LEADER 05194nam 2200637Ia 450 001 996202138303316 005 20230421044556.0 010 $a1-281-75857-4 010 $a9786611758578 010 $a3-527-61517-2 010 $a3-527-61516-4 035 $a(CKB)1000000000376621 035 $a(EBL)482005 035 $a(OCoLC)261225144 035 $a(SSID)ssj0000096914 035 $a(PQKBManifestationID)11116484 035 $a(PQKBTitleCode)TC0000096914 035 $a(PQKBWorkID)10113124 035 $a(PQKB)10421445 035 $a(MiAaPQ)EBC482005 035 $a(EXLCZ)991000000000376621 100 $a19951010d1996 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aActive metals$b[electronic resource] $epreparation, characterization, applications /$fedited by Alois Fu?rstner 210 $aWeinheim ;$aNew York $cVCH$dc1996 215 $a1 online resource (486 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29207-1 320 $aIncludes bibliographical references and indexes. 327 $aActive Metals; Preface; Contents; List of Contributors; 1 Rieke Metals : Highly Reactive Metal Powders Prepared by Alkali Metal Reduction of Metal Salts; 1.1 Introduction; 1.1.1 Physical Characteristics of Highly Reactive Metal Powders; 1.2 Rieke Magnesium, Calcium, Strontium, and Barium; 1.2.1 Formation of Rieke Magnesium; 1.2.2 Formation of Rieke Calcium. Strontium. and Barium; 1.2.3 Grignard Reactions Using Rieke Metals; 1.2.4 1,3-Dicne-Magnesium Reagents; 1.2.4.1 Preparation; 1.2. 4.2 Regioselcctivity 327 $a1.2.4.3 Carbocyclization of (1.4-Diphenyl-2-butene-1,4-diyl)magnesium with Organic Dihalides1.2.4.4 1,2-Dimethylenecycloalkan e.Magnesium Reagents; 1.2.4.5 Synthesis of Fused Carbocycles, ?, ?-Unsaturated Ketones and 3-Cyclopentenols from Conjugated Diene-Magnesium Reagents; 1.2.4.6 Synthesis of Spiro ?-Lactones and Spiro ?-Lactones from 1,3-Diene-Magnesium Reagents; 1.2.4.7 Synthesis of ?-Lactams from Conjugated Diene-Magnesium Reagents; 1.3 Rieke Zinc; 1.3.1 The Preparation of Rieke Zinc; 1.3.2 Direct Oxidative Addition of Functionalized Alkyl and Aryl Halides 327 $a1.3.3 Reactions of Organozinc Reagents with Acid Chlorides1.3.4 Reactions of Organozinc Reagents with ?, ?-Unsaturated Ketones; 1.3.5 Reactions with Allylic and Alkynyl Halides; 1.3.6 Cross-Coupling of Vinyl and Aryl Organozinc Reagents Using a Palladium Catalyst; 1.3.7 Intramolecular Cyclizations and Conjugate Additions Mediated by Rieke Zinc; 1.3.8 Formation of Tertiary and Secondary Alkylzinc Bromides; 1.3.9 Cyanide-Based Rieke Zinc; 1.4 Organocopper Reagents Utilizing Rieke Copper; 1.4.1 Introduction; 1.4.2 Background to the Development of Rieke Copper; 1.4.3 Phosphine-Based Copper 327 $a1.4.4 Lithium 2-Thienylcyanocuprate-Based Copper1.4.5 Copper Cyanide-Based Active Copper; 1.4.6 Two-Equivalent Reduction of Copper(I) Complexes : A Formal Copper Anion; 1.5 Rieke Aluminum, Indium, and Nickel; 1.5.1 Aluminum; 1.5.2 Indium; 1 5.3 Nickel; 1.6 Synthesis of Specialized Polymers and New Materials via Rieke Metals; 1.6.1 Formation of Polyarylenes Mediated by Rieke Zinc; 1.6.2 Regiocontrolled Synthesis of Poly(3-alkylthiophenes) and Related Polymers Mediated by Rieke Zinc; 1.6.3 Synthesis of Poly(phenylcarbyne) Mediated by Rieke Calcium, Strontium, or Barium 327 $a1.6.4 Chemical Modification of Halogenated Polystyrenes Using Rieke Calcium or Copper1.6.5 Polymer Supported Rieke Metal Reagents and their Applications in Organic Synthesis; 2 Allylic Barium Reagents; 2.1 Introduction; 2.2 Preparation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.1 Direct Insertion Method Using Reactive Barium; 2.2.2 Stereochemical Stability; 2.2.3 Silylation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.3.1 Procedure for Generation of Reactive Barium (Ba*); 2.2.3.2 Procedure for Protonation of the Geranyl Barium Reagent 327 $a2.2.3.3 Silylation of (E)-2-Decenylbarium Chloride 330 $aReactions with metals are ubiquitous in organic synthesis and, particularly in the last few years, a large repertoire of methods for the activation of metals and for their use in organic synthesis has been developed. In Active Metals, topics ranging from morphology of metal clusters and nanometallurgy to organometallic chemistry, catalysis and the use of activated metals in natural product synthesis are authoritatively discussed by leading experts in the field.Active Metals will allow you to fully benefit from the recent advances in the field by giving:* Detailed experimental p 606 $aMetal activation 606 $aActive metals 606 $aOrganometallic compounds$xSynthesis 615 0$aMetal activation. 615 0$aActive metals. 615 0$aOrganometallic compounds$xSynthesis. 676 $a546.3 676 $a547.05 701 $aFu?rstner$b Alois$0945461 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996202138303316 996 $aActive metals$92134486 997 $aUNISA LEADER 02989nam 2200517 450 001 9910787276303321 005 20231110221409.0 010 $a2-8062-1771-7 035 $a(CKB)3710000000306923 035 $a(EBL)1869985 035 $a(Au-PeEL)EBL1869985 035 $a(OCoLC)897070925 035 $a(MiAaPQ)EBC1869985 035 $a(PPN)248793721 035 $a(EXLCZ)993710000000306923 100 $a20220519d2011 uy 1 101 0 $afre 135 $aur|n|---||||| 181 $ctxt$2rdacontent 182 $cc$2rdamedia 183 $acr$2rdacarrier 200 10$aGerminal d'Emile Zola (Analyse de L'oeuvre) $eResume Complet et Analyse detaillee de L'oeuvre /$fHadrien Seret, Lucile Lhoste 210 1$aCork, Ireland :$cLemaitre Publishing,$d[2011] 210 4$dİ2011 215 $a1 online resource (30 p.) 225 1 $aFiche de Lecture 300 $aDescription based upon print version of record. 311 $a2-8062-1284-7 327 $a1. Re?sume?; Premie?re partie; Deuxie?me partie; Troisie?me partie; Quatrie?me partie; Cinquie?me partie; Sixie?me partie; Septie?me partie; 2. E?tude des personnages; Les ouvriers; a) E?tienne Lantier; b) Maheu; c) Catherine Maheu; d) Chaval; La bourgeoisie; a) La bourgeoisie aise?e : les Gre?goire; b) La bourgeoisie moyenne : les Hennebeau; c) La bourgeoisie en difficulte? : Deneulin; 3. Cle?s de lecture; Un roman ancre? dans son temps; a) Situation des mineurs au milieu du XIXe sie?cle; b) L'e?mergence du socialisme et l'Internationale; c) Un traitement e?quitable des deux camps 327 $ad) Les malheurs de la bourgeoisieUn roman des Rougon-Macquart; The?mes principaux de Germinal; a) L'amour; b) La violence; c) L'amitie?; d) L'espoir, la cle? du titre; 4. Pistes de re?flexion; 5. Informations comple?mentaires 330 $a Tout ce qu'il faut savoir sur Germinal de Zola ! Retrouvez l'essentiel de l'?uvre dans une fiche de lecture comple?te et de?taille?e, avec un re?sume?, une e?tude des personnages, des cle?s de lecture et des pistes de re?flexion. Re?dige?e de manie?re claire et accessible, la fiche de lecture propose d'abord un re?sume? partie par partie du roman, puis s'inte?resse aux personnages des ouvriers, dont Lantier, Maheu et Chaval, et aux industriels bourgeois comme les Gre?goire et les Hennebeau. On e?tudie ensuite la porte?e sociale et politique de l'?uvre, l'inte?re?t documentaire de la description de la mine au XI 410 0$aFiche de Lecture 606 $aCoal mines and mining$vFiction 606 $aStrikes and lockouts$vFiction 615 0$aCoal mines and mining 615 0$aStrikes and lockouts 676 $a823.912 700 $aSeret$b Hadrien$0847095 702 $aLhoste$b Lucile 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a9910787276303321 996 $aGerminal d'Emile Zola (Analyse de L'oeuvre)$93682389 997 $aUNINA