LEADER 05328nam 22006734a 450 001 996204916703316 005 20220302155723.0 010 $a1-4443-2020-3 010 $a1-282-54817-4 010 $a1-281-21483-3 010 $a9786611214838 010 $a9786612548178 010 $a0-470-76152-0 010 $a1-4443-0539-5 010 $a1-4051-6838-2 035 $a(CKB)1000000000278450 035 $a(EBL)487733 035 $a(SSID)ssj0000071595 035 $a(PQKBManifestationID)11107102 035 $a(PQKBTitleCode)TC0000071595 035 $a(PQKBWorkID)10091057 035 $a(PQKB)10192198 035 $a(MiAaPQ)EBC284152 035 $a(MiAaPQ)EBC487733 035 $a(PPN)14042122X 035 $a(EXLCZ)991000000000278450 100 $a20050204d2005 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aColloid science$b[electronic resource] $eprinciples, methods and applications /$fedited by Terence Cosgrove 205 $a2nd ed. 210 $aOxford, UK ;$aAmes, Iowa $cBlackwell Pub.$d2010 215 $a1 online resource (399 p.) 300 $aDescription based upon print version of record. 311 $a1-4443-2018-1 311 $a1-4051-2673-6 320 $aIncludes bibliographical references and index. 327 $aColloid Science Principles, methods and applications; Contents; Preface; Introduction; Acknowledgements; List of Contributors; 1 An Introduction to Colloids; 1.1 Introduction; 1.2 Basic Definitions; 1.2.1 Concentration; 1.2.2 Interfacial Area; 1.2.3 Effective Concentrations; 1.2.4 Average Separation; 1.3 Stability; 1.3.1 Quiescent Systems; 1.3.2 Sedimentation or Creaming; 1.3.3 Shearing Flows; 1.3.4 Other Forms of Instability; 1.4 Colloid Frontiers; References; 2 Charge in Colloidal Systems; 2.1 Introduction; 2.2 The Origin of Surface Charge; 2.2.1 Ionisation of Surface Groups 327 $a2.2.2 Ion Adsorption2.2.3 Dissolution of Ionic Solids; 2.2.4 Isomorphous Substitution; 2.2.5 Potential Determining Ions; 2.3 The Electrochemical Double Layer; 2.3.1 The Stern-Gouy-Chapman (SGC) Model of the Double Layer; 2.3.2 The Double Layer at the Hg/Electrolyte Interface; 2.3.3 Specific Adsorption; 2.3.4 Interparticle Forces; 2.4 Electrokinetic Properties; 2.4.1 Electrolyte Flow; 2.4.2 Streaming Potential Measurements; 2.4.3 Electro-osmosis; 2.4.4 Electrophoresis; 2.4.5 Electroacoustic Technique; References; 3 Stability of Charge-stabilised Colloids; 3.1 Introduction 327 $a3.2 The Colloidal Pair Potential3.2.1 Attractive Forces; 3.2.2 Electrostatic Repulsion; 3.2.3 Effect of Particle Concentration; 3.2.4 Total Potential; 3.3 Criteria for Stability; 3.3.1 Salt Concentration; 3.3.2 Counter-ion Valency; 3.3.3 Zeta Potential; 3.3.4 Particle Size; 3.4 Kinetics of Coagulation; 3.4.1 Diffusion-limited Rapid Coagulation; 3.4.2 Interaction-limited Coagulation; 3.4.3 Experimental Determination of c.c.c.; 3.5 Conclusions; References; 4 Surfactant Aggregation and Adsorption at Interfaces; 4.1 Introduction; 4.2 Characteristic Features of Surfactants 327 $a4.3 Classification and Applications of Surfactants4.3.1 Types of Surfactants; 4.3.2 Surfactant Uses and Development; 4.4 Adsorption of Surfactants at Interfaces; 4.4.1 Surface Tension and Surface Activity; 4.4.2 Surface Excess and Thermodynamics of Adsorption; 4.4.3 Efficiency and Effectiveness of Surfactant Adsorption; 4.5 Surfactant Solubility; 4.5.1 The Krafft Temperature; 4.5.2 The Cloud Point; 4.6 Micellisation; 4.6.1 Thermodynamics of Micellisation; 4.6.2 Factors Affecting the CMC; 4.6.3 Structure of Micelles and Molecular Packing; 4.7 Liquid Crystalline Mesophases; 4.7.1 Definition 327 $a4.7.2 Structures4.7.3 Phase Diagrams; 4.8 Advanced Surfactants; References; 5 Microemulsions; 5.1 Introduction; 5.2 Microemulsions: Definition and History; 5.3 Theory of Formation and Stability; 5.3.1 Interfacial Tension in Microemulsions; 5.3.2 Kinetic Instability; 5.4 Physicochemical Properties; 5.4.1 Predicting Microemulsion Type; 5.4.2 Surfactant Film Properties; 5.4.3 Phase Behaviour; 5.5 Developments and Applications Temperature; 5.5.1 Microemulsions with Green and Novel Solvents; 5.5.2 Microemulsions as Reaction Media for Nanoparticles; References; 6 Emulsions; 6.1 Introduction 327 $a6.1.1 Definitions of Emulsion Type 330 $aColloidal systems are important across a range of industries, such as the food, pharmaceutical, agrochemical, cosmetics, polymer, paint and oil industries, and form the basis of a wide range of products (eg cosmetics & toiletries, processed foodstuffs and photographic film). A detailed understanding of their formation, control and application is required in those industries, yet many new graduate or postgraduate chemists or chemical engineers have little or no direct experience of colloids. Based on lectures given at the highly successful Bristol Colloid Centre Spring School, Colloid Scie 606 $aColloids 615 0$aColloids. 676 $a541.345 676 $a541/.345 701 $aCosgrove$b T$g(Terence)$0879122 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996204916703316 996 $aColloid science$91963223 997 $aUNISA