LEADER 05287nam 2200649Ia 450 001 996201944303316 005 20170810191455.0 010 $a1-281-76427-2 010 $a9786611764272 010 $a3-527-61380-3 010 $a3-527-61381-1 035 $a(CKB)1000000000376615 035 $a(EBL)481287 035 $a(SSID)ssj0000257031 035 $a(PQKBManifestationID)11240281 035 $a(PQKBTitleCode)TC0000257031 035 $a(PQKBWorkID)10227646 035 $a(PQKB)11352768 035 $a(MiAaPQ)EBC481287 035 $a(PPN)156596016 035 $a(OCoLC)212131972 035 $a(EXLCZ)991000000000376615 100 $a19990502d1999 uy 0 101 0 $aeng 135 $aur|n|---||||| 181 $ctxt 182 $cc 183 $acr 200 10$aTemplate synthesis of macrocyclic compounds$b[electronic resource] /$fNicolai V. Gerbeleu, Vladimir B. Arion, John Burgess 210 $aWeinheim ;$aNew York $cWiley-VCH$dc1999 215 $a1 online resource (579 p.) 300 $aDescription based upon print version of record. 311 $a3-527-29559-3 320 $aIncludes bibliographical references and index. 327 $aTemplate Synthesis of Macrocyclic Compounds; Contents; 1 Template processes; 1.1 Introduction; 1.2 Fundamental terms and notions; 1.3 Mechanistic aspects of the template effect; 1.4 Generation of metal-free macrocycles; 1.5 Transmetallation; 1.6 Template particle types for obtaining different ligand products; 1.7 The place of metal template processes among other chemical reactions with participation of metal ions; 1.8 Classification of macrocyclic compounds; 1.9 References; 2 Template synthesis of polyazamacrocyclic compounds; 2.1 Cyclic hydrazines and hydrazones 327 $a2.2 Hexa- and pentaazamacrocyclic systems based on chalcogensemicarbazides2.3 Nickel(II) octaazamacrocyclic complexes based on thiocarbohydrazide; 2.4 Hexaazacyclotetradecine compounds containing azo groups; 2.5 Saturated polyazamacrocyclic compounds; 2.6 Tetra- and hexaazamacrocyclic complexes derived from diamines and bifunctional carbonyl compounds; 2.7 Macrocyclic complexes with ligands based on 1,3-dicarbonyl compounds and 1,2- or 1,3-diamines; 2.8 Macrocyclic systems based on aromatic o-aminocarbonyl compounds and their derivatives 327 $a2.9 The role of transition metal ions in the construction of model systems2.9.1 Porphyrins and related compounds; 2.9.2 Corrins; 2.9.3 Phthalocyanines; 2.10 References; 3 Template synthesis of macrocyclic systems based on di- and polyamines, and polyfunctional dicarbonyl compounds; 3.1 Macrocycles based on 2,6-dicarbonylpyridines, 2,5-diformylpyrrole and the simplest diamines; 3.2 Macrocycles based on 2,6-dicarbonylpyridines and 1,n-diamines containing an additional supporting donor atom 327 $a3.3 Macrocycles based on 2,6-dicarbonylpyridines and diamines containing two additional supporting donor atoms3.4 Macrocycles based on 2,6-dicarbonylpyridines and diamines containing three additional supporting donor atoms; 3.5 Macrocycles derived from 2,6-dicarbonylpyridines, 2,5- diformylpyrrole and 1,3-diaminopropan-2-ol; 3.6 Macrocycles derived from 2,5-diformylfuran, 2,5-diformylthiophene and 1,n-diamines; 3.7 References; 4 Template synthesis of three-dimensional macrocyclic systems; 4.1 Clathrochelates; 4.1.1 Clathrochelates based on 1,2- and 1,3-diaminoalkanes 327 $a4.1.2 Macrobicyclic tris(mono- and di-)oximates and other cage complexes4.1.3 Siderophore models and cryptands; 4.2 Catenanes, rotaxanes and knots; 4.2.1 Introduction; 4.2.2 Threading: pseudorotaxanes; 4.2.3 Rotaxanes; 4.2.4 Catenanes; 4.2.5 Knots; 4.3 References; 5 Phosphorus- and arsenic-containing macrocyclic compounds; 5.1 Phosphorus; 5.2 Arsenic; 5.3 References; 6 Crown ethers and related compounds; 6.1 Crown ethers; 6.2 Thiacrown ethers; 6.3 Heterocrown ethers; 6.4 References; 7 Covalent template synthesis; 7.1 Macrocyclic polylactones, polylactams and related compounds; 7.2 References 327 $a8 Polynucleating macrocyclic compounds 330 $aThe synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis.This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The c 606 $aMacrocyclic compounds$xSynthesis 606 $aBiochemical templates 615 0$aMacrocyclic compounds$xSynthesis. 615 0$aBiochemical templates. 676 $a546 676 $a547.50459 700 $aGe?rbe?le?u$b Nikolai? Vasil?evich$0542827 701 $aBurgess$b John$f1936-$0863257 701 $aArion$b V. B$g(Vladimir Borisovich)$0542828 801 0$bMiAaPQ 801 1$bMiAaPQ 801 2$bMiAaPQ 906 $aBOOK 912 $a996201944303316 996 $aTemplate synthesis of macrocyclic compounds$91926979 997 $aUNISA