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Zuckerman; editor, A.P. Hagen 210 $aNew York $cWiley-VCH$dc1990 215 $a1 online resource (462 p.) 225 0 $aInorganic reactions and methods ;$vv. 17 300 $aDescription based upon print version of record. 311 $a0-471-18667-8 320 $aIncludes bibliographical references and indexes. 327 $aInorganic Reactions and Methods; Contents; Ring-ring and Ring-chain interconversions.; in Cage Polyboranes and Carboranes.; The Formation of Sheet Structures; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 17; Oligomerization and Polymerization; Introduction; Definitions and Scope.; Definitions of Oligomers and Polymers.; General Synthesis Methods.; Scope.; Small-Ring Systems-Examples of Synthesis.; Cages-ExampIes of Synthesis.; Short Chains-Examples of Synthesis.; Long Chains- Long Chains-Examples of 327 $aCharacteristic Differences Between Small and Large Molecules as Related to Their Synthesis.Special Characteristics of Small Cyclic and Linear Molecules.; Special Characteristics of Long-Chain MolecuIes.; Chain-Chain , Chain-Ringand Ring-Ring Equilibria; Bond Lability in Inorganic Systems.; Some Important Relationships Based on Theory.; The Chain Population.; The Ring Population and Network Macromolecules.; Introduction; Scrambling in Inorganic Systems.; All-Neso Systems.; Oligomers and Polymers in QZ,-QT, Systems with Z Bridging.; Exchange of Segments Between CycIic MoIecules. 327 $aChains and Rings from Scrambling Between Two Kinds of Central Moieties.Ring-Ring and Ring-Polymer Ring-Ring and Ring-Polymer Interconversions; Introduction; lnterconversion of Sulfur or Selenium Rings and Chains; Theory; Experimental Techniques; Viscosity Measurements.; Ultrasonic Absorption in Liquid Selenium.; Quenching Experiments.; Diamagnetic SusceptibiIity Measurements.; Paramagnetic SusceptibiIity Measurements.; Electron Spin Resonance Absorption (ESR); Optical Absorption.; Vibrational Spectroscopy of Sulfur.; Nuclear Magnetic Resonance (NMR) Measurements on Selenium. 327 $aDielectric Constant Measurements of SuIfur.Specific Heat Measurements on Sulfur and Selenium.; Density Measurements.; Thermal Conductivity in Liquid Selenium.; Electrical Conductivity of Sulfur.; In Oligomeric Catenates of P, As, Sb and Bi.; General Trends.; Phosphorus.; Arsenic.; Antimony.; Stabilized Rings and Chains.; In Silicon-Silicon Systems.; Formation of Cyclic Silicon-Silicon Systems.; Perarylcyclosilanes.; Permethylcyclosilanes.; Other Peralkylcyclosilanes.; AIkyIarylcyclosiIanes .; Reactions of Cyclosilanes.; Substitutional Reactions.; Ring-Cleavage Reactions.; Photolysis. 327 $aRing-Ring and Chain-Ring Interconversion.Cage Polysilanes.; Silane High Polymers.; in Boron-Nitrogen Systems.; Synthesis of Ring Compounds; Borazines and Related Compounds.; Coordinately Saturated B-N Rings.; Factors Affecting Stability of Ring Species.; Preparation of Linear Boron-Nitrogon 0ligomers.; lnterconversions in Boron-Nitrogen System; Preparation of Boron-Nitrogen Polymers.; Linear Boron-Nitrogen Chains.; Polycyclic Chains.; in Boron-Oxygen and Boron-Sulfur Systems; Anionic Boron-Oxygen Compounds.; Molecular Boron-Oxygen Species.; Boron-SuIfur Compounds. 327 $aRing-Ring and Ring-Polymer interconversions. 330 $aFor the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximize 410 0$aInorganic Reactions and Methods 606 $aPolymerization 606 $aClathrate compounds 608 $aElectronic books. 615 0$aPolymerization. 615 0$aClathrate compounds. 676 $a541.3/9 676 $a547.28 701 $aHagen$b A. P$0857124 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910144318303321 996 $aOligomerization and polymerization$92186512 997 $aUNINA LEADER 01237cam a22002898i 4500 001 991003616379707536 008 181010s2019 flu b 001 0 eng 020 $a9781138711136 (hardback : alk. paper) 035 $ab14360688-39ule_inst 040 $aBibl. Dip.le Aggr. Scienze Economia - Sez. 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