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200 1 $aEconomia aziendale$fAurelio Tommasetti, Marco Bisogno
210 $aMilano$cAngeli$d2015
215 $aXIV, 378 p.$d24 cm
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183 $acr
200 00$aLanthanides and actinides in molecular magnetism /$fedited by Richard A. Layfield and Muralee Murugesu
210 1$aWeinheim :$cWiley-VCH,$d[2015]
210 4$dİ2015
215 $a1 online resource (367 p.)
300 $aDescription based upon print version of record.
311 $a3-527-33526-9
311 $a1-322-77641-5
320 $aIncludes bibliographical references and index.
327 $aLanthanides and Actinides in Molecular Magnetism; Contents; Preface; List of Contributors; Chapter 1 Electronic Structure and Magnetic Properties of Lanthanide Molecular Complexes; 1.1 Introduction; 1.2 Free Ion Electronic Structure; 1.2.1 Free Ion Magnetism; 1.3 Electronic Structure of Lanthanide Ions in a Ligand Field; 1.3.1 Stevens' Formalism; 1.3.2 Wybourne's Formalism; 1.3.3 Standardization; 1.3.4 Calculation of Crystal Field Parameters; 1.4 Magnetic Properties of Isolated Lanthanide Ions; 1.4.1 Effect of a Magnetic Field; 1.4.2 EPR Spectroscopy of Lanthanide Complexes
327 $a1.5 Exchange Coupling in Systems Containing Orbitally Degenerate LanthanidesAcknowledgements; References; Chapter 2 Mononuclear Lanthanide Complexes: Use of the Crystal Field Theory to Design Single-Ion Magnets and Spin Qubits; 2.1 Introduction; 2.2 Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets: The Use of the Crystal Field Model; 2.2.1 Theoretical Background; 2.2.2 How to Determine the Crystal-Field Parameters: 1. The Ishikawa Approach; 2.2.3 How to Determine the Crystal-Field Parameters: 2. The Point Charge Electrostatic Model
327 $a2.2.4 How to Determine the Crystal-Field Parameters: 3. The Effective Point Charge Model2.3 Magneto-Structural Correlations for Some Typical Symmetries; 2.4 Impact of Lanthanide Complexes in Quantum Computing; 2.4.1 Quantum Computing Paradigms and Design Criteria; 2.4.2 Combining Physical Qubit Implementations with Lanthanide Complexes; 2.4.3 Molecular Spin Qubits; 2.5 Conclusions; Acknowledgements; References; Chapter 3 Polynuclear Lanthanide Single Molecule Magnets; 3.1 Introduction; 3.2 Synthetic Strategies; 3.2.1 Dy3 Triangles and Their Derivatives; 3.2.1.1 Seminal Dy3 Triangle
327 $a3.2.1.2 Other Triangular Dy3 Systems3.2.1.3 The Coupling of Dy3 Triangles; 3.2.2 Linear Polynuclear Lanthanide Complexes Showing Robust SMM Behaviour; 3.2.2.1 Linear Dy3 SMMs; 3.2.2.2 Linear Dy4 SMMs; 3.2.3 Planar Dy4 SMMs; 3.2.4 Dyn SMMs Having Multiple ?n-O (n>4) Bridges; 3.2.4.1 The Dy4 Grids Fixed by ?4-O Atom; 3.2.4.2 The Dy4 Tetrahedron Fixed by ?4-O Atom; 3.2.4.3 The Dy5 Pyramid Fixed by ?5-O Atom; 3.2.5 Hydrazone-Based Lanthanide SMMs; 3.2.5.1 The Assembly of Dy6 Triangular Prism with Dy2 Units; 3.2.5.2 A Dy3 Molecular Cluster Pair (Dy6)
327 $a3.2.6 The Organometallic Synthesis - A New Approach3.3 Conclusion; References; Chapter 4 Lanthanides in Extended Molecular Networks; 4.1 Introduction; 4.2 Extended Networks Based on Gd3+; 4.2.1 Metal-Organic Frameworks; 4.2.1.1 Magneto-Caloric Effect; 4.2.1.2 Slow Magnetic Relaxation and Phonon Bottleneck Effects; 4.2.2 Magnetic Chains; 4.2.2.1 Magnetic Interactions Involving Gd3+ Ions; 4.2.2.2 Gadolinium-Radical Chains; 4.3 Extended Networks Based on Anisotropic Ions; 4.3.1 SCM in a Nutshell; 4.3.2 An Overview of Monodimensional Lanthanide Chains Based on Anisotropic Ions
327 $a4.3.2.1 Chains Based on 4f Ions
330 $aThe first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends.
A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial applications.
The resulting unique overview is a must-have for researchers, both in academia and industry, who are entering or already working in the field.
606 $aRare earth metals
606 $aActinide elements
615 0$aRare earth metals.
615 0$aActinide elements.
676 $a551.5
702 $aLayfield$b Richard A.
702 $aMurugesu$b Muralee
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906 $aBOOK
912 $a9910132284103321
996 $aLanthanides and actinides in molecular magnetism$91978881
997 $aUNINA