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[null,"1.","Record Nr.",null,"UNINA9910146268103321"]
[null,null,"Titolo",null,"Supramolecular catalysis / / edited by Piet W. N. M. van Leeuwen"]
[null,null,"Pubbl/distr/stampa",null,"Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008"]
[{"$nulls":4},"©2008"]
[null,null,"ISBN",null,"1-282-78442-0"]
[{"$nulls":4},"9786612784422"]
[{"$nulls":4},"3-527-62178-4"]
[{"$nulls":4},"3-527-62179-2"]
[null,null,"Descrizione fisica",null,"1 online resource (321 p.)"]
[null,null,"Disciplina",null,"541.395"]
[null,null,"Soggetti",null,"Catalysis"]
[{"$nulls":4},"Supramolecular chemistry"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references at the end of each chapters and index."]
[null,null,"Nota di contenuto",null,"Supramolecular Catalysis; Contents; List of Authors; 1 Introduction to Supramolecular Catalysis; 1.1 Introduction; 1.2 Design Approaches to Supramolecular Catalysis; 1.2.1 Molecular Receptors that Place a Binding Site Close to a Catalytic Center; 1.2.2 Molecular Receptors that Promote the Reaction of two Simultaneously Complexed Reactants; 1.2.3 Preparation of the Catalyst Backbone via Supramolecular Interactions; 1.3 Artificial Biomacromolecules for Asymmetric Catalysis; 1.4 Summary and Outlook; References"]
[{"$nulls":4},"2 Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis2.1 Introduction; 2.2 Emulation of Chelation through Self-Assembly of Monodentate Ligands; 2.3 Tautomeric Self-Complementary Interligand Hydrogen Bonding; 2.3.1 Hydroformylation; 2.3.2 Room Temperature/Ambient Pressure Hydroformylation; 2.3.3 Asymmetric Hydrogenation; 2.4 A-T Base Pair Analogous Complementary Hydrogen Bonding for the Construction of Heterodimeric Self-Assembling Ligands; 2.4.1 Aminopyridine/Isoquinolone Platform"]
[{"$nulls":4},"3.3.2 X-Ray and other Techniques for Structural Characterization in the Solid State3.3.3 Structural Characterization in Solution by NMR; 3.3.4 Anion Exchange in the Solid State; 3.4 Preparation of Coordination "]
[{"$nulls":4},"Polymers with 2,3-Pyrazolylquinoxalines or 2,3-Pyrazolylpyrazines and Cu(I) or Ag(I); 3.4.1 Preparation and Characterization of Dinuclear Building Blocks and Coordination Polymers; 3.4.2 X-Ray and other Techniques for Structural Characterization; 3.5 Preparation of Supramolecular Structures with 2,4-Diamino-6-R-1,3,5-triazines and Ag(I); 3.5.1 Synthesis"]
[{"$nulls":4},"3.5.2 X-Ray Structure Determination3.5.3 Structural Characterization in Solution by NMR; 3.6 Conclusions; References; 4 Chiral Metallocycles for Asymmetric Catalysis; 4.1 Introduction; 4.2 Thermodynamically-Controlled Metallocycles; 4.3 Kinetically-Controlled Metallocycles; 4.4 General Synthetic Strategies for Chiral Metallocycles; 4.5 Self- and Directed-Assembly of Chiral Pt-Alkynyl Metallocycles; 4.6 Chiral Pt-Alkynyl Metallocycles for Asymmetric Catalysis; 4.7 Concluding Remarks; References; 5 Catalysis of Acyl Transfer Processes by Crown-Ether Supported Alkaline-Earth Metal Ions"]
[{"$nulls":4},"5.1 Introduction"]
[null,null,null,"Sommario/riassunto","In the past few years, supramolecular chemistry has led to new approaches in homogeneous catalysis. While host-guest chemistry had already found applications in catalysis as a result of the pioneering work carried out by Professor Ronald Breslow and Nobel prizewinner Professor Jean-Marie Lehn that began some 40 years ago, the construction of catalysts by supramolecular forces has only recently become a powerful tool. This development paves the way for large numbers of new potential catalysts that can be varied in an expedient way by changing the constituting building blocks.Written by some"]