LEADER 05130nam 2200613 450 001 996203158103316 005 20230421044601.0 010 $a1-281-84260-5 010 $a9786611842604 010 $a3-527-61471-0 010 $a3-527-61470-2 035 $a(CKB)1000000000376827 035 $a(EBL)481535 035 $a(SSID)ssj0000398168 035 $a(PQKBManifestationID)11249238 035 $a(PQKBTitleCode)TC0000398168 035 $a(PQKBWorkID)10362627 035 $a(PQKB)11714072 035 $a(MiAaPQ)EBC481535 035 $a(OCoLC)184983898 035 $a(EXLCZ)991000000000376827 100 $a20160819h19971997 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aSingle-molecule optical detection, imaging and spectroscopy /$fedited by T. Basche? [and three others] 210 1$aWeinheim, Germany :$cVCH,$d1997. 210 4$dİ1997 215 $a1 online resource (266 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29316-7 320 $aIncludes bibliographical references and index. 327 $aSingle-Molecule Optical Detection, Imaging and Spectroscopy; List of Contents; 1 Low-Temperature Studies in Solids; 1.1 Physical Principles and Methods of Single-Molecule Spectroscopy in Solids; 1.1.2 Physical principles and optimal conditions; 1.1.2.1 General considerations; 1.1.2.2 Spectral selection using zero-phonon lines and inhomogeneous broadening; 1.1.2.3 Peak absorption cross-section; 1.1.2.4 Other important requirements for single-molecule spectroscopy; 1.1.3 Methods; 1.1.3.1 Geometrical configurations for focusing and fluorescence collection; 1.1.3.2 Detection techniques 327 $aDirect absorption (frequency-modulation) spectroscopy with secondary modulationFluorescence excitation spectroscopy; Single-molecule imaging in frequency and space; Measurement of spectral trajectories of single molecules; Time correlation of single-molecule emission signal; 1.1.3.3 Materials systems and structures; 1.1.4 Summary and outlook; References; 1.2 Excitation and Emission Spectroscopy and Quantum Optical Measurements; 1.2.1 Introduction; 1.2.2 Single molecule optical excitation lineshape; 1.2.2.1 Basic properties; 1.2.2.2 Temperature dependence of the optical linewidth and lineshift 327 $a1.2.2.3 Saturation behaviour1.2.3 Flurorescence spectroscopy; 1.2.3.1 Basic instrumentation; 1.2.3.2 Observables; 1.2.3.3 Results of some specific systems; Pentacene in p-terphenyl; Terrylene in polyethylene; Terrylene in p-terphenyl; 1.2.4 Quantum optical experiments; 1.2.4.1 Introduction; 1.2.4.2 Quantum Jumps; Quantum jumps in single trapped Ions; Quantum jumps of a single molecule; 1.2.4.3 Fluorescence intensity autocorrelation function; Theoretical description of correlation effects in a single molecule; Experimental determination of the intensity correlation function 327 $aExperimental results1.2.4.4 Pump-probe experiments: lights shift; 1.2.5 Conclusion and outlook; Acknowledgeinent; References; 1.3 Polarization and Lifetime Measurements, External Perturbations and Microscopy; 1.3.1 Introduction; 1.3.2 Spectroscopy with polarized light; 1.3.2.1 Introduction; 1.3.2.2 Experimental; 1.3.2.3 Results and discussion; Modulation of the fluorescence intensity; Theoretical interpretation; Observation of domains; Assignment of the spectroscopic sites to the crystallographic sites; Determination of the depth of a single molecule relative to the surface 327 $a1.3.3 Fluorescence lifetime1.3.3.1 Experimental setup; 1.3.3.2 Data analysis; 1.3.3.3 Measurements and results; 1.3.4 External electric fields and Stark effect; 1.3.4.1 Theoretical overview; 1.3.4.2 Linear Stark effect of single terrylene molecules in polyethylene; Experimental setup; Measurements and results; 1.3.4.3 Perylene in nonane; 1.3.4.4 Quadratic Stark Effect of single pentacene molecules in p-terphenyl; Experimental setup; Measurement procedure; Results; 1.3.4.5 Stark effect in the optical near-field; Experimental setup; Results; 1.3.5 Pressure effect; 1.3.5.1 Experimental 327 $aReference cavity 330 $aSingle Molecule Spectroscopy is one of the hottest topics in today's chemistry. It brings us close to the the most exciting vision generations of chemists have been dreaming of: To observe and examine single molecules!While most of chemistry deals with myriads of molecules, this books presents the latest developments for the detection and investigation of single entities. Written by internationally renowned authors, it is a thorough and comprehensive survey of current methods and their applications. 606 $aMolecular spectra 606 $aMolecular spectroscopy 615 0$aMolecular spectra. 615 0$aMolecular spectroscopy. 676 $a543.0858 702 $aBasche?$b T. 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996203158103316 996 $aSingle-molecule optical detection, imaging and spectroscopy$93070410 997 $aUNISA