LEADER 05194nam 2200637Ia 450 001 996202138303316 005 20230421044556.0 010 $a1-281-75857-4 010 $a9786611758578 010 $a3-527-61517-2 010 $a3-527-61516-4 035 $a(CKB)1000000000376621 035 $a(EBL)482005 035 $a(OCoLC)261225144 035 $a(SSID)ssj0000096914 035 $a(PQKBManifestationID)11116484 035 $a(PQKBTitleCode)TC0000096914 035 $a(PQKBWorkID)10113124 035 $a(PQKB)10421445 035 $a(MiAaPQ)EBC482005 035 $a(EXLCZ)991000000000376621 100 $a19951010d1996 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 00$aActive metals$b[electronic resource] $epreparation, characterization, applications /$fedited by Alois Fu?rstner 210 $aWeinheim ;$aNew York $cVCH$dc1996 215 $a1 online resource (486 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29207-1 320 $aIncludes bibliographical references and indexes. 327 $aActive Metals; Preface; Contents; List of Contributors; 1 Rieke Metals : Highly Reactive Metal Powders Prepared by Alkali Metal Reduction of Metal Salts; 1.1 Introduction; 1.1.1 Physical Characteristics of Highly Reactive Metal Powders; 1.2 Rieke Magnesium, Calcium, Strontium, and Barium; 1.2.1 Formation of Rieke Magnesium; 1.2.2 Formation of Rieke Calcium. Strontium. and Barium; 1.2.3 Grignard Reactions Using Rieke Metals; 1.2.4 1,3-Dicne-Magnesium Reagents; 1.2.4.1 Preparation; 1.2. 4.2 Regioselcctivity 327 $a1.2.4.3 Carbocyclization of (1.4-Diphenyl-2-butene-1,4-diyl)magnesium with Organic Dihalides1.2.4.4 1,2-Dimethylenecycloalkan e.Magnesium Reagents; 1.2.4.5 Synthesis of Fused Carbocycles, ?, ?-Unsaturated Ketones and 3-Cyclopentenols from Conjugated Diene-Magnesium Reagents; 1.2.4.6 Synthesis of Spiro ?-Lactones and Spiro ?-Lactones from 1,3-Diene-Magnesium Reagents; 1.2.4.7 Synthesis of ?-Lactams from Conjugated Diene-Magnesium Reagents; 1.3 Rieke Zinc; 1.3.1 The Preparation of Rieke Zinc; 1.3.2 Direct Oxidative Addition of Functionalized Alkyl and Aryl Halides 327 $a1.3.3 Reactions of Organozinc Reagents with Acid Chlorides1.3.4 Reactions of Organozinc Reagents with ?, ?-Unsaturated Ketones; 1.3.5 Reactions with Allylic and Alkynyl Halides; 1.3.6 Cross-Coupling of Vinyl and Aryl Organozinc Reagents Using a Palladium Catalyst; 1.3.7 Intramolecular Cyclizations and Conjugate Additions Mediated by Rieke Zinc; 1.3.8 Formation of Tertiary and Secondary Alkylzinc Bromides; 1.3.9 Cyanide-Based Rieke Zinc; 1.4 Organocopper Reagents Utilizing Rieke Copper; 1.4.1 Introduction; 1.4.2 Background to the Development of Rieke Copper; 1.4.3 Phosphine-Based Copper 327 $a1.4.4 Lithium 2-Thienylcyanocuprate-Based Copper1.4.5 Copper Cyanide-Based Active Copper; 1.4.6 Two-Equivalent Reduction of Copper(I) Complexes : A Formal Copper Anion; 1.5 Rieke Aluminum, Indium, and Nickel; 1.5.1 Aluminum; 1.5.2 Indium; 1 5.3 Nickel; 1.6 Synthesis of Specialized Polymers and New Materials via Rieke Metals; 1.6.1 Formation of Polyarylenes Mediated by Rieke Zinc; 1.6.2 Regiocontrolled Synthesis of Poly(3-alkylthiophenes) and Related Polymers Mediated by Rieke Zinc; 1.6.3 Synthesis of Poly(phenylcarbyne) Mediated by Rieke Calcium, Strontium, or Barium 327 $a1.6.4 Chemical Modification of Halogenated Polystyrenes Using Rieke Calcium or Copper1.6.5 Polymer Supported Rieke Metal Reagents and their Applications in Organic Synthesis; 2 Allylic Barium Reagents; 2.1 Introduction; 2.2 Preparation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.1 Direct Insertion Method Using Reactive Barium; 2.2.2 Stereochemical Stability; 2.2.3 Silylation of Stereochemically Homogeneous Allylic Barium Reagents; 2.2.3.1 Procedure for Generation of Reactive Barium (Ba*); 2.2.3.2 Procedure for Protonation of the Geranyl Barium Reagent 327 $a2.2.3.3 Silylation of (E)-2-Decenylbarium Chloride 330 $aReactions with metals are ubiquitous in organic synthesis and, particularly in the last few years, a large repertoire of methods for the activation of metals and for their use in organic synthesis has been developed. In Active Metals, topics ranging from morphology of metal clusters and nanometallurgy to organometallic chemistry, catalysis and the use of activated metals in natural product synthesis are authoritatively discussed by leading experts in the field.Active Metals will allow you to fully benefit from the recent advances in the field by giving:* Detailed experimental p 606 $aMetal activation 606 $aActive metals 606 $aOrganometallic compounds$xSynthesis 615 0$aMetal activation. 615 0$aActive metals. 615 0$aOrganometallic compounds$xSynthesis. 676 $a546.3 676 $a547.05 701 $aFu?rstner$b Alois$0945461 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996202138303316 996 $aActive metals$92134486 997 $aUNISA