LEADER 01258nam a22002531i 4500 001 991004174149707536 005 20030225162554.0 008 020821s1923 sz a||||||||||||||||ita 035 $ab11930366-39ule_inst 035 $aARCHE-002018$9ExL 040 $aDip.to Filologia Ling. e Lett.$bita$cA.t.i. Arché s.c.r.l. Pandora Sicilia s.r.l. 100 1 $aBertoldi, Vittorio$0156486 245 13$aUn ribelle nel regno de' fiori :$bi nomi romanzi del colchicum autumnale L attraverso il tempo e lo spazio /$cVittorio Bertoldi 260 $aGenève :$bL.S. Olschki,$c1923 300 $aV, 224 p., [3] c. di tav. :$bill. ;$c27 cm 490 0 $aBiblioteca dell'Archivum Romanicum.$nSerie 2,$pLinguistica 907 $a.b11930366$b28-04-17$c01-04-03 912 $a991004174149707536 945 $aLE008 FL.M. IV D 35$g1$i2008000148386$lle008$o-$pE0.00$q-$rn$so $t0$u0$v0$w0$x0$y.i12202721$z01-04-03 945 $aLE008 LLI.S L I 20$g2$i2008000288778$lle008$o-$pE0.00$q-$rn$so $t0$u0$v0$w0$x0$y.i12202733$z01-04-03 945 $aLE008 FL.M. (f.r.) IX 30$g3$i2008000414221$lle008$o-$pE0.00$q-$rn$so $t0$u0$v0$w0$x0$y.i12202745$z01-04-03 996 $aRibelle nel regno de' fiori$9527509 997 $aUNISALENTO 998 $ale008$b01-04-03$cm$da $e-$fita$gsz $h3$i3 LEADER 05844nam 22008413u 450 001 996218171503316 005 20230617011948.0 010 $a1-280-27032-2 010 $a9786610270323 010 $a0-470-36296-0 010 $a0-470-85579-7 010 $a0-470-85580-0 035 $a(CKB)111087027148366 035 $a(EBL)153812 035 $a(OCoLC)807996068 035 $a(SSID)ssj0000291044 035 $a(PQKBManifestationID)11217254 035 $a(PQKBTitleCode)TC0000291044 035 $a(PQKBWorkID)10249037 035 $a(PQKB)10569495 035 $a(MiAaPQ)EBC153812 035 $a(EXLCZ)99111087027148366 100 $a20131014d2003|||| u|| | 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aCatalysts for fine chemical synthesis$b[electronic resource] $ehydrolysis, oxidation and reduction 210 $aHoboken $cWiley$d2003 215 $a1 online resource (245 p.) 225 1 $aCatalysts For Fine Chemicals Synthesis ;$vv.7 300 $aDescription based upon print version of record. 311 $a0-471-98123-0 327 $aCatalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds 327 $a4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols 327 $a5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters 327 $a6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3)) 327 $a6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References 327 $a9 Asymmetric Reduction of Ketones Using Organometallic Catalysts 330 $aCatalysts are increasingly used by chemists engaged in fine chemical synthesis within both industry and academia. Today, there exists a huge choice of high-tech catalysts, which add enormously to the repertoire of synthetic possibilities. However, catalysts are occasionally capricious, sometimes difficult to use and almost always require both skill and experience in order to achieve optimal results. 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