeolite as Catalyst -- 3.2.4.6 Ionic Liquids (ILs) as Catalyst -- 3.2.4.7 Other Catalysts -- 3.2.5 Carbonylation of C-X with Formic Acid -- 3.2.6 Other Reactions -- Chapter 4 CO Surrogates -- 4.1 Carbonyl Metal -- 4.2 Formates -- 4.3 Formamides -- 4.4 Formic Anhydride -- 4.5 Silacarboxylic Acid -- 4.6 N‐Formylsaccharin -- 4.7 Acyl Chloride -- 4.8 In Situ Generated Carbonyl Source -- 4.8.1 Methanol -- 4.8.2 Glycerol -- 4.8.3 Aldoses -- 4.8.4 Epoxide -- 4.8.5 Chloroform -- 4.8.5.1 Pd‐catalyzed Carbonylation Reactions -- 4.8.5.2 Fe‐Catalyzed Carbonylation Reactions -- 4.8.5.3 Zn‐Catalyzed Carbonylation Reactions -- Part I References -- Part II Carbonyl Compounds as Catalysts -- Chapter 5 Acid‐Catalyzed Reactions with -CO2H -- 5.1 Carboxylic Acid Molecules Catalyzed Reactions -- 5.1.1 Hydrolysis/Aminolysis/Ethanolysis Reactions -- 5.1.2 Mutarotation of 2,3,4,6‐Tetramethyl‐d‐glucose (TM‐G) -- 5.1.3 Depolymerization of Polyoxymethylenes -- 5.1.4 Elimination Reactions -- 5.1.5 Hydrogen-Deuterium Exchange Reactions -- 5.1.6 Reduction Reactions -- 5.1.7 Decomposition of Diazodiphenylmethane -- 5.1.8 Amino-Imino Tautomerism Reactions -- 5.1.9 Aldol Reaction -- 5.1.10 Friedel-Crafts Reaction -- 5.1.11 Hydrogen Shifts Reaction -- 5.1.12 Cyclization Reaction -- 5.1.13 Hydroboration Reaction -- 5.1.14 Trifluoromethylation Reaction -- 5.2 Carbon Material-Catalyzed "]
[{"$nulls":4},"Reactions -- 5.2.1 Reduction of Nitric Oxide -- 5.2.2 Oxidative Coupling of Amines to Imines -- 5.2.3 Depolymerization of Cellulose and Lignocellulose -- 5.2.4 Nitrobenzene Reduction Reaction and Beckmann Rearrangement Reaction -- 5.2.5 Ring‐Opening Reaction of Styrene Oxide -- Chapter 6 Reactions via Carbonyl and Hydroxyl Groups Recycling."]
[{"$nulls":4},"6.1 Carbon‐Catalyzed Selective Oxidation Reactions -- 6.1.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.1.2 Oxidative Dehydrogenation of n‐Butane -- 6.1.3 Oxidative Dehydrogenation of Isobutane -- 6.1.4 Oxidative Dehydrogenation of Propane -- 6.2 Polymer‐Catalyzed Selective Oxidation Reactions -- 6.2.1 Oxidative Dehydrogenation of Ethylbenzene -- 6.2.2 Oxidative Dehydrogenation of Heterocyclic Compounds -- 6.3 Aldehyde/Ketone‐Catalyzed Borrowing‐Hydrogen Reactions -- 6.3.1 Dehydrative β‐C‐Alkylation Reaction of Methyl Carbinols with Alcohols -- 6.3.2 Dehydrative α‐Alkylation Reactions of Ketones with Alcohols -- 6.3.3 Dehydrative Alkylation Reactions of Fluorenes with Alcohols -- 6.3.4 Dehydrative N‐Alkylation Reactions of Amines with Alcohols -- 6.4 Carbon‐Catalyzed Borrowing‐Hydrogen Reactions -- Part II References -- Part III The Synthetic Applications of Carbonyl Compounds -- Chapter 7 Synthesis of Functional Molecules -- 7.1 Reduction of Carbonyl Compounds -- 7.1.1 Aldehydes and Ketones to Alcohol -- 7.1.2 Acids to the Alcohols and Aldehydes -- 7.1.2.1 To Alcohols -- 7.1.2.2 To Aldehydes -- 7.1.3 Ester to Alcohols and Ethers -- 7.1.3.1 To Alcohols -- 7.1.3.2 To Ethers -- 7.1.4 Amides to Amines -- 7.1.5 Clemmensen Reduction -- 7.1.6 Wolff-Kishner Reduction -- 7.2 Nucleophilic Addition Reactions of Aldehydes and Ketones -- 7.2.1 Carbon Nucleophiles -- 7.2.1.1 Grignard Reagent and Other Organometallic Reagents -- 7.2.1.2 Reformatsky Reaction -- 7.2.1.3 Benzoin Condensation -- 7.2.1.4 CN Group -- 7.2.1.5 Aromatic and Aliphatic C H Bond -- 7.2.2 Nitrogen Nucleophiles -- 7.2.3 Oxygen Nucleophiles -- 7.2.3.1 H2O as a Nucleophile -- 7.2.3.2 ROH as a Nucleophile -- 7.3 Addition Elimination Reactions of Aldehydes and Ketones -- 7.3.1 Aldol Reaction -- 7.3.2 Perkin Reaction -- 7.3.3 Knoevenagel Condensation -- 7.4 Oxidation of Aldehydes and Ketones."]
[{"$nulls":4},"7.4.1 Baeyer-Villiger Oxidation -- 7.4.2 To Acid -- 7.5 Wittig Reaction -- 7.6 Reductive Amination Reaction -- 7.6.1 Homogeneous Catalyst System -- 7.6.2 Heterogeneous Catalyst System -- 7.7 Hydroboration/Hydrophosphonylation/Hydrosilylation/Hydroacylation of Aldehydes and Ketones -- 7.7.1 Hydroboration -- 7.7.2 Hydrophosphonylation -- 7.7.3 Hydrosilylation Reactions -- 7.7.4 Hydroacylation Reactions -- 7.8 Oxidative Cross‐Coupling Reaction of Aldehydes -- 7.8.1 Homogeneous Catalyst System -- 7.8.2 Heterogeneous Catalyst System -- 7.9 Reductive Coupling Reactions of Aldehydes -- 7.10 Reaction of Acids as Starting Materials -- 7.10.1 Esterification Reactions -- 7.10.2 Amidation Reactions -- 7.10.3 Decarboxylation Coupling Reactions -- 7.11 Reaction of Esters as Starting Materials -- 7.11.1 Hydrolysis Reaction -- 7.11.2 Transesterification Reaction -- 7.11.3 Aminolysis Reaction -- 7.12 Reaction of Amides as Starting Materials -- 7.12.1 Hydrolysis Reaction -- 7.12.2 Alcoholysis Reaction -- Chapter 8 Synthesis of Functional Materials -- 8.1 Polyamides -- 8.1.1 Aliphatic Polyamides -- 8.1.2 Aromatic Polyamides -- 8.1.3 Long‐Chain Semiaromatic Polyamides -- 8.2 Phenol Formaldehyde Resins -- 8.2.1 Novolac Resins -- 8.2.2 Resole Resins -- 8.3 Polyurethanes -- 8.4 Polyesters -- Part III References -- Chapter 9 Conclusion and Perspectives -- 9.1 Conclusion -- 9.2 Perspectives -- Index -- EULA."]