LEADER 05203nam 22006374a 450 001 996205342703316 005 20170809173641.0 010 $a1-280-74827-3 010 $a9786610748273 010 $a0-470-98859-2 010 $a1-4051-7179-0 035 $a(CKB)1000000000341909 035 $a(EBL)284288 035 $a(OCoLC)437176163 035 $a(SSID)ssj0000120549 035 $a(PQKBManifestationID)11141692 035 $a(PQKBTitleCode)TC0000120549 035 $a(PQKBWorkID)10092551 035 $a(PQKB)10698300 035 $a(MiAaPQ)EBC284288 035 $a(PPN)14039673X 035 $a(EXLCZ)991000000000341909 100 $a20050617d2006 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aChemistry and technology of surfactants$b[electronic resource] /$fedited by Richard J. Farn 210 $aOxford ;$aAmes, Iowa $cBlackwell Pub.$d2006 215 $a1 online resource (338 p.) 300 $aDescription based upon print version of record. 311 $a1-4051-2696-5 320 $aIncludes bibliographical references and index. 327 $aChemistry and Technology of Surfactants; Contents; Contributors; Preface; Glossary; 1 What Are Surfactants?; 1.1 History and applications of surfactants; 1.1.1 Introduction; 1.1.2 Properties and other criteria influencing surfactant choice; 1.1.3 Surfactant applications; 1.1.4 Conclusion; Appendix: Application guide; 1.2 Surfactant market overview: importance in different industries; 1.2.1 Introduction; 1.2.2 Consumer; 1.2.3 Industrial; 2 The Basic Theory; 2.1 Molecular structure of surfactants; 2.2 Surface activity; 2.2.1 Surface tension; 2.2.2 Interfacial tension 327 $a2.2.3 Surface and interfacial tension reduction2.2.4 Test methods for surface and interfacial tension measurements; 2.3 Self-assembled surfactant aggregates; 2.3.1 Micelles and critical micelle concentration; 2.3.2 Aggregate structures and shapes; 2.4 Adsorption of surfactants at surfaces; 2.4.1 Adsorption at liquid-gas and liquid-liquid interfaces; 2.4.2 Adsorption at liquid-solid interface; Acknowledgement; References; 3 Applied Theory of Surfactants; 3.1 Introduction; 3.2 Detergency; 3.2.1 Fundamental processes; 3.2.2 Basic formulae of detergents and cleansers 327 $a3.2.3 Adsorption at the solid-liquid interface3.2.4 Surface tension and wetting; 3.2.5 Interplay of surfactants with other detergent ingredients; 3.3 Phase behaviour of surfactants; 3.3.1 Introduction; 3.3.2 Surfactant phases; 3.3.3 Impact of the phase behaviour on detergency; 3.4 Emulsions; 3.4.1 Introduction; 3.4.2 Emulsion types; 3.4.3 Breakdown of emulsions; 3.5 Foaming and defoaming; 3.5.1 Introduction; 3.5.2 Stabilising effects in foams; 3.5.3 Correlation of foamability with interfacial parameters; 3.5.4 Foam control; 3.6 Rheology of surfactant solutions; 3.6.1 Introduction 327 $a3.6.2 Rheological terms3.6.3 Rheological behaviour of monomeric solutions and non-interacting micelles; 3.6.4 Entanglement networks of rod-like micelles; 3.6.5 The rheological behaviour of bilayer phases; References; 4 Anionic Surfactants; 4.1 Sulphonates; 4.1.1 Alkylbenzene sulphonates; 4.1.2 a-Olefin sulphonates; 4.1.3 Paraffin sulphonates; 4.1.4 Sulphonated methyl esters; 4.1.5 Sulphonated fatty acids; 4.1.6 Sulphosuccinates; 4.2 Sulphates; 4.2.1 Alkyl sulphates; 4.2.2 Alkyl ether sulphates; 4.3 Phosphate esters; 4.4 Carboxylates; 4.4.1 Soap; 4.4.2 Ether carboxylates 327 $a4.4.3 Acyl sarcosinates4.4.4 Alkyl phthalamates; 4.4.5 Isethionates; 4.4.6 Taurates; References; 5 Non-ionic Surfactants; 5.1 Introduction; 5.2 General alkoxylation reactions; 5.3 Alkyl phenol ethoxylates; 5.4 Fatty alcohol ethoxylates; 5.5 Polyoxethylene esters of fatty acids; 5.6 Methyl ester ethoxylates; 5.7 Polyalkylene oxide block co-polymers; 5.8 Amine ethoxylates; 5.9 Fatty alkanolamides; 5.10 Amine oxides; 5.11 Esters of polyhydric alcohols and fatty acids; 5.12 Glycol esters; 5.13 Glycerol esters; 5.14 Polyglycerol esters; 5.15 Anhydrohexitol esters 327 $a5.16 Polyoxyalkylene polyol esters 330 $aSurfactants are used throughout industry as components in a huge range of formulated products or as effect chemicals in the production or processing of other materials. A detailed understanding of the basis of their activity is required by all those who use surfactants, yet the new graduate or postgraduate chemist or chemical engineer will generally have little or no experience of how and why surfactants work. Chemistry & Technology of Surfactants is aimed at new graduate or postgraduate level chemists and chemical engineers at the beginning their industrial careers and those in l 606 $aSurface chemistry 606 $aSurface active agents 615 0$aSurface chemistry. 615 0$aSurface active agents. 676 $a541.33 676 $a541/.33 676 $a668.1 701 $aFarn$b Richard J$0881284 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996205342703316 996 $aChemistry and technology of surfactants$91968213 997 $aUNISA