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[null,"1.","Record Nr.",null,"UNINA9910816076303321"]
[null,null,"Autore",null,"Soustelle Michel"]
[null,null,"Titolo",null,"Modeling of liquid phases . Volume 2 / / Michel Soustelle"]
[null,null,"Pubbl/distr/stampa",null,"London, England ; ; Hoboken, New Jersey : , : ISTE : , : Wiley, , 2015"]
[{"$nulls":4},"©2015"]
[null,null,"ISBN",null,"1-119-17850-9"]
[{"$nulls":4},"1-119-17849-5"]
[{"$nulls":4},"1-119-17848-7"]
[null,null,"Descrizione fisica",null,"1 online resource (261 p.)"]
[null,null,"Collana",null,"Chemical Engineering Series"]
[null,null,"Disciplina",null,"541.36"]
[null,null,"Soggetti",null,"Thermochemistry"]
[{"$nulls":4},"Solution (Chemistry)"]
[{"$nulls":4},"Kinetic theory of liquids"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Cover; Title Page; Copyright ; Contents; Preface; Notations and Symbols; 1: Pure Liquids; 1.1. Macroscopic modeling of liquids; 1.2. Distribution of molecules in a liquid; 1.2.1. Molecular structure of a non-associated liquid; 1.2.2. The radial distribution function; 1.2.3 The curve representative of the radial distribution function; 1.2.4. Calculation of the macroscopic thermodynamic values; 1.3. Models extrapolated from gases or solids; 1.3.1. Guggenheim's smoothed potential model; 1.3.2. Mie's harmonic oscillator model"]
[{"$nulls":4},"1.3.3. Determination of the free volume on the basis of the dilation and the compressibility1.4. Lennard-Jones and Devonshire cellular model; 1.5. Cellular and vacancies model; 1.6. Eyring's semi-microscopic formulation of the vacancy model; 1.7. Comparison between the different microscopic models and experimental results; 2: Macroscopic Modeling of Liquid Molecular Solutions; 2.1. Macroscopic modeling of the Margules expansion; 2.2. General representation of a solution with several components; 2.3. Macroscopic modeling of the Wagner expansions"]
[{"$nulls":4},"2.3.1. Definition of the Wagner interaction coefficients2.3.2. Example of a ternary solution: experimental determination of Wagner's interaction coefficients; 2.4. Dilute ideal solutions; 2.4.1. Thermodynamic definition of a dilute ideal solution; 2.4.2. Activity coefficients of a component with a pure-substance reference; 2.4.3. "]
[{"$nulls":4},"Excess Gibbs energy of an ideal dilute solution; 2.4.4. Enthalpy of mixing for an ideal dilute solution; 2.4.5. Excess entropy of a dilute ideal solution; 2.4.6. Molar heat capacity of an ideal dilute solution at constant pressure; 2.5. Associated solutions"]
[{"$nulls":4},"2.5.1. Example of the study of an associated solution2.5.2. Relations between the chemical potentials of the associated solution; 2.5.3. Calculating the extent of the equilibrium in an associated solution; 2.5.4. Calculating the activity coefficients in an associated solution; 2.5.5. Definition of a regular solution; 2.5.6. Strictly-regular solutions; 2.5.7. Macroscopic modeling of strictly-regular binary solutions; 2.5.8. Extension of the model of a strictly-regular solution to solutions with more than two components; 2.6. Athermic solutions"]
[{"$nulls":4},"2.6.1. Thermodynamic definition of an athermic solution2.6.2. Variation of the activity coefficients with temperature in an athermic solution; 2.6.3. Molar entropy and Gibbs energy of mixing for an athermic solution; 2.6.4. Molar heat capacity of an athermic solution; 3: Microscopic Modeling of Liquid Molecular Solutions; 3.1. Models of binary solutions with molecules of similar dimensions; 3.1.1. The microscopic model of a perfect solution; 3.1.2. Microscopic description of strictly-regular solutions; 3.1.3. Microscopic modeling of an ideal dilute solution"]
[{"$nulls":4},"3.2. The concept of local composition"]
[null,null,null,"Sommario/riassunto","This book is part of a set of books which offers advanced students successive characterization tool phases, the study of all types of phase (liquid, gas and solid, pure or multi-component), process engineering, chemical and electrochemical equilibria, and the properties of surfaces and phases of small sizes. Macroscopic and microscopic models are in turn covered with a constant correlation between the two scales. Particular attention has been given to the rigor of mathematical developments.   This second volume in the set is devoted to the study of liquid phases."]