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[null,"1.","Record Nr.",null,"UNINA9910155302703321"]
[null,null,"Autore",null,"Sahoo Basudev"]
[null,null,"Titolo",null,"Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks / / by Basudev Sahoo"]
[null,null,"Pubbl/distr/stampa",null,"Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017"]
[null,null,"ISBN",null,"9783319483504"]
[null,null,"Edizione",null,"[1st ed. 2017.]"]
[null,null,"Descrizione fisica",null,"1 online resource (XXIII, 258 p. 113 illus., 37 illus. in color.)"]
[null,null,"Collana",null,"Springer Theses, Recognizing Outstanding Ph.D. Research, , 2190-5053"]
[null,null,"Disciplina",null,"541.395"]
[null,null,"Soggetti",null,"Chemistry, Organic"]
[{"$nulls":4},"Catalysis"]
[{"$nulls":4},"Chemical engineering"]
[{"$nulls":4},"Organic Chemistry"]
[{"$nulls":4},"Industrial Chemistry/Chemical Engineering"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Nota di bibliografia","Includes bibliographical references at the end of each chapters."]
[null,null,"Nota di contenuto",null,"Abstract -- Introduction to Photocatalysis -- Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-Activated Alkenes -- Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement -- Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines -- Synthesis and Characterizations of Novel Metal-Organic Frameworks (MOFs) -- Experimental Section."]
[null,null,null,"Sommario/riassunto","This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated "]
[{"$nulls":4},"compounds, is presented, since compounds featuring fluorinated functionality are the subject of increasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures."]