LEADER 05603nam 2200697Ia 450 001 996203158703316 005 20230421044552.0 010 $a1-281-75852-3 010 $a9786611758523 010 $a3-527-61493-1 010 $a3-527-61492-3 035 $a(CKB)1000000000376821 035 $a(EBL)481405 035 $a(SSID)ssj0000145053 035 $a(PQKBManifestationID)11150664 035 $a(PQKBTitleCode)TC0000145053 035 $a(PQKBWorkID)10156265 035 $a(PQKB)11221409 035 $a(MiAaPQ)EBC481405 035 $a(OCoLC)212132327 035 $a(EXLCZ)991000000000376821 100 $a19960611d1996 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aElectrochemical phase formation and growth$b[electronic resource] $ean introduction to the initial stages of metal deposition /$fE. Budevski, G. Staikov, W.J. Lorenz 210 $aWeinheim ;$aNew York $cVCH$dc1996 215 $a1 online resource (424 p.) 225 1 $aAdvances in electrochemical science and engineering 300 $aDescription based upon print version of record. 311 $a3-527-29422-8 320 $aIncludes bibliographical references (p. [343]-380) and indexes. 327 $aElectrochemical Phase Formation and Growth; Contents; 1 Fundamentals of Electrocrystallization of Metals; 1.1 Thermodynamic and Kinetic Aspects; 1.2 Metal Deposition Mechanisms; 1.3 Topics of this Book; 2 Crystalline Metal Surfaces; 2.1 Structural Aspects; Close-packed 2D and 3D crystal structures; Crystal imperfections and surface inhomogeneities; Surface reconstruction; Surface roughness and the kink position; Step roughness; 2.2 Atomic Dynamics; Atom exchange frequencies; Local, partial, and overall current densities; Kink atoms and the Nernst equilibrium potential 327 $aExchange current density of kink atomsConcentration of adatoms; Exchange current density of adatoms; Mean residence time and surface displacement of adatoms; 2.3 Surface Profile Mobility; Surface diffusion and mean displacement of adatoms; Surface diffusion . The exact solution; Direct transfer; Current density on a stepped crystal face; 2.4 Conclusions; 3 Underpotential Deposition of Metals-2D Phases; 3.1 Historical Background; 3.2 Phenomenology; 3.3 Thermodynamics; Thermodynamic formalism; Adsorption isotherm models; Experimental results; 3.4 Structures of 2D Meads Phases 327 $aDegree of registryInternal strain; Electrochemical results; Comparative and ex situ UHV results; In situ surface analytical results; 3.5 Kinetics; Quasi-homogeneous substrate surface approach; Inhomogeneous substrate surface approach; Phase transitions; 3.6 2D and 3D Me-S Alloy Formation; Phenomenology; Thermodynamics; Structures of 2D and 3D Me-alloys; Kinetics; 3.7 Conclusion; 4 Initial Stages of Bulk Phase Formation; 4.1 Equilibrium Form of Crystals and Forms of Growth; Equilibrium form; Crystal-substrate interaction; Gibbs-Wulff-Kaishew theorem; Two dimensional crystal; Forms of growth 327 $aEnergy of cluster formation3D nucleation; 2D nucleation; Gibbs-Thomson equation; 4.2 Nucleation Rate; Classical approach (Volmer and Weber); Kinetic approach (Becker and Doering); Binding energies and energy of nucleation; Atomistic model; Nucleation rate equation; Small cluster model; Experimental results; 4.3 3D Phase Formation on UPD Modified Foreign Substrate Surfaces; UPD-OPD transitions; Nucleation and growth; Epitaxy; Experimental results; 4.4 Conclusions; 5 Growth of Crystalline Faces; 5.1 Dislocation-Free Crystal Faces; Preparation of single crystal faces by electrodeposition 327 $aDouble pulse techniqueNucleation rate-overvoltage dependence; Time distribution of the nucleation events; Form of growth of monatomic layers; Propagation rate of monatomic steps; Space distribution of nucleation events; Propagation rate of polyatomic steps; Mechanism of metal deposition and adatom concentration; 5.2 Growth Kinetics of Perfect Faces; Mononuclear layer-by-layer growth; Multinuclear monolayer formation; Deposition kinetics on quasi-perfect crystal faces; 5.3 Real Crystal Faces; Dislocations; Spiral growth mechanism; Theory of spiral growth; Growth morphology 327 $aSteady state and transient current densities 330 $aElectrochemical processes and methods are basic to many important scientific disciplines, materials science and nanotechnology being only two keywords. For the first time in more than twenty years this volume presents a critical survey of the foundations, methodology and applications of electrochemical phase formation and growth processes. Written by a team of three internationally renowned authors, it is an invaluable source of information for all scientists concerned with electrocrystallization of metals or the in-situ characterization of electron-conducting surfaces. Not only the numerous i 410 0$aAdvances in electrochemical science and engineering. 606 $aElectroplating 606 $aMetals$xSurfaces 606 $aCrystal growth 615 0$aElectroplating. 615 0$aMetals$xSurfaces. 615 0$aCrystal growth. 676 $a541.37 676 $a670.7/32 676 $a670.732 700 $aBudevski$b E$g(Evgeni)$0924352 701 $aStaikov$b Georgi$0866153 701 $aLorenz$b W. J$0912235 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996203158703316 996 $aElectrochemical phase formation and growth$92074336 997 $aUNISA