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[null,"1.","Record Nr.",null,"UNINA9910139364503321"]
[null,null,"Autore",null,"Laurence Christian"]
[null,null,"Titolo",null,"Lewis basicity and affinity scales [[electronic resource] ] : data and measurement / / Christian Laurence, Jean-Franc ʹois Gal"]
[null,null,"Pubbl/distr/stampa",null,"Chichester, : Wiley, 2010"]
[null,null,"ISBN",null,"1-282-68724-7"]
[{"$nulls":4},"9786612687242"]
[{"$nulls":4},"0-470-68190-X"]
[{"$nulls":4},"0-470-68189-6"]
[null,null,"Descrizione fisica",null,"1 online resource (490 p.)"]
[null,null,"Disciplina",null,"541.39"]
[{"$nulls":4},"541.395"]
[{"$nulls":4},"546.24"]
[null,null,"Soggetti",null,"Lewis acids"]
[{"$nulls":4},"Chemistry"]
[{"$nulls":4},"Electronic books."]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,"Nota di contenuto",null,"Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̈onsted Definition of Acids and Bases; 1.2 Scales of Br ̈onsted Basicity and Affinity in Solution; 1.3 Scales of Br ̈onsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory"]
[{"$nulls":4},"1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; 1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach"]
[{"$nulls":4},"1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 "]
[{"$nulls":4},"Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects"]
[{"$nulls":4},"3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies"]
[{"$nulls":4},"4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data"]
[{"$nulls":4},"5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale?"]
[null,null,null,"Sommario/riassunto","The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry.  Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More t"]
[null,"2.","Record Nr.",null,"UNINA9910816095103321"]
[null,null,"Autore",null,"Nakamoto Kazuo <1922->"]
[null,null,"Titolo",null,"Infrared and Raman spectra of inorganic and coordination compounds . Part A Theory and applications in inorganic chemistry / / Kazuo Nakamoto"]
[null,null,"Pubbl/distr/stampa",null,"Hoboken, N.J., : Wiley, c2009"]
[null,null,"ISBN",null,"9786612001895"]
[{"$nulls":4},"9781282001893"]
[{"$nulls":4},"1282001892"]
[{"$nulls":4},"9780470405840"]
[{"$nulls":4},"0470405848"]
[{"$nulls":4},"9780470405796"]
[{"$nulls":4},"0470405791"]
[null,null,"Edizione",null,"[6th ed.]"]
[null,null,"Descrizione fisica",null,"1 online resource (433 p.)"]
[null,null,"Disciplina",null,"535.842"]
[{"$nulls":4},"543.57"]
[{"$nulls":4},"543/.57"]
[null,null,"Soggetti",null,"Infrared spectroscopy"]
[{"$nulls":4},"Raman spectroscopy"]
[{"$nulls":4},"Espectroscòpia infraroja"]
[{"$nulls":4},"Espectroscòpia Raman"]
[{"$nulls":4},"Llibres electrònics"]
[null,null,"Lingua di pubblicazione",null,"Inglese"]
[null,null,"Formato",null,"Materiale a stampa"]
[null,null,null,"Livello bibliografico","Monografia"]
[null,null,null,"Note generali","Description based upon print version of record."]
[null,null,null,"Nota di bibliografia","Includes bibliographical references and index."]
[null,null,"Nota di contenuto",null,"Infrared and Raman Spectra of Inorganic and Coordination Compounds; Contents; PREFACE TO THE SIXTH EDITION; ABBREVIATIONS; Chapter 1. Theory of Normal Vibrations; 1.1. Origin of Molecular Spectra; 1.2. Origin of Infrared and Raman Spectra; 1.3. Vibration of a Diatomic Molecule; 1.4. Normal Coordinates and Normal Vibrations; 1.5. Symmetry Elements and Point Groups; 1.6. Symmetry of Normal Vibrations and Selection Rules; 1.7. Introduction to Group Theory; 1.8. The Number of Normal Vibrations for Each Species; 1.9. Internal Coordinates; 1.10. Selection Rules for Infrared and Raman Spectra"]
[{"$nulls":4},"1.11. Structure Determination1.12. Principle of the GF Matrix Method; 1.13. Utilization of Symmetry Properties; 1.14. Potential Fields and Force Constants; 1.15. Solution of the Secular Equation; 1.16. "]
[{"$nulls":4},"Vibrational Frequencies of Isotopic Molecules; 1.17. Metal-Isotope Spectroscopy; 1.18. Group Frequencies and Band Assignments; 1.19. Intensity of Infrared Absorption; 1.20. Depolarization of Raman Lines; 1.21. Intensity of Raman Scattering; 1.22. Principle of Resonance Raman Spectroscopy; 1.23. Resonance Raman Spectra; 1.24. Theoretical Calculation of Vibrational Frequencies"]
[{"$nulls":4},"1.25. Vibrational Spectra in Gaseous Phase and Inert Gas Matrices1.26. Matrix Cocondensation Reactions; 1.27. Symmetry in Crystals; 1.28. Vibrational Analysis of Crystals; 1.29. The Correlation Method; 1.30. Lattice Vibrations; 1.31. Polarized Spectra of Single Crystals; 1.32. Vibrational Analysis of Ceramic Superconductors; References; Chapter 2. Applications in Inorganic Chemistry; 2.1. Diatomic Molecules; 2.2. Triatomic Molecules; 2.3. Pyramidal Four-Atom Molecules; 2.4. Planar Four-Atom Molecules; 2.5. Other Four-Atom Molecules; 2.6. Tetrahedral and Square-Planar Five-Atom Molecules"]
[{"$nulls":4},"2.7. Trigonal-Bipyramidal and Tetragonal-Pyramidal XY(5) and Related Molecules2.8. Octahedral Molecules; 2.9. XY(7) and XY(8) Molecules; 2.10. X(2)Y(4) and X(2)Y(6) Molecules; 2.11. X(2)Y(7), X(2)Y(8), X(2)Y(9), and X(2)Y(10) Molecules; 2.12. Metal Cluster Compounds; 2.13. Compounds of Boron; 2.14. Compounds of Carbon; 2.15. Compounds of Silicon, Germanium, and Other Group IVB Elements; 2.16. Compounds of Nitrogen; 2.17. Compounds of Phosphorus and Other Group VB Elements; 2.18. Compounds of Sulfur and Selenium; 2.19. Compounds of Halogen; References; Appendixes"]
[{"$nulls":4},"I. Point Groups and Their Character TablesII. Matrix Algebra; III. General Formulas for Calculating the Number of Normal Vibrations in Each Species; IV. Direct Products of Irreducible Representations; V. Number of Infrared- and Raman-Active Stretching Vibrations for MX(n)Y(m)-Type Molecules; VI. Derivation of Eq. 1.113; VII. The G and F Matrix Elements of Typical Molecules; VIII. Group Frequency Charts; IX. Correlation Tables; X. Site Symmetry for the 230 Space Groups; Index"]
[null,null,null,"Sommario/riassunto","The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working wit"]