LEADER 05487nam 2200661Ia 450 001 996213067903316 005 20231115213205.0 010 $a1-280-74867-2 010 $a9786610748679 010 $a0-470-98879-7 010 $a9780470988794 035 $a(CKB)1000000000341837 035 $a(EBL)284291 035 $a(OCoLC)298973680 035 $a(SSID)ssj0000178510 035 $a(PQKBManifestationID)11156318 035 $a(PQKBTitleCode)TC0000178510 035 $a(PQKBWorkID)10230360 035 $a(PQKB)11519855 035 $a(MiAaPQ)EBC284291 035 $a(EXLCZ)991000000000341837 100 $a20060429d2007 uy 0 101 0 $aeng 135 $aurnn|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aInductively coupled plasma spectrometry and its applications$b[electronic resource] /$fedited by Steve J. Hill 205 $a2nd ed. 210 $aOxford $cBlackwell$d2007 215 $a1 online resource (447 p.) 225 1 $aAnalytical chemistry 300 $aPrevious ed.: Sheffield: Sheffield Academic Press, 1999 311 0 $a978-1-4051-3594-8 320 $aIncludes bibliographical references and index 327 $aInductively Coupled Plasma Spectrometry and its Applications; Contents; Contributors; Preface; 1 Introduction - A Forward-Looking Perspective; 1.1 Introduction; 1.2 Extrapolation of past and current trends; 1.2.1 Influences from science and technology; 1.2.2 Influences from society, politics, and the economy; 1.2.3 Past and current trends in atomic spectrometry; 1.3 Influence of technology transfer; 1.3.1 Electronics and data manipulation; 1.3.2 Metal-binding structures; 1.3.3 Novel separation methods; 1.3.4 Detector technologies; 1.4 Strengths and weaknesses of ICP-AES and ICP-MS 327 $a1.4.1 Strengths and weaknesses of ICP-AES1.4.2 Strengths and weaknesses of ICP-MS; 1.4.3 ICP limitations; 1.5 Potential directions in ICP spectrometry; 1.6 Concluding considerations; References; 2 Fundamental Principles of Inductively Coupled Plasmas; 2.1 Principles to inductively coupled plasma generation; 2.2 Equilibrium in a plasma; 2.3 Line intensities; 2.4 Line profiles; 2.5 Temperature definitions; 2.6 Temperature measurements; 2.6.1 Kinetic temperature measurement; 2.6.2 Rotational temperature measurement; 2.6.3 Excitation temperature; 2.6.3.1 Boltzmann plot; 2.6.3.2 Line pair method 327 $a2.6.4 Electron temperature2.7 Electron number density measurement; 2.8 Ionic to atomic line intensity ratio; 2.9 Active methods; 2.9.1 Laser-induced fluorescence; 2.9.2 Light scattering; 2.10 Spatial profiles; 2.11 Temperature and electron number densities observed in analytical ICPs; 2.12 Plasma perturbation; 2.13 Multiline diagnostics; References; 3 Basic Concepts and Instrumentation for Plasma Spectrometry; 3.1 Detection limits and sensitivity; 3.1.1 ICP-Atomic emission spectrometry; 3.1.2 Limits of detection; 3.1.3 Axial systems; 3.1.4 The sample introduction system; 3.1.5 Detectors 327 $a3.2 Accuracy and precision3.2.1 Instrumental drift; 3.2.2 Matrix effects; 3.2.3 Plasma effects; 3.2.4 Spectral effects, interferences and background correction; 3.2.5 Dynamic range; 3.2.6 ICP-MS; 3.3 Multi-element capability and selectivity; 3.4 Instrumental overview; 3.5 Radio-frequency generators; 3.6 Torches; 3.7 Spectrometers; 3.7.1 Line isolation; 3.7.2 Monochromators; 3.7.3 Polychromators; 3.8 Detectors; 3.8.1 Photomultiplier tubes; 3.8.2 Solid-state detectors; 3.9 Nebulisers and spray chambers; 3.10 Read-out devices, instrument control and data processing; 3.11 Radial and axial plasmas 327 $a3.12 Instrumentation for high-resolution spectrometry3.13 Micro-plasmas and plasma on a chip; References; 4 Aerosol Generation and Sample Transport; 4.1 Introduction; 4.2 Sample introduction characteristics of the ICP source; 4.2.1 Particle size distribution; 4.2.2 Plasma loading; 4.3 Liquid aerosol generation; 4.3.1 Pneumatic nebulization; 4.3.1.1 Pneumatic nebulizer designs; 4.3.1.2 Ultrasonic nebulizers; 4.3.1.3 Alternative nebulizer designs; 4.3.2 Spray chambers; 4.3.2.1 Mode of operation; 4.3.2.2 Practical designs of spray chambers; 4.3.2.3 Desolvation; 4.3.3 Chromatographic interfaces 327 $a4.4 Vapour generation 330 $aThe first edition of Inductively Coupled Plasma Spectrometry and its Applications was written as a handbook for users who wanted a better understanding of the theory augmented by a practical insight of how best to approach a range of applications, and to provide a useful starting point for users trying an approach or technique new to them. These objectives have been retained in the second edition but a slight shift in emphasis gives the volume an overall perspective that is more forward looking.Structured into 11 chapters, the current edition is a thorough revision of the original, cov 410 0$aAnalytical chemistry series 606 $aInductively coupled plasma spectrometry 606 $aInductively coupled plasma mass spectrometry 615 0$aInductively coupled plasma spectrometry 615 0$aInductively coupled plasma mass spectrometry 676 $a543.65 676 $a543/.65 676 $a643.65 702 $aHill$b Steve J. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996213067903316 996 $aInductively coupled plasma spectrometry and its applications$93583808 997 $aUNISA