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[null,"1.","Record Nr.",null,"UNINA9910144722603321"]
[null,null,"Titolo",null,"Regio- and stereo-controlled oxidations and reductions [[electronic resource] /] / edited by Stanley M. Roberts, John Whittall"]
[null,null,"Pubbl/distr/stampa",null,"Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007"]
[null,null,"ISBN",null,"1-281-03233-6"]
[{"$nulls":4},"9786611032333"]
[{"$nulls":4},"0-470-09024-3"]
[{"$nulls":4},"0-470-09023-5"]
[null,null,"Descrizione fisica",null,"1 online resource (336 p.)"]
[null,null,"Collana",null,"Catalysts for fine chemical synthesis ; ; v. 5"]
[null,null,"Disciplina",null,"547.215"]
[{"$nulls":4},"547/.23"]
[null,null,"Soggetti",null,"Oxidation"]
[{"$nulls":4},"Reduction (Chemistry)"]
[{"$nulls":4},"Organic compounds - Synthesis"]
[{"$nulls":4},"Catalysts"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 5; Abbreviations; 1 Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets; 1.1 Introduction; 1.2 Reduction of Carbon-Carbon Double Bonds; 1.2.1 Privileged structures: a-amino acids and itaconic acids; 1.2.2 b-Amino acids; 1.2.3 a-Alkyl substituted acids; 1.2.4 a-Alkoxy substituted acids; 1.2.5 Unsaturated nitriles; 1.2.6 Alkenes and allyl alcohols; 1.2.7 a,b-Unsaturated aldehyde reduction.; 1.3 Ketone and Imine Reduction"]
[{"$nulls":4},"1.3.1 Catalytic hydrogenation of ketones and imines1.3.2 Asymmetric transfer hydrogenation (ATH) catalysts; 1.3.3 Modified borane reagents; 1.3.4 Biocatalysts (alcohol dehydrogenases and ketoreductases); 1.4 Oxidation; 1.4.1 Sharpless chiral epoxidation of allyl alcohols; 1.4.2 Dioxirane catalyzed epoxidation; 1.4.3 Amines and iminium salts; 1.4.4 Phase transfer catalysts; 1.4.5 The Julia ́-Colonna method (polyleucine oxidation); 1.4.6 Organocatalytic alfa-hydroxylation of ketones; 1.4.7 Baeyer-Villiger oxidation.; 1.4.8 Chiral sulfoxides.; References"]
[{"$nulls":4},"2 Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids2.1 (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}"]
[{"$nulls":4},"-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation; 2.1.1 Synthesis of (S)-5,50,6,60,7,70,8,80-Octahydro-1,10-bi-2-naphthol; 2.1.2 Synthesis of (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl.; 2.1.3 Asymmetric hydrogenation of Dimethyl itaconate; Conclusion; References"]
[{"$nulls":4},"2.2 Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes2.2.1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol; 2.2.2 Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite; 2.2.3 Synthesis of (4S,5S)-[(Z4-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.2.4 Asymmetric hydrogenation of trans-a-Methylstilbene"]
[{"$nulls":4},"Conclusion.References; 2.3 Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes; 2.3.3 Synthesis of (4S)-[(Z4-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.3.4 Asymmetric hydrogenation of trans-a-Methylstilbene; Conclusion; 2.3.1 Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole; 2.3.2 Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphinothiophene-2-yl)-4,5-dihydrooxazole; References"]
[{"$nulls":4},"2.4 (R)-2,20,6,60-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,30-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodiumcatalyzed asymmetric hydrogenation of a-dehydroamino acids."]
[null,null,null,"Sommario/riassunto","Volume 5 in the Catalysts for Fine Chemical Synthesis series describes new procedures for the regio- and stereo-controlled transformations of compounds involving oxidation or reduction reactions. It describes a wide range of catalysts, including organometallic systems, biocatalysts and biomimetics. This volume also includes descriptions of a variety of conversions, including: Baeyer-Villiger oxidations; Epoxidation reactions; Hydroxylation reactions; Oxidation of alcohols to aldehydes, ketones and carboxylic acids; Reduction of ketones; and Reduction of alkenes including a, ß-unsaturate"]