LEADER 05331nam 2200637Ia 450 001 996211961703316 005 20230213211345.0 010 $a1-282-30827-0 010 $a9786612308277 010 $a0-470-14530-7 010 $a0-470-14551-X 035 $a(CKB)1000000000376310 035 $a(EBL)468925 035 $a(OCoLC)741345816 035 $a(SSID)ssj0000299742 035 $a(PQKBManifestationID)11242833 035 $a(PQKBTitleCode)TC0000299742 035 $a(PQKBWorkID)10243321 035 $a(PQKB)10671225 035 $a(MiAaPQ)EBC468925 035 $a(EXLCZ)991000000000376310 100 $a19870613d1986 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aElectron-transfer and electrochemical reactions$b[electronic resource] $ephotochemical and other energized reactions /$feditor, J.J. Zuckerman; subject index editor, A.P. Hagen 210 $a[Deerfield Beach, FL] $cVCH$dc1986 215 $a1 online resource (426 p.) 225 0 $aInorganic reactions and methods ;$vv. 15 300 $aDescription based upon print version of record. 311 $a0-471-18665-1 320 $aIncludes bibliographical references. 327 $aInorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes 327 $aMixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical Treatment; Cross Reactions and Electron-Exchange Rates 327 $aQuantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants 327 $aOxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials 327 $aInvolving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions 327 $aThermodynamics of Simple Electrochemical Reactions 330 $aHow to Use this Book. Preface to the Series. Editorial Consultants to the Series. Contributors to Volume 15. 12. Electron-Transfer and Electrochemical Reactions. 12.1. Introduction. 12.2. Electron Transfer. 12.3. Electrochemical Reactions. 13. Photochemical and Other Energized Reactions. 13.1. Introduction. 13.2. Photosubstitution and Photoisomerization. 13.3. Photoinduced Cleavage of Metal-Metal Bonds. 13.4. Photoinduced Electron-Transfer Reactions. 13.5. Pulse Radiolysis. List of Abbreviations. Author Index. Compound Index. Subject Index 410 0$aInorganic Reactions and Methods 606 $aPhotochemistry 606 $aCharge transfer 615 0$aPhotochemistry. 615 0$aCharge transfer. 676 $a541.3/9 676 $a541.39 701 $aZuckerman$b J. J$g(Jerold J.),$f1936-1987.$0857123 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996211961703316 996 $aElectron-transfer and electrochemical reactions$93005130 997 $aUNISA