LEADER 04828nam 2200673 450 001 9910458081803321 005 20200520144314.0 010 $a1-281-03728-1 010 $a9786611037284 010 $a0-08-052133-9 035 $a(CKB)1000000000363806 035 $a(EBL)299474 035 $a(OCoLC)437182708 035 $a(SSID)ssj0000275342 035 $a(PQKBManifestationID)11221357 035 $a(PQKBTitleCode)TC0000275342 035 $a(PQKBWorkID)10350358 035 $a(PQKB)11047050 035 $a(MiAaPQ)EBC299474 035 $a(PPN)182569063 035 $a(Au-PeEL)EBL299474 035 $a(CaPaEBR)ebr10186737 035 $a(CaONFJC)MIL103728 035 $a(EXLCZ)991000000000363806 100 $a20170814h20002000 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aWriting reaction mechanisms in organic chemistry /$fAudrey Miller, Philippa H. Solomon 205 $aSecond edition. 210 1$aSan Diego, California :$cAcademic Press,$d2000. 210 4$dİ2000 215 $a1 online resource (487 p.) 225 1 $aAdvanced Organic Chemistry Series 300 $aIncludes index. 311 $a0-12-410509-2 311 $a0-12-496712-4 320 $aIncludes bibliographical references and index. 327 $aFront Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Contents; Preface to the Second Edition; Preface to First Edition; Chapter 1. Introduction-Molecular Structure and Reactivity; 1. How to Write Lewis Structures and Calculate Formal Charges; 2. Representations of Organic Compounds; 3. Geometry and Hybridization; 4. Electronegativities and Dipoles; 5. Resonance Structures; 6. Aromaticity and Antiaromaticity; 7. Tautomers and Equilibrium; 8. Acidity and Basicity; 9. Nucleophiles and Electrophiles; Chapter 2. General Principles for Writing Reaction Mechanisms 327 $a1. Balancing Equations2. Using Arrows to Show Moving Electrons; 3. Mechanisms in Acidic and Basic Media; 4. Electron-Rich Species: Bases or Nucleophiles?; 5. Trimolecular Steps; 6. Stability of Intermediates; 7. Driving Forces for Reactions; 8. Structural Relationships between Starting Materials and Products; 9. Solvent Effects; 10. A Last Word; Chapter 3. Reactions of Nucleophiles and Bases; 1. Nucleophilic Substitution; 2. Eliminations at Saturated Carbon; 3. Nucleophilic Addition to Carbonyl Compounds; 4. Base-Promoted Rearrangements; 5. Additional Mechanisms in Basic Media 327 $aChapter 4. Reactions Involving Acids and Other Electrophiles1. Stability of Carbocations; 2. Formation of Carbocations; 3. The Fate of Carbocations; 4. Rearrangement of Carbocations; 5. Electrophilic Addition; 6. Acid-Catalyzed Reactions of Carbonyl Compounds; 7. Electrophilic Aromatic Substitution; 8. Carbenes; 9. Electrophilic Heteroatoms; Chapter 5. Radicals and Radical Anions; 1. Introduction; 2. Formation of Radicals; 3. Radical Chain Processes; 4. Radical Inhibitors; 5. Determining the Thermodynamic Feasibility of Radical Reactions; 6. Addition of Radicals; 7. Fragmentation Reactions 327 $a8. Rearrangement of Radicals9. The Srnl Reaction; 10. The Birch Reduction; 11. A Radical Mechanism for the Rearrangement of Some Anions; Chapter 6. Pericyclic Reactions; 1. Introduction; 2. Electrocyclic Reactions; 3. Cycloadditions; 4. Sigmatropic Rearrangements; 5. The Ene Reaction; 6. A Molecular Orbital View of Pericyclic Processes; Chapter 7. Additional Problems; Appendix A: Lewis Structures of Common Functional Groups; Appendix B: Symbols and Abbreviations Used in Chemical Notation; Appendix C: Relative Acidities of Common Organic and Inorganic Substances; Index 330 $aWriting Reaction Mechanisms in Organic Chemistry, Second Edition, is an invaluable guide to charting the movements of atoms and electrons in the reactions of organic molecules. Miller and Solomon illustrate that understanding organic reactions is based on applying general principles rather than the rote memorization of unrelated processes, and, in turn, emphasize that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. Students and research chemists alike will find this book useful in providing a me 410 0$aAdvanced organic chemistry series. 606 $aOrganic reaction mechanisms 608 $aElectronic books. 615 0$aOrganic reaction mechanisms. 676 $a547/.139 700 $aMiller$b Audrey$0440363 702 $aSolomon$b Philippa H. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910458081803321 996 $aWriting reaction mechanisms in organic chemistry$91502625 997 $aUNINA LEADER 01130nam a2200277 i 4500 001 991003988509707536 008 081106s1998 enka 001 0 eng d 020 $a9780863433030 035 $ab13781546-39ule_inst 040 $aDi.S.Te.B.A.$beng 082 0 $a778.932$221 245 00$aWildlife photographer of the year.$nPortfolio 08 /$cdesigned by Grant Bradford ; competition manager Louise Grove-White 260 $aSurbiton :$bFountain Press,$c1998 300 $a160 p. :$bchiefly col. ill. ;$c26 cm 500 $aIncludes index of photographers 650 0$aWildlife photography 650 0$aAnimals$vPictorial works 650 0$aNature$vPictorial works 700 1 $aBradford, Grant$eauthor$4http://id.loc.gov/vocabulary/relators/aut$0739466 700 1 $aWhite-Grove, Louise 907 $a.b13781546$b28-01-14$c06-11-08 912 $a991003988509707536 945 $aLE003 704 WIL01.01 08 (1998)$g1$i2003000081978$lle003$op$pE33.11$q-$rl$s- $t0$u1$v0$w1$x0$y.i14902692$z11-12-08 996 $aWildlife photographer of the year$91464813 997 $aUNISALENTO 998 $ale003$b06-11-08$cm$da $e-$feng$genk$h0$i0